Influence of potassium iodide in polyvinyl alcohol-based gel polymer electrolyte for efficiency enhancement of dye-sensitized solar cells
This study investigates the impact of small cations on improving conductivity and efficiency of dye-sensitized solar cells (DSSCs). The work includes preparation and characterization of polyvinyl alcohol-based gel polymer electrolytes (GPEs) containing tetramethyl ammonium iodide (TMAI) and potassiu...
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| Veröffentlicht in: | Journal of polymer research 2022-11, Vol.29 (11), Article 455 |
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| creator | Aziz, M. F. Azam, M. A. Yusuf, S. N. F. Buraidah, M. H. Arof, A. K. |
| description | This study investigates the impact of small cations on improving conductivity and efficiency of dye-sensitized solar cells (DSSCs). The work includes preparation and characterization of polyvinyl alcohol-based gel polymer electrolytes (GPEs) containing tetramethyl ammonium iodide (TMAI) and potassium iodide (KI) salts. The degree of crystallinity of the GPEs has been determined from x-ray diffraction (XRD). From electrical impedance spectroscopy (EIS), the gel polymer electrolyte with only TMAI salt exhibits a conductivity of 1.72 mS cm
−1
. On addition of KI salt, conductivity increased up to a maximum of 7.87 mS cm
−1
for the GPE comprising 70 wt. % KI. The dye-sensitized solar cells (DSSCs) with GPE comprising 100 wt. % TMAI – 0 wt. % KI exhibits a short-current density,
J
sc
of 6.60 mA cm
−2
and open-circuit voltage,
V
oc
of 0.56 V. The fill factor,
ff
, and efficiency,
η
, obtained are 79% and 2.92%, respectively. The existence of a small cation K
+
in the GPE enhances DSSCs performance with GPE consisting of a 3:7 weight ratio between TMAI and KI exhibits
J
sc
of 11.30 mA cm
−2
and
V
oc
of 0.60 V. The acquired fill factor,
ff
, and efficiency,
η
, are 74% and 5.02%, respectively. |
| doi_str_mv | 10.1007/s10965-022-03305-x |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2722728372</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A721541470</galeid><sourcerecordid>A721541470</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-13965c723f9b2146937ec24c3754d52b14fd12b6c4687ad055141a0a70a5bf513</originalsourceid><addsrcrecordid>eNp9UctKJDEULQYHRp35gVkFXMfJo1LpWorMQxDc6DqkUjdtJJW0SfVgzR_41962RREGSSD3cc65uZym-c7ZKWdM_6ic9Z2iTAjKpGSKPnxqDrnSgq56qQ4w3rV63bEvzVGtd4wppbvVYfN4kXzcQnJAsiebPNtaw3YiIY9hBBIS1uLyN6QlEhtdvs2RDrbCSNYQn3sTFAIR3FwwmYH4jLn3wQVUXQikW4vqE6R5N2FcgFZINczhH4rUHG0hDmKsX5vP3sYK317e4-bm18_r8z_08ur3xfnZJXWSdzPlEhd1WkjfD4K3XS81ONE6qVU7KjHw1o9cDJ1ru5W2I-7JW26Z1cyqwSsuj5uTve6m5Pst1Nnc5W1JONIILfCuJKq_otY2ggnJ57lYN4XqzJkWXLW81QxRp_9B4RlhCi4n8AHr7whiT3Al11rAm00Jky2L4czsnDR7Jw3aZZ6dNA9IkntSRXBaQ3n78QesJ9Kwojw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2722728372</pqid></control><display><type>article</type><title>Influence of potassium iodide in polyvinyl alcohol-based gel polymer electrolyte for efficiency enhancement of dye-sensitized solar cells</title><source>SpringerLink</source><creator>Aziz, M. F. ; Azam, M. A. ; Yusuf, S. N. F. ; Buraidah, M. H. ; Arof, A. K.</creator><creatorcontrib>Aziz, M. F. ; Azam, M. A. ; Yusuf, S. N. F. ; Buraidah, M. H. ; Arof, A. K.</creatorcontrib><description>This study investigates the impact of small cations on improving conductivity and efficiency of dye-sensitized solar cells (DSSCs). The work includes preparation and characterization of polyvinyl alcohol-based gel polymer electrolytes (GPEs) containing tetramethyl ammonium iodide (TMAI) and potassium iodide (KI) salts. The degree of crystallinity of the GPEs has been determined from x-ray diffraction (XRD). From electrical impedance spectroscopy (EIS), the gel polymer electrolyte with only TMAI salt exhibits a conductivity of 1.72 mS cm
−1
. On addition of KI salt, conductivity increased up to a maximum of 7.87 mS cm
−1
for the GPE comprising 70 wt. % KI. The dye-sensitized solar cells (DSSCs) with GPE comprising 100 wt. % TMAI – 0 wt. % KI exhibits a short-current density,
J
sc
of 6.60 mA cm
−2
and open-circuit voltage,
V
oc
of 0.56 V. The fill factor,
ff
, and efficiency,
η
, obtained are 79% and 2.92%, respectively. The existence of a small cation K
+
in the GPE enhances DSSCs performance with GPE consisting of a 3:7 weight ratio between TMAI and KI exhibits
J
sc
of 11.30 mA cm
−2
and
V
oc
of 0.60 V. The acquired fill factor,
ff
, and efficiency,
η
