Steam reforming of monoatomic aliphatic alcohols: factors affecting an equilibrium composition of products
The results of calculations of thermodynamic equilibria published over the last 15 years and experimental data for the catalytic steam reforming of ethanol, propanol, and n - and isobutyl alcohols were analyzed. When the conversion of the initial alcohol and yield of H 2 approach equilibrium values,...
Gespeichert in:
| Veröffentlicht in: | Russian chemical bulletin 2022-09, Vol.71 (9), p.1837-1846 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1846 |
|---|---|
| container_issue | 9 |
| container_start_page | 1837 |
| container_title | Russian chemical bulletin |
| container_volume | 71 |
| creator | Kuz’min, A. E. Kulikova, M. V. Osipov, A. K. Loktev, A. S. Dedov, A. G. |
| description | The results of calculations of thermodynamic equilibria published over the last 15 years and experimental data for the catalytic steam reforming of ethanol, propanol, and
n
- and isobutyl alcohols were analyzed. When the conversion of the initial alcohol and yield of H
2
approach equilibrium values, the selectivity to CO, CO
2
, and methane can both approach the equilibrium values and appreciably differ from them depending on the catalyst and reaction conditions. This illustrates a complicated character of the kinetic control of reforming reactions and demonstrates a possibility of generating either hydrogen, or synthesis-gas enriched in hydrogen. |
| doi_str_mv | 10.1007/s11172-022-3600-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2725634519</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2725634519</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-c070c1fea78fb6f677a88b3340b6bbf8b88df1a53daae41922c9fa98f73396473</originalsourceid><addsrcrecordid>eNp1kDtPwzAUhS0EEqXwA9gsMRv8iB9hQxUvqRIDMFuOa7eukri1nYF_T0KQmJjuGc53ju4B4JrgW4KxvMuEEEkRphQxgTHiJ2BBuGSoJpKcjhoLgThV_Bxc5LzHGFOl1ALs34szHUzOx9SFfgujh13soymxCxaaNhx2pvwoG3exzffQG1tiytB472yZGNNDdxxCG5oUhg7a2B1iDiXEfoo7pLgZbMmX4MybNrur37sEn0-PH6sXtH57fl09rJFlRBRkscSWeGek8o3wQkqjVMNYhRvRNF41Sm08MZxtjHEVqSm1tTe18pKxWlSSLcHNnDsWHweXi97HIfVjpaaScsEqTurRRWaXTTHn8X99SKEz6UsTrKdJ9TypHifV06SajwydmTx6-61Lf8n_Q9-BOntj</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2725634519</pqid></control><display><type>article</type><title>Steam reforming of monoatomic aliphatic alcohols: factors affecting an equilibrium composition of products</title><source>SpringerLink Journals</source><creator>Kuz’min, A. E. ; Kulikova, M. V. ; Osipov, A. K. ; Loktev, A. S. ; Dedov, A. G.</creator><creatorcontrib>Kuz’min, A. E. ; Kulikova, M. V. ; Osipov, A. K. ; Loktev, A. S. ; Dedov, A. G.</creatorcontrib><description>The results of calculations of thermodynamic equilibria published over the last 15 years and experimental data for the catalytic steam reforming of ethanol, propanol, and
n
- and isobutyl alcohols were analyzed. When the conversion of the initial alcohol and yield of H
2
approach equilibrium values, the selectivity to CO, CO
2
, and methane can both approach the equilibrium values and appreciably differ from them depending on the catalyst and reaction conditions. This illustrates a complicated character of the kinetic control of reforming reactions and demonstrates a possibility of generating either hydrogen, or synthesis-gas enriched in hydrogen.</description><identifier>ISSN: 1066-5285</identifier><identifier>EISSN: 1573-9171</identifier><identifier>DOI: 10.1007/s11172-022-3600-5</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aliphatic alcohols ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Ethanol ; Inorganic Chemistry ; Organic Chemistry ; Reforming ; Reviews ; Selectivity ; Thermodynamic equilibrium</subject><ispartof>Russian chemical bulletin, 2022-09, Vol.71 (9), p.1837-1846</ispartof><rights>Springer Science+Business Media LLC 2022</rights><rights>Springer Science+Business Media LLC 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-c070c1fea78fb6f677a88b3340b6bbf8b88df1a53daae41922c9fa98f73396473</citedby><cites>FETCH-LOGICAL-c316t-c070c1fea78fb6f677a88b3340b6bbf8b88df1a53daae41922c9fa98f73396473</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11172-022-3600-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11172-022-3600-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Kuz’min, A. E.</creatorcontrib><creatorcontrib>Kulikova, M. V.</creatorcontrib><creatorcontrib>Osipov, A. K.</creatorcontrib><creatorcontrib>Loktev, A. S.</creatorcontrib><creatorcontrib>Dedov, A. G.</creatorcontrib><title>Steam reforming of monoatomic aliphatic alcohols: factors affecting an equilibrium composition of products</title><title>Russian chemical bulletin</title><addtitle>Russ Chem Bull</addtitle><description>The results of calculations of thermodynamic equilibria published over the last 15 years and experimental data for the catalytic steam reforming of ethanol, propanol, and
n
- and isobutyl alcohols were analyzed. When the conversion of the initial alcohol and yield of H
