Direct difunctional carbonylation of terminal alkynes with sodium sulfinates to access olefin sulfonyl methyl esters under metal-free conditions

A metal-free difunctional carbonylation procedure toward the synthesis of olefin sulfonyl methyl esters has been developed. By employing easily available terminal alkynes and sodium sulfinates as the starting materials, a broad range of olefin sulfonyl methyl esters were synthesized in moderate to g...

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Veröffentlicht in:	Organic Chemistry Frontiers 2022-10, Vol.9 (20), p.5631-5636
Hauptverfasser:	Chen, Bo, Yin, Han, Bao, Zhi-Peng, Kuai, Chang-Sheng, Wu, Xiao-Feng
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Carbonyls Esters Intermediates Organic chemistry Sodium
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description	A metal-free difunctional carbonylation procedure toward the synthesis of olefin sulfonyl methyl esters has been developed. By employing easily available terminal alkynes and sodium sulfinates as the starting materials, a broad range of olefin sulfonyl methyl esters were synthesized in moderate to good yields via radical intermediates.
doi_str_mv	10.1039/D2QO01311H
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subjects	Alkynes Carbonyls Esters Intermediates Organic chemistry Sodium
title	Direct difunctional carbonylation of terminal alkynes with sodium sulfinates to access olefin sulfonyl methyl esters under metal-free conditions
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