Magnetic Metal–Organic Framework (Fe3O4@MIL-101) Functionalized with Dendrimer: Highly Efficient and Selective Adsorption Removal of Organic Dyes
Herein, a magnetic chromium-based metal–organic framework (MOF) was successfully synthesized and applied for adsorption and removal of methylene blue MB and methyl orange MO from an aqueous solution. To achieve high adsorption capacity and selective removal of organic dyes, rational surface function...
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| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2022-10, Vol.32 (10), p.3848-3863 |
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| creator | Far, Hossein Shahriyari Hasanzadeh, Mahdi Najafi, Mina Rabbani, Mahboubeh |
| description | Herein, a magnetic chromium-based metal–organic framework (MOF) was successfully synthesized and applied for adsorption and removal of methylene blue MB and methyl orange MO from an aqueous solution. To achieve high adsorption capacity and selective removal of organic dyes, rational surface functionalization of synthesized MOF with poly (propylene imine) PPI dendrimer was carried out. The Fe
3
O
4
@MIL-101@PPI composite exhibits a crystalline structure with high thermal stability and magnetic properties. In addition, this framework shows a high specific surface area (116 m
2
/g) and porosity which is beneficial for wastewater treatment. The results indicate that Fe
3
O
4
@MIL-101@PPI composite can remove cationic dye from an aqueous solution more selectively and efficiently than anionic dye. The adsorption experiments revealed high adsorption capacity (93.9 mg/g) and fast adsorption kinetics following the pseudo-second-order kinetic model. Interestingly, the regeneration study showed that the Fe
3
O
4
@MIL-101@PPI composite had appropriate reusability for dye removal with an almost unchanged structure after five regeneration cycles. This research provides new insights for the rational design of hybrid magnetic adsorbents with synergistic functionality and porous structure by combining the advantages of magnetic nanoparticles, MOFs, and dendrimers.
Graphical Abstract |
| doi_str_mv | 10.1007/s10904-022-02398-7 |
| format | Article |
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3
O
4
@MIL-101@PPI composite exhibits a crystalline structure with high thermal stability and magnetic properties. In addition, this framework shows a high specific surface area (116 m
2
/g) and porosity which is beneficial for wastewater treatment. The results indicate that Fe
3
O
4
@MIL-101@PPI composite can remove cationic dye from an aqueous solution more selectively and efficiently than anionic dye. The adsorption experiments revealed high adsorption capacity (93.9 mg/g) and fast adsorption kinetics following the pseudo-second-order kinetic model. Interestingly, the regeneration study showed that the Fe
3
O
4
@MIL-101@PPI composite had appropriate reusability for dye removal with an almost unchanged structure after five regeneration cycles. This research provides new insights for the rational design of hybrid magnetic adsorbents with synergistic functionality and porous structure by combining the advantages of magnetic nanoparticles, MOFs, and dendrimers.
Graphical Abstract</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-022-02398-7</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorption ; Aqueous solutions ; Cationic dyes ; Chemistry ; Chemistry and Materials Science ; Dendrimers ; Dyes ; Inorganic Chemistry ; Iron oxides ; Magnetic properties ; Metal-organic frameworks ; Methylene blue ; Nanoparticles ; Organic Chemistry ; Polymer Sciences ; Propylene ; Regeneration ; Selective adsorption ; Surface chemistry ; Synthesis ; Thermal stability ; Wastewater treatment</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2022-10, Vol.32 (10), p.3848-3863</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-fb250615adfae9279097db50026b6cb2af71013a564efe3e432363b8333162db3</citedby><cites>FETCH-LOGICAL-c249t-fb250615adfae9279097db50026b6cb2af71013a564efe3e432363b8333162db3</cites><orcidid>0000-0003-4951-8348</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-022-02398-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-022-02398-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Far, Hossein Shahriyari</creatorcontrib><creatorcontrib>Hasanzadeh, Mahdi</creatorcontrib><creatorcontrib>Najafi, Mina</creatorcontrib><creatorcontrib>Rabbani, Mahboubeh</creatorcontrib><title>Magnetic Metal–Organic Framework (Fe3O4@MIL-101) Functionalized with Dendrimer: Highly Efficient and Selective Adsorption Removal of Organic Dyes</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>Herein, a magnetic chromium-based metal–organic framework (MOF) was successfully synthesized and applied for adsorption and removal of methylene blue MB and methyl orange MO from an aqueous solution. To achieve high adsorption capacity and selective removal of organic dyes, rational surface functionalization of synthesized MOF with poly (propylene imine) PPI dendrimer was carried out. The Fe
3
O
4
@MIL-101@PPI composite exhibits a crystalline structure with high thermal stability and magnetic properties. In addition, this framework shows a high specific surface area (116 m
2
/g) and porosity which is beneficial for wastewater treatment. The results indicate that Fe
3
O
4
@MIL-101@PPI composite can remove cationic dye from an aqueous solution more selectively and efficiently than anionic dye. The adsorption experiments revealed high adsorption capacity (93.9 mg/g) and fast adsorption kinetics following the pseudo-second-order kinetic model. Interestingly, the regeneration study showed that the Fe
3
O
4
@MIL-101@PPI composite had appropriate reusability for dye removal with an almost unchanged structure after five regeneration cycles. This research provides new insights for the rational design of hybrid magnetic adsorbents with synergistic functionality and porous structure by combining the advantages of magnetic nanoparticles, MOFs, and dendrimers.
