Zinc Pentafluorobenzoate [Zn2(H2O)(C6F5COO)4(Py)4]: Synthesis, Structure, and Thermodynamic Characteristics
The reaction of zinc pentafluorobenzoate [Zn(H 2 O)(C 6 F 5 COO) 2 ] n with a pyridine excess (Py, ratio Zn : Py = 1 : 4) affords crystals of complex [Zn 2 (H 2 O)(C 6 F 5 COO) 4 (Py) 4 ] ( I ). The crystal packing of complex I is stabilized by numerous intra- and intermolecular interactions π…π, O…...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2022-10, Vol.48 (10), p.608-614 |
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| container_title | Russian journal of coordination chemistry |
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| creator | Malkerova, I. P. Kayumova, D. B. Belova, E. V. Shmelev, M. A. Sidorov, A. A. Alikhanyan, A. S. |
| description | The reaction of zinc pentafluorobenzoate [Zn(H
2
O)(C
6
F
5
COO)
2
]
n
with a pyridine excess (Py, ratio Zn : Py = 1 : 4) affords crystals of complex [Zn
2
(H
2
O)(C
6
F
5
COO)
4
(Py)
4
] (
I
). The crystal packing of complex
I
is stabilized by numerous intra- and intermolecular interactions π…π, O…H, F…π, C–H…F, and С–H…O. The compound is characterized by the data of X-ray diffraction (XRD) (CIF file ССDС no. 2157445), IR spectroscopy, C,H,N elemental analysis, and phase XRD analysis. The vaporization of [Zn
2
(H
2
O)(C
6
F
5
COO)
4
(Py)
4
] is studied by the Knudsen effusion method with mass spectral analysis of the gas phase. This process is found to proceed in three stages with the consecutive transition of pyridine molecules to the vapor, partial hydrolysis, and congruent sublimation of zinc pentafluorobenzoate to form free molecules of Zn(C
6
F
5
)
2
and СО
2
. The absolute partial pressures of saturated vapor and standard enthalpies of formation are calculated:
(Zn(C
6
F
5
COO)
2
, s) ≤ –2634.1 ± 32.2 kJ/mol and
(Zn(С
6
F
5
)
2
, g) ≤ –1422.6 ± 31.3 kJ/mol. |
| doi_str_mv | 10.1134/S1070328422100037 |
| format | Article |
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2
O)(C
6
F
5
COO)
2
]
n
with a pyridine excess (Py, ratio Zn : Py = 1 : 4) affords crystals of complex [Zn
2
(H
2
O)(C
6
F
5
COO)
4
(Py)
4
] (
I
). The crystal packing of complex
I
is stabilized by numerous intra- and intermolecular interactions π…π, O…H, F…π, C–H…F, and С–H…O. The compound is characterized by the data of X-ray diffraction (XRD) (CIF file ССDС no. 2157445), IR spectroscopy, C,H,N elemental analysis, and phase XRD analysis. The vaporization of [Zn
2
(H
2
O)(C
6
F
5
COO)
4
(Py)
4
] is studied by the Knudsen effusion method with mass spectral analysis of the gas phase. This process is found to proceed in three stages with the consecutive transition of pyridine molecules to the vapor, partial hydrolysis, and congruent sublimation of zinc pentafluorobenzoate to form free molecules of Zn(C
6
F
5
)
2
and СО
2
. The absolute partial pressures of saturated vapor and standard enthalpies of formation are calculated:
(Zn(C
6
F
5
COO)
2
, s) ≤ –2634.1 ± 32.2 kJ/mol and
(Zn(С
6
F
5
)
2
, g) ≤ –1422.6 ± 31.3 kJ/mol.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328422100037</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemical analysis ; Chemistry ; Chemistry and Materials Science ; Enthalpy ; Infrared spectroscopy ; Inorganic Chemistry ; Knudsen effusion ; Physical Chemistry ; Pyridines ; Spectrum analysis ; Sublimation ; Vapor phases ; Vaporization ; X-ray diffraction ; Zinc</subject><ispartof>Russian journal of coordination chemistry, 2022-10, Vol.48 (10), p.608-614</ispartof><rights>Pleiades Publishing, Ltd. 2022. