Anomeric Stereoauxiliary Cleavage of the C−N Bond of d‐Glucosamine for the Preparation of Imidazopyridines

The targeted cleavage of the C−N bonds of alkyl primary amines in sustainable compounds of biomass according to a metal‐free pathway and the conjunction of nitrogen in the synthesis of imidazo[1,5‐a]pyridines are still highly challenging. Despite tremendous progress in the synthesis of imidazo[1,5‐a...

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Veröffentlicht in:	Chemistry : a European journal 2022-05, Vol.28 (29)
Hauptverfasser:	Zeng, Kui, Ye, Jin, Meng, Xintong, Dechert, Sebastian, Martin, Simon, Gong, Shuaiyu, Mata, Ricardo A, Zhang, Kai
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Amines Chemical bonds Chemistry Cleavage Deuteration Ductile-brittle transition Glucosamine Ketones Nitrogen Pyridines Synthesis
Online-Zugang:	Volltext
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