Effects of structural variation on the self‐assembly of bis‐urea based bolaamphiphiles
We report on the self‐assembly in water of a set of bis‐urea amphiphiles. A range of techniques, including dynamic light scattering, Cryo‐TEM, SAXS, and MS are used to study the effect of structural variation on the morphology of the assemblies. The length, dispersity, and end‐group of the ethylene...
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| Veröffentlicht in: | Journal of polymer science (2020) 2021-06, Vol.59 (12), p.1162-1170 |
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| container_title | Journal of polymer science (2020) |
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| creator | Liu, Jie Schotman, Maaike J. G. Hendrix, Marco M. R. M. Lou, Xianwen Marín San Román, Patricia P. Voets, Ilja K. Sijbesma, Rint P. |
| description | We report on the self‐assembly in water of a set of bis‐urea amphiphiles. A range of techniques, including dynamic light scattering, Cryo‐TEM, SAXS, and MS are used to study the effect of structural variation on the morphology of the assemblies. The length, dispersity, and end‐group of the ethylene glycol hydrophilic part of the molecule, as well as of the alkyl chain length are varied to tailor the morphology towards soluble wormlike micelles. Slight modification on molecular structures gave a large difference in self‐assembly behavior in water, giving guidelines for the design of rodlike supramolecular fibers with novel functionalities, such as strain‐stiffening and bioactivity.
In this research, the self‐assembly of a set of bis‐urea amphiphiles in water is investigated. Slight modifications of end group, chain length, and dispersity can tailor the morphology. The findings provide new insights into the relationship between selfassembled morphologies and chemical composition, which can guide the design of rodlike supramolecular fibers with novel functionalities. |
| doi_str_mv | 10.1002/pol.20200888 |
| format | Article |
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In this research, the self‐assembly of a set of bis‐urea amphiphiles in water is investigated. Slight modifications of end group, chain length, and dispersity can tailor the morphology. The findings provide new insights into the relationship between selfassembled morphologies and chemical composition, which can guide the design of rodlike supramolecular fibers with novel functionalities.</description><identifier>ISSN: 2642-4150</identifier><identifier>EISSN: 2642-4169</identifier><identifier>DOI: 10.1002/pol.20200888</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Assembly ; bis‐urea bolaamphiphiles ; chemical structures ; Ethylene glycol ; Micelles ; Molecular structure ; Morphology ; oligo(ethylene glycol) ; Photon correlation spectroscopy ; self‐assembly ; Stiffening ; Ureas</subject><ispartof>Journal of polymer science (2020), 2021-06, Vol.59 (12), p.1162-1170</ispartof><rights>2021 The Authors. published by Wiley Periodicals LLC.</rights><rights>2021. This article is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3827-d39790e4cb951ad42e1567cc00fbb40dd71a37fa2b9ee87a35036c2f594e2cba3</citedby><cites>FETCH-LOGICAL-c3827-d39790e4cb951ad42e1567cc00fbb40dd71a37fa2b9ee87a35036c2f594e2cba3</cites><orcidid>0000-0003-0118-9872 ; 0000-0003-4826-3646 ; 0000-0002-7393-4889 ; 0000-0002-8975-636X ; 0000-0003-3543-4821 ; 0000-0002-5403-3647</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpol.20200888$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpol.20200888$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,1416,27915,27916,45565,45566</link.rule.ids></links><search><creatorcontrib>Liu, Jie</creatorcontrib><creatorcontrib>Schotman, Maaike J. G.</creatorcontrib><creatorcontrib>Hendrix, Marco M. R. M.</creatorcontrib><creatorcontrib>Lou, Xianwen</creatorcontrib><creatorcontrib>Marín San Román, Patricia P.</creatorcontrib><creatorcontrib>Voets, Ilja K.</creatorcontrib><creatorcontrib>Sijbesma, Rint P.</creatorcontrib><title>Effects of structural variation on the self‐assembly of bis‐urea based bolaamphiphiles</title><title>Journal of polymer science (2020)</title><description>We report on the self‐assembly in water of a set of bis‐urea amphiphiles. A range of techniques, including dynamic light scattering, Cryo‐TEM, SAXS, and MS are used to study the effect of structural variation on the morphology of the assemblies. The length, dispersity, and end‐group of the ethylene glycol hydrophilic part of the molecule, as well as of the alkyl chain length are varied to tailor the morphology towards soluble wormlike micelles. Slight modification on molecular structures gave a large difference in self‐assembly behavior in water, giving guidelines for the design of rodlike supramolecular fibers with novel functionalities, such as strain‐stiffening and bioactivity.
