Synthesis of new N-(diphosphonomethyl)-containing peptides on the base of tris(trimethylsilyl) phosphite

New functionalized N -(diphosphonomethyl)-containing peptides were synthesized in high yields by the reaction of tris(trimethylsilyl) phosphite with the appropriate N -formylpeptides under mild conditions in the presence of an effective catalyst, trimethylsilyl triflate. A catalytic scheme for the f...

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Veröffentlicht in:Russian chemical bulletin 2022-09, Vol.71 (9), p.1976-1980
Hauptverfasser: Prishchenko, A. A., Alekseev, R. S., Novikova, O. P., Livantsov, M. V., Livantsova, L. I., Baranin, S. V.
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container_end_page 1980
container_issue 9
container_start_page 1976
container_title Russian chemical bulletin
container_volume 71
creator Prishchenko, A. A.
Alekseev, R. S.
Novikova, O. P.
Livantsov, M. V.
Livantsova, L. I.
Baranin, S. V.
description New functionalized N -(diphosphonomethyl)-containing peptides were synthesized in high yields by the reaction of tris(trimethylsilyl) phosphite with the appropriate N -formylpeptides under mild conditions in the presence of an effective catalyst, trimethylsilyl triflate. A catalytic scheme for the formation of the products was proposed. The resulting compounds are of interest as promising biologically active substances and effective ligands.
doi_str_mv 10.1007/s11172-022-3616-x
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subjects Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Organic Chemistry
Peptides
title Synthesis of new N-(diphosphonomethyl)-containing peptides on the base of tris(trimethylsilyl) phosphite
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