Oxidative Radical NHC Catalysis: Divergent Difunctionalization of Olefins through Intermolecular Hydrogen Atom Transfer

Oxidative N‐heterocyclic carbene (NHC) organocatalysis, typically leading to the formation of acyl azolium reactive intermediates, constitutes one of the most important activation strategies for the NHC‐catalyzed chemical transformations. Here, we report an unprecedented oxidative radical NHC cataly...

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Veröffentlicht in:	Angewandte Chemie 2022-11, Vol.134 (44), p.n/a
Hauptverfasser:	Li, Qing‐Zhu, Liu, Yan‐Qing, Kou, Xin‐Xin, Zou, Wen‐Lin, Qi, Ting, Xiang, Peng, Xing, Jin‐Dun, Zhang, Xiang, Li, Jun‐Long
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Catalysis Chemistry Density-Functional Calculations Hydrogen atoms Intermediates N-Heterocyclic Carbenes Oxidants Oxidizing agents Peroxyesters Radicals Reaction Mechanisms
Online-Zugang:	Volltext
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