Graphical Abstract</description><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Cationic dyes</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dendrimers</subject><subject>Dyes</subject><subject>Inorganic Chemistry</subject><subject>Iron oxides</subject><subject>Magnetic properties</subject><subject>Metal-organic frameworks</subject><subject>Methylene blue</subject><subject>Nanoparticles</subject><subject>Organic Chemistry</subject><subject>Polymer Sciences</subject><subject>Propylene</subject><subject>Regeneration</subject><subject>Selective adsorption</subject><subject>Surface chemistry</subject><subject>Synthesis</subject><subject>Thermal stability</subject><subject>Wastewater treatment</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwkAUhhujiYi-gKtJ3OiiOpdOS11JgAoJhMTLejJtz5RiaXGmQHDlO_CGPomD9bJzcXLOSf7vXH7HOSf4mmAc3BiCQ-y5mFIbLOy4wYHTIjzwXOJxcvhbe-zYOTFmjjHrYE5azm4isxLqPEETqGXx8b6b6kyWto-0XMCm0i_oMgI29e4mo7FLMLlC0apM6rwqZZG_QYo2eT1DfShTnS9A36Jhns2KLRoolSc5lDWSZYoeoQALrQF1U1Pp5Z5HD7Co1rJAlUI_W_tbMKfOkZKFgbPv3Haeo8FTb-iOp_ejXnfsJtQLa1fFlGOfcJkqCSENQhwGacwxpn7sJzGVKrDnMsl9DxQw8BhlPos7jDHi0zRmbeeimbvU1esKTC3m1Urbt4ygAeW-FVJuVbRRJboyRoMSS_uo1FtBsNibLxrzhTVffJkvAguxBjJWXGag_0b_Q30CkguH5g</recordid><startdate>20221001</startdate><enddate>20221001</enddate><creator>Far, Hossein Shahriyari</creator><creator>Hasanzadeh, Mahdi</creator><creator>Najafi, Mina</creator><creator>Rabbani, Mahboubeh</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-4951-8348</orcidid></search><sort><creationdate>20221001</creationdate><title>Magnetic Metal–Organic Framework (Fe3O4@MIL-101) Functionalized with Dendrimer: Highly Efficient and Selective Adsorption Removal of Organic Dyes</title><author>Far, Hossein Shahriyari ; Hasanzadeh, Mahdi ; Najafi, Mina ; Rabbani, Mahboubeh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-fb250615adfae9279097db50026b6cb2af71013a564efe3e432363b8333162db3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Adsorption</topic><topic>Aqueous solutions</topic><topic>Cationic dyes</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dendrimers</topic><topic>Dyes</topic><topic>Inorganic Chemistry</topic><topic>Iron oxides</topic><topic>Magnetic properties</topic><topic>Metal-organic frameworks</topic><topic>Methylene blue</topic><topic>Nanoparticles</topic><topic>Organic Chemistry</topic><topic>Polymer Sciences</topic><topic>Propylene</topic><topic>Regeneration</topic><topic>Selective adsorption</topic><topic>Surface chemistry</topic><topic>Synthesis</topic><topic>Thermal stability</topic><topic>Wastewater treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Far, Hossein Shahriyari</creatorcontrib><creatorcontrib>Hasanzadeh, Mahdi</creatorcontrib><creatorcontrib>Najafi, Mina</creatorcontrib><creatorcontrib>Rabbani, Mahboubeh</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Far, Hossein Shahriyari</au><au>Hasanzadeh, Mahdi</au><au>Najafi, Mina</au><au>Rabbani, Mahboubeh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Magnetic Metal–Organic Framework (Fe3O4@MIL-101) Functionalized with Dendrimer: Highly Efficient and Selective Adsorption Removal of Organic Dyes</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2022-10-01</date><risdate>2022</risdate><volume>32</volume><issue>10</issue><spage>3848</spage><epage>3863</epage><pages>3848-3863</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>Herein, a magnetic chromium-based metal–organic framework (MOF) was successfully synthesized and applied for adsorption and removal of methylene blue MB and methyl orange MO from an aqueous solution. To achieve high adsorption capacity and selective removal of organic dyes, rational surface functionalization of synthesized MOF with poly (propylene imine) PPI dendrimer was carried out. The Fe
3
O
4
@MIL-101@PPI composite exhibits a crystalline structure with high thermal stability and magnetic properties. In addition, this framework shows a high specific surface area (116 m
2
/g) and porosity which is beneficial for wastewater treatment. The results indicate that Fe
3
O
4
@MIL-101@PPI composite can remove cationic dye from an aqueous solution more selectively and efficiently than anionic dye. The adsorption experiments revealed high adsorption capacity (93.9 mg/g) and fast adsorption kinetics following the pseudo-second-order kinetic model. Interestingly, the regeneration study showed that the Fe
3
O
4
@MIL-101@PPI composite had appropriate reusability for dye removal with an almost unchanged structure after five regeneration cycles. This research provides new insights for the rational design of hybrid magnetic adsorbents with synergistic functionality and porous structure by combining the advantages of magnetic nanoparticles, MOFs, and dendrimers.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-022-02398-7</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0003-4951-8348</orcidid></addata></record> |
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| subjects | Adsorption Aqueous solutions Cationic dyes Chemistry Chemistry and Materials Science Dendrimers Dyes Inorganic Chemistry Iron oxides Magnetic properties Metal-organic frameworks Methylene blue Nanoparticles Organic Chemistry Polymer Sciences Propylene Regeneration Selective adsorption Surface chemistry Synthesis Thermal stability Wastewater treatment |
| title | Magnetic Metal–Organic Framework (Fe3O4@MIL-101) Functionalized with Dendrimer: Highly Efficient and Selective Adsorption Removal of Organic Dyes |
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