, are 74% and 5.02%, respectively.</description><identifier>ISSN: 1022-9760</identifier><identifier>EISSN: 1572-8935</identifier><identifier>DOI: 10.1007/s10965-022-03305-x</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Cations ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Circuits ; Degree of crystallinity ; Diffraction ; Dye-sensitized solar cells ; Dyes ; Efficiency ; Electric properties ; Electrical impedance ; Electrolytes ; Electrolytic cells ; Industrial Chemistry/Chemical Engineering ; Open circuit voltage ; Original Paper ; Photovoltaic cells ; Polyelectrolytes ; Polymer industry ; Polymer Sciences ; Polymers ; Polyvinyl alcohol ; Potassium ; Potassium iodide ; Potassium iodides ; Solar batteries ; Solar cells ; X-rays</subject><ispartof>Journal of polymer research, 2022-11, Vol.29 (11), Article 455</ispartof><rights>The Polymer Society, Taipei 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>COPYRIGHT 2022 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-13965c723f9b2146937ec24c3754d52b14fd12b6c4687ad055141a0a70a5bf513</citedby><cites>FETCH-LOGICAL-c316t-13965c723f9b2146937ec24c3754d52b14fd12b6c4687ad055141a0a70a5bf513</cites><orcidid>0000-0001-5325-0773 ; 0000-0001-8551-7559</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10965-022-03305-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10965-022-03305-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Aziz, M. F.</creatorcontrib><creatorcontrib>Azam, M. A.</creatorcontrib><creatorcontrib>Yusuf, S. N. F.</creatorcontrib><creatorcontrib>Buraidah, M. H.</creatorcontrib><creatorcontrib>Arof, A. K.</creatorcontrib><title>Influence of potassium iodide in polyvinyl alcohol-based gel polymer electrolyte for efficiency enhancement of dye-sensitized solar cells</title><title>Journal of polymer research</title><addtitle>J Polym Res</addtitle><description>This study investigates the impact of small cations on improving conductivity and efficiency of dye-sensitized solar cells (DSSCs). The work includes preparation and characterization of polyvinyl alcohol-based gel polymer electrolytes (GPEs) containing tetramethyl ammonium iodide (TMAI) and potassium iodide (KI) salts. The degree of crystallinity of the GPEs has been determined from x-ray diffraction (XRD). From electrical impedance spectroscopy (EIS), the gel polymer electrolyte with only TMAI salt exhibits a conductivity of 1.72 mS cm
−1
. On addition of KI salt, conductivity increased up to a maximum of 7.87 mS cm
−1
for the GPE comprising 70 wt. % KI. The dye-sensitized solar cells (DSSCs) with GPE comprising 100 wt. % TMAI – 0 wt. % KI exhibits a short-current density,
J
sc
of 6.60 mA cm
−2
and open-circuit voltage,
V
oc
of 0.56 V. The fill factor,
ff
, and efficiency,
η
, obtained are 79% and 2.92%, respectively. The existence of a small cation K
+
in the GPE enhances DSSCs performance with GPE consisting of a 3:7 weight ratio between TMAI and KI exhibits
J
sc
of 11.30 mA cm
−2
and
V
oc
of 0.60 V. The acquired fill factor,
ff
, and efficiency,
η
, are 74% and 5.02%, respectively.</description><subject>Cations</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Circuits</subject><subject>Degree of crystallinity</subject><subject>Diffraction</subject><subject>Dye-sensitized solar cells</subject><subject>Dyes</subject><subject>Efficiency</subject><subject>Electric properties</subject><subject>Electrical impedance</subject><subject>Electrolytes</subject><subject>Electrolytic cells</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Open circuit voltage</subject><subject>Original Paper</subject><subject>Photovoltaic cells</subject><subject>Polyelectrolytes</subject><subject>Polymer industry</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Polyvinyl alcohol</subject><subject>Potassium</subject><subject>Potassium iodide</subject><subject>Potassium iodides</subject><subject>Solar batteries</subject><subject>Solar cells</subject><subject>X-rays</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9UctKJDEULQYHRp35gVkFXMfJo1LpWorMQxDc6DqkUjdtJJW0SfVgzR_41962RREGSSD3cc65uZym-c7ZKWdM_6ic9Z2iTAjKpGSKPnxqDrnSgq56qQ4w3rV63bEvzVGtd4wppbvVYfN4kXzcQnJAsiebPNtaw3YiIY9hBBIS1uLyN6QlEhtdvs2RDrbCSNYQn3sTFAIR3FwwmYH4jLn3wQVUXQikW4vqE6R5N2FcgFZINczhH4rUHG0hDmKsX5vP3sYK317e4-bm18_r8z_08ur3xfnZJXWSdzPlEhd1WkjfD4K3XS81ONE6qVU7KjHw1o9cDJ1ru5W2I-7JW26Z1cyqwSsuj5uTve6m5Pst1Nnc5W1JONIILfCuJKq_otY2ggnJ57lYN4XqzJkWXLW81QxRp_9B4RlhCi4n8AHr7whiT3Al11rAm00Jky2L4czsnDR7Jw3aZZ6dNA9IkntSRXBaQ3n78QesJ9Kwojw</recordid><startdate>20221101</startdate><enddate>20221101</enddate><creator>Aziz, M. F.</creator><creator>Azam, M. A.</creator><creator>Yusuf, S. N. F.</creator><creator>Buraidah, M. H.