MOF-derived multi-interface carbon-based composites with enhanced polarization loss and efficient microwave absorption

Metal-organic framework materials (MOFs) have been widely studied because of their adjustable composition and controllable structure in the field of microwave absorption (MA). Therein, Prussian blue analogs (PBA) have attracted the attention of researchers with ultra-high metal content. However, the...

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Veröffentlicht in:International journal of smart and nano materials 2022-07, Vol.13 (3), p.465-480
Hauptverfasser: Qu, Hongjiao, Zheng, Peng, Wang, Tao, Yu, Xingyu, Pan, Junjie, Fan, Xiaoli, Zhang, Tengfei, Sun, Xin, He, Jianping
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container_issue 3
container_start_page 465
container_title International journal of smart and nano materials
container_volume 13
creator Qu, Hongjiao
Zheng, Peng
Wang, Tao
Yu, Xingyu
Pan, Junjie
Fan, Xiaoli
Zhang, Tengfei
Sun, Xin
He, Jianping
description Metal-organic framework materials (MOFs) have been widely studied because of their adjustable composition and controllable structure in the field of microwave absorption (MA). Therein, Prussian blue analogs (PBA) have attracted the attention of researchers with ultra-high metal content. However, the attenuation ability of microwave for PBA-based composites is still unsatisfactory up to now. Therefore, the NiFe/CoFe@C composites were prepared by carbonizing polymetallic PBA (NiCoFe PBA) materials in this work, and the influence of different metal alloy components on MA was explored by adjusting the ratio of metal ions (Ni 2+ /Co 2+ ). Moreover, the NiFe/CoFe@C composites have rich interfaces and enhance the polarization loss due to the introduction of Ni and it has an optimal performance at 2.7 mm that is the reflection loss (RL) is −41.49 dB and an effective absorption bandwidth (EAB) is 7.12 GHz with 1/1 (Ni 2+ /Co 2+ ). The above data provides a research idea for obtaining light and efficient absorbers.
doi_str_mv 10.1080/19475411.2022.2095456
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Therein, Prussian blue analogs (PBA) have attracted the attention of researchers with ultra-high metal content. However, the attenuation ability of microwave for PBA-based composites is still unsatisfactory up to now. Therefore, the NiFe/CoFe@C composites were prepared by carbonizing polymetallic PBA (NiCoFe PBA) materials in this work, and the influence of different metal alloy components on MA was explored by adjusting the ratio of metal ions (Ni 2+ /Co 2+ ). Moreover, the NiFe/CoFe@C composites have rich interfaces and enhance the polarization loss due to the introduction of Ni and it has an optimal performance at 2.7 mm that is the reflection loss (RL) is −41.49 dB and an effective absorption bandwidth (EAB) is 7.12 GHz with 1/1 (Ni 2+ /Co 2+ ). 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subjects Aeronautics
Alloys
Carbon
carbon-based composites
Cobalt
Composite materials
Intermetallic compounds
Iron compounds
Laboratories
Materials science
metal alloy
Metal-organic frameworks
Microwave absorption
Microwave attenuation
Morphology
Nickel base alloys
Nickel compounds
Pigments
Polarization
polarization loss
Prussian blue analogs
title MOF-derived multi-interface carbon-based composites with enhanced polarization loss and efficient microwave absorption
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