In this research, the self‐assembly of a set of bis‐urea amphiphiles in water is investigated. Slight modifications of end group, chain length, and dispersity can tailor the morphology. The findings provide new insights into the relationship between selfassembled morphologies and chemical composition, which can guide the design of rodlike supramolecular fibers with novel functionalities.</description><subject>Assembly</subject><subject>bis‐urea bolaamphiphiles</subject><subject>chemical structures</subject><subject>Ethylene glycol</subject><subject>Micelles</subject><subject>Molecular structure</subject><subject>Morphology</subject><subject>oligo(ethylene glycol)</subject><subject>Photon correlation spectroscopy</subject><subject>self‐assembly</subject><subject>Stiffening</subject><subject>Ureas</subject><issn>2642-4150</issn><issn>2642-4169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNp9kM9KAzEQh4MoWGpvPsCCV7dOJrubzbGU-gcK9aAXLyHJJnTLtrsmu0pvPoLP6JOYUvUo_GCG4WOG-Qi5pDClAHjTtc0UAQHKsjwhIywyTDNaiNO_PodzMglhAxFneZFBMSIvC-es6UPSuiT0fjD94FWTvClfq75ud0lMv7ZJsI37-vhUIditbvYHXNchTgZvVaJVsFWi20apbbeuYxobLsiZU02wk586Js-3i6f5fbpc3T3MZ8vUsBJ5WjHBBdjMaJFTVWVoaV5wYwCc1hlUFaeKcadQC2tLrlgOrDDocpFZNFqxMbk67u18-zrY0MtNO_hdPCmRI2UItMBIXR8p49sQvHWy8_VW-b2kIA8CZRQofwVGnB3x9_jK_l9WPq6WMxSCc_YNIWx1tA</recordid><startdate>20210615</startdate><enddate>20210615</enddate><creator>Liu, Jie</creator><creator>Schotman, Maaike J. G.</creator><creator>Hendrix, Marco M. R. M.</creator><creator>Lou, Xianwen</creator><creator>Marín San Román, Patricia P.</creator><creator>Voets, Ilja K.</creator><creator>Sijbesma, Rint P.</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>24P</scope><scope>WIN</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-0118-9872</orcidid><orcidid>https://orcid.org/0000-0003-4826-3646</orcidid><orcidid>https://orcid.org/0000-0002-7393-4889</orcidid><orcidid>https://orcid.org/0000-0002-8975-636X</orcidid><orcidid>https://orcid.org/0000-0003-3543-4821</orcidid><orcidid>https://orcid.org/0000-0002-5403-3647</orcidid></search><sort><creationdate>20210615</creationdate><title>Effects of structural variation on the self‐assembly of bis‐urea based bolaamphiphiles</title><author>Liu, Jie ; Schotman, Maaike J. G. ; Hendrix, Marco M. R. M. ; Lou, Xianwen ; Marín San Román, Patricia P. ; Voets, Ilja K. ; Sijbesma, Rint P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3827-d39790e4cb951ad42e1567cc00fbb40dd71a37fa2b9ee87a35036c2f594e2cba3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Assembly</topic><topic>bis‐urea bolaamphiphiles</topic><topic>chemical structures</topic><topic>Ethylene glycol</topic><topic>Micelles</topic><topic>Molecular structure</topic><topic>Morphology</topic><topic>oligo(ethylene glycol)</topic><topic>Photon correlation spectroscopy</topic><topic>self‐assembly</topic><topic>Stiffening</topic><topic>Ureas</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Jie</creatorcontrib><creatorcontrib>Schotman, Maaike J. G.</creatorcontrib><creatorcontrib>Hendrix, Marco M. R. M.</creatorcontrib><creatorcontrib>Lou, Xianwen</creatorcontrib><creatorcontrib>Marín San Román, Patricia P.</creatorcontrib><creatorcontrib>Voets, Ilja K.</creatorcontrib><creatorcontrib>Sijbesma, Rint P.</creatorcontrib><collection>Wiley-Blackwell Open Access Titles</collection><collection>Wiley Free Content</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of polymer science (2020)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Jie</au><au>Schotman, Maaike J. G.</au><au>Hendrix, Marco M. R. 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Slight modification on molecular structures gave a large difference in self‐assembly behavior in water, giving guidelines for the design of rodlike supramolecular fibers with novel functionalities, such as strain‐stiffening and bioactivity.
In this research, the self‐assembly of a set of bis‐urea amphiphiles in water is investigated. Slight modifications of end group, chain length, and dispersity can tailor the morphology. The findings provide new insights into the relationship between selfassembled morphologies and chemical composition, which can guide the design of rodlike supramolecular fibers with novel functionalities.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/pol.20200888</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-0118-9872</orcidid><orcidid>https://orcid.org/0000-0003-4826-3646</orcidid><orcidid>https://orcid.org/0000-0002-7393-4889</orcidid><orcidid>https://orcid.org/0000-0002-8975-636X</orcidid><orcidid>https://orcid.org/0000-0003-3543-4821</orcidid><orcidid>https://orcid.org/0000-0002-5403-3647</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Assembly bis‐urea bolaamphiphiles chemical structures Ethylene glycol Micelles Molecular structure Morphology oligo(ethylene glycol) Photon correlation spectroscopy self‐assembly Stiffening Ureas |
| title | Effects of structural variation on the self‐assembly of bis‐urea based bolaamphiphiles |
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