</creator><creator>Arof, A. K.</creator><general>Springer Netherlands</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-5325-0773</orcidid><orcidid>https://orcid.org/0000-0001-8551-7559</orcidid></search><sort><creationdate>20221101</creationdate><title>Influence of potassium iodide in polyvinyl alcohol-based gel polymer electrolyte for efficiency enhancement of dye-sensitized solar cells</title><author>Aziz, M. F. ; Azam, M. A. ; Yusuf, S. N. F. ; Buraidah, M. H. ; Arof, A. K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-13965c723f9b2146937ec24c3754d52b14fd12b6c4687ad055141a0a70a5bf513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Cations</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Circuits</topic><topic>Degree of crystallinity</topic><topic>Diffraction</topic><topic>Dye-sensitized solar cells</topic><topic>Dyes</topic><topic>Efficiency</topic><topic>Electric properties</topic><topic>Electrical impedance</topic><topic>Electrolytes</topic><topic>Electrolytic cells</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Open circuit voltage</topic><topic>Original Paper</topic><topic>Photovoltaic cells</topic><topic>Polyelectrolytes</topic><topic>Polymer industry</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Polyvinyl alcohol</topic><topic>Potassium</topic><topic>Potassium iodide</topic><topic>Potassium iodides</topic><topic>Solar batteries</topic><topic>Solar cells</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aziz, M. F.</creatorcontrib><creatorcontrib>Azam, M. A.</creatorcontrib><creatorcontrib>Yusuf, S. N. F.</creatorcontrib><creatorcontrib>Buraidah, M. H.</creatorcontrib><creatorcontrib>Arof, A. K.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aziz, M. F.</au><au>Azam, M. A.</au><au>Yusuf, S. N. F.</au><au>Buraidah, M. H.</au><au>Arof, A. K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of potassium iodide in polyvinyl alcohol-based gel polymer electrolyte for efficiency enhancement of dye-sensitized solar cells</atitle><jtitle>Journal of polymer research</jtitle><stitle>J Polym Res</stitle><date>2022-11-01</date><risdate>2022</risdate><volume>29</volume><issue>11</issue><artnum>455</artnum><issn>1022-9760</issn><eissn>1572-8935</eissn><abstract>This study investigates the impact of small cations on improving conductivity and efficiency of dye-sensitized solar cells (DSSCs). The work includes preparation and characterization of polyvinyl alcohol-based gel polymer electrolytes (GPEs) containing tetramethyl ammonium iodide (TMAI) and potassium iodide (KI) salts. The degree of crystallinity of the GPEs has been determined from x-ray diffraction (XRD). From electrical impedance spectroscopy (EIS), the gel polymer electrolyte with only TMAI salt exhibits a conductivity of 1.72 mS cm
−1
. On addition of KI salt, conductivity increased up to a maximum of 7.87 mS cm
−1
for the GPE comprising 70 wt. % KI. The dye-sensitized solar cells (DSSCs) with GPE comprising 100 wt. % TMAI – 0 wt. % KI exhibits a short-current density,
J
sc
of 6.60 mA cm
−2
and open-circuit voltage,
V
oc
of 0.56 V. The fill factor,
ff
, and efficiency,
η
, obtained are 79% and 2.92%, respectively. The existence of a small cation K
+
in the GPE enhances DSSCs performance with GPE consisting of a 3:7 weight ratio between TMAI and KI exhibits
J
sc
of 11.30 mA cm
−2
and
V
oc
of 0.60 V. The acquired fill factor,
ff
, and efficiency,
η
, are 74% and 5.02%, respectively.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10965-022-03305-x</doi><orcidid>https://orcid.org/0000-0001-5325-0773</orcidid><orcidid>https://orcid.org/0000-0001-8551-7559</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Journal of polymer research, 2022-11, Vol.29 (11), Article 455 |
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| language | eng |
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| subjects | Cations Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Circuits Degree of crystallinity Diffraction Dye-sensitized solar cells Dyes Efficiency Electric properties Electrical impedance Electrolytes Electrolytic cells Industrial Chemistry/Chemical Engineering Open circuit voltage Original Paper Photovoltaic cells Polyelectrolytes Polymer industry Polymer Sciences Polymers Polyvinyl alcohol Potassium Potassium iodide Potassium iodides Solar batteries Solar cells X-rays |
| title | Influence of potassium iodide in polyvinyl alcohol-based gel polymer electrolyte for efficiency enhancement of dye-sensitized solar cells |
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