2
approach equilibrium values, the selectivity to CO, CO
2
, and methane can both approach the equilibrium values and appreciably differ from them depending on the catalyst and reaction conditions. This illustrates a complicated character of the kinetic control of reforming reactions and demonstrates a possibility of generating either hydrogen, or synthesis-gas enriched in hydrogen.</description><subject>Aliphatic alcohols</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Ethanol</subject><subject>Inorganic Chemistry</subject><subject>Organic Chemistry</subject><subject>Reforming</subject><subject>Reviews</subject><subject>Selectivity</subject><subject>Thermodynamic equilibrium</subject><issn>1066-5285</issn><issn>1573-9171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kDtPwzAUhS0EEqXwA9gsMRv8iB9hQxUvqRIDMFuOa7eukri1nYF_T0KQmJjuGc53ju4B4JrgW4KxvMuEEEkRphQxgTHiJ2BBuGSoJpKcjhoLgThV_Bxc5LzHGFOl1ALs34szHUzOx9SFfgujh13soymxCxaaNhx2pvwoG3exzffQG1tiytB472yZGNNDdxxCG5oUhg7a2B1iDiXEfoo7pLgZbMmX4MybNrur37sEn0-PH6sXtH57fl09rJFlRBRkscSWeGek8o3wQkqjVMNYhRvRNF41Sm08MZxtjHEVqSm1tTe18pKxWlSSLcHNnDsWHweXi97HIfVjpaaScsEqTurRRWaXTTHn8X99SKEz6UsTrKdJ9TypHifV06SajwydmTx6-61Lf8n_Q9-BOntj</recordid><startdate>20220901</startdate><enddate>20220901</enddate><creator>Kuz’min, A. E.</creator><creator>Kulikova, M. V.</creator><creator>Osipov, A. K.</creator><creator>Loktev, A. S.</creator><creator>Dedov, A. G.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220901</creationdate><title>Steam reforming of monoatomic aliphatic alcohols: factors affecting an equilibrium composition of products</title><author>Kuz’min, A. E. ; Kulikova, M. V. ; Osipov, A. K. ; Loktev, A. S. ; Dedov, A. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-c070c1fea78fb6f677a88b3340b6bbf8b88df1a53daae41922c9fa98f73396473</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aliphatic alcohols</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Ethanol</topic><topic>Inorganic Chemistry</topic><topic>Organic Chemistry</topic><topic>Reforming</topic><topic>Reviews</topic><topic>Selectivity</topic><topic>Thermodynamic equilibrium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kuz’min, A. E.</creatorcontrib><creatorcontrib>Kulikova, M. V.</creatorcontrib><creatorcontrib>Osipov, A. K.</creatorcontrib><creatorcontrib>Loktev, A. S.</creatorcontrib><creatorcontrib>Dedov, A. G.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian chemical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kuz’min, A. E.</au><au>Kulikova, M. V.</au><au>Osipov, A. K.</au><au>Loktev, A. S.</au><au>Dedov, A. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Steam reforming of monoatomic aliphatic alcohols: factors affecting an equilibrium composition of products</atitle><jtitle>Russian chemical bulletin</jtitle><stitle>Russ Chem Bull</stitle><date>2022-09-01</date><risdate>2022</risdate><volume>71</volume><issue>9</issue><spage>1837</spage><epage>1846</epage><pages>1837-1846</pages><issn>1066-5285</issn><eissn>1573-9171</eissn><abstract>The results of calculations of thermodynamic equilibria published over the last 15 years and experimental data for the catalytic steam reforming of ethanol, propanol, and
n
- and isobutyl alcohols were analyzed. When the conversion of the initial alcohol and yield of H
2
approach equilibrium values, the selectivity to CO, CO
2
, and methane can both approach the equilibrium values and appreciably differ from them depending on the catalyst and reaction conditions. This illustrates a complicated character of the kinetic control of reforming reactions and demonstrates a possibility of generating either hydrogen, or synthesis-gas enriched in hydrogen.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11172-022-3600-5</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1066-5285 |
| ispartof | Russian chemical bulletin, 2022-09, Vol.71 (9), p.1837-1846 |
| issn | 1066-5285 1573-9171 |
| language | eng |
| recordid | cdi_proquest_journals_2725634519 |
| source | SpringerLink Journals |
| subjects | Aliphatic alcohols Chemistry Chemistry and Materials Science Chemistry/Food Science Ethanol Inorganic Chemistry Organic Chemistry Reforming Reviews Selectivity Thermodynamic equilibrium |
| title | Steam reforming of monoatomic aliphatic alcohols: factors affecting an equilibrium composition of products |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T12%3A03%3A29IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Steam%20reforming%20of%20monoatomic%20aliphatic%20alcohols:%20factors%20affecting%20an%20equilibrium%20composition%20of%20products&rft.jtitle=Russian%20chemical%20bulletin&rft.au=Kuz%E2%80%99min,%20A.%20E.&rft.date=2022-09-01&rft.volume=71&rft.issue=9&rft.spage=1837&rft.epage=1846&rft.pages=1837-1846&rft.issn=1066-5285&rft.eissn=1573-9171&rft_id=info:doi/10.1007/s11172-022-3600-5&rft_dat=%3Cproquest_cross%3E2725634519%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2725634519&rft_id=info:pmid/&rfr_iscdi=true |