Enhancement of anticorrosion and antibiofouling performance of self-healing epoxy coating using nano-hydrotalcite materials and bifunctional biocide sodium pyrithione

The industry has an urgent demand for anticorrosion and antibiofouling integrated coating in the marine environment due to the huge economic loss caused by corrosion and biofouling. In this work, a self-healing epoxy coating was prepared based on nano-hydrotalcite (LDH) materials and bifunctional bi...

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Veröffentlicht in:Progress in organic coatings 2022-11, Vol.172, p.107121, Article 107121
Hauptverfasser: Jin, Zhengyu, Liu, Haixian, Wang, Zhi, Zhang, Wanqing, Chen, Yile, Zhao, Tong, Meng, Guozhe, Liu, Hongfang, Liu, Hongwei
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container_end_page
container_issue
container_start_page 107121
container_title Progress in organic coatings
container_volume 172
creator Jin, Zhengyu
Liu, Haixian
Wang, Zhi
Zhang, Wanqing
Chen, Yile
Zhao, Tong
Meng, Guozhe
Liu, Hongfang
Liu, Hongwei
description The industry has an urgent demand for anticorrosion and antibiofouling integrated coating in the marine environment due to the huge economic loss caused by corrosion and biofouling. In this work, a self-healing epoxy coating was prepared based on nano-hydrotalcite (LDH) materials and bifunctional biocide sodium pyrithione (SPT) aiming to provide some foundations for the anticorrosion and antibiofouling areas. Surface analysis, salt spray tests, and electrochemical measurements were used to character the prepared nanomaterials or measure the anticorrosion and antibiofouling performance of prepared coatings. Results indicate that the prepared CuAl-LDH-SPT coating not only had a high corrosion resistance but effectively inhibited the adhesion of Pseudomonas aeruginosa and Spirulina. The impedance values of CuAl-LDH-SPT coating increases by two orders of magnitude compared with the pure epoxy resin coating after 60 days of testing in 3.5 wt% NaCl solution. The prepared CuAl-LDH-SPT coating has a self-healing property due to the presence of SPT. •A self-healing epoxy coating based on nano-hydrotalcite materials and bifunctional biocide sodium pyrithione (SPT) is prepared.•The coating has excellent anticorrosion resistance in the seawater.•The coating can effectively inhibit the adhesion of P. aeruginosa and Spirulina.•The self-healing property of coating comes from the release and adsorption of SPT on the broken area.
doi_str_mv 10.1016/j.porgcoat.2022.107121
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subjects Antibiofouling
Anticorrosion
Biocides
Biofouling
Corrosion prevention
Corrosion resistance
Economic impact
Epoxy coatings
Epoxy resins
Marine environment
Nanomaterials
Protective coatings
Pseudomonas aeruginosa
Salt spray tests
Self healing materials
Self-healing coating
Sodium
Surface analysis (chemical)
title Enhancement of anticorrosion and antibiofouling performance of self-healing epoxy coating using nano-hydrotalcite materials and bifunctional biocide sodium pyrithione
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