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2022, Vol. 48, No. 10, pp. 608–614. © Pleiades Publishing, Ltd., 2022. Russian Text © The Author(s), 2022, published in Koordinatsionnaya Khimiya, 2022, Vol. 48, No. 10, pp. 590–597.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-4e2116d650cbc50758b5934f9446bc2385b25636035a642f69b17fcc4473ad293</citedby><cites>FETCH-LOGICAL-c316t-4e2116d650cbc50758b5934f9446bc2385b25636035a642f69b17fcc4473ad293</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328422100037$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328422100037$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27911,27912,41475,42544,51306</link.rule.ids></links><search><creatorcontrib>Malkerova, I. P.</creatorcontrib><creatorcontrib>Kayumova, D. B.</creatorcontrib><creatorcontrib>Belova, E. V.</creatorcontrib><creatorcontrib>Shmelev, M. A.</creatorcontrib><creatorcontrib>Sidorov, A. A.</creatorcontrib><creatorcontrib>Alikhanyan, A. S.</creatorcontrib><title>Zinc Pentafluorobenzoate [Zn2(H2O)(C6F5COO)4(Py)4]: Synthesis, Structure, and Thermodynamic Characteristics</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>The reaction of zinc pentafluorobenzoate [Zn(H
2
O)(C
6
F
5
COO)
2
]
n
with a pyridine excess (Py, ratio Zn : Py = 1 : 4) affords crystals of complex [Zn
2
(H
2
O)(C
6
F
5
COO)
4
(Py)
4
] (
I
). The crystal packing of complex
I
is stabilized by numerous intra- and intermolecular interactions π…π, O…H, F…π, C–H…F, and С–H…O. The compound is characterized by the data of X-ray diffraction (XRD) (CIF file ССDС no. 2157445), IR spectroscopy, C,H,N elemental analysis, and phase XRD analysis. The vaporization of [Zn
2
(H
2
O)(C
6
F
5
COO)
4
(Py)
4
] is studied by the Knudsen effusion method with mass spectral analysis of the gas phase. This process is found to proceed in three stages with the consecutive transition of pyridine molecules to the vapor, partial hydrolysis, and congruent sublimation of zinc pentafluorobenzoate to form free molecules of Zn(C
6
F
5
)
2
and СО
2
. The absolute partial pressures of saturated vapor and standard enthalpies of formation are calculated:
(Zn(C
6
F
5
COO)
2
, s) ≤ –2634.1 ± 32.2 kJ/mol and
(Zn(С
6
F
5
)
2
, g) ≤ –1422.6 ± 31.3 kJ/mol.</description><subject>Chemical analysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Enthalpy</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Knudsen effusion</subject><subject>Physical Chemistry</subject><subject>Pyridines</subject><subject>Spectrum analysis</subject><subject>Sublimation</subject><subject>Vapor phases</subject><subject>Vaporization</subject><subject>X-ray diffraction</subject><subject>Zinc</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kE1Lw0AYhBdRsFZ_gLeAlxYa3e9NvEmwVii00HqpSNhsNja13dTdzSH-erdU8CCe3oF5Zl4YAK4RvEWI0LsFggISnFCMEYSQiBPQQxwmMSEoOQ062PHBPwcXzm0gDBRLe-BjVRsVzbXxstq2jW0Kbb4a6XX0ujJ4MMGz4SDjY5bNZkM6mHdD-nYfLTrj19rVbhQtvG2Vb60eRdKU0XKt7a4pOyN3tYqytbRSeW1r52vlLsFZJbdOX_3cPngZPy6zSTydPT1nD9NYEcR9TDVGiJecQVUoBgVLCpYSWqWU8kJhkrACM044JExyiiueFkhUSlEqiCxxSvrg5ti7t81nq53PN01rTXiZY4EEIWELESh0pJRtnLO6yve23knb5Qjmh03zP5uGDD5mXGDNu7a_zf-HvgFwr3Vo</recordid><startdate>20221001</startdate><enddate>20221001</enddate><creator>Malkerova, I. P.</creator><creator>Kayumova, D. B.</creator><creator>Belova, E. V.</creator><creator>Shmelev, M. A.</creator><creator>Sidorov, A. A.</creator><creator>Alikhanyan, A. S.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20221001</creationdate><title>Zinc Pentafluorobenzoate [Zn2(H2O)(C6F5COO)4(Py)4]: Synthesis, Structure, and Thermodynamic Characteristics</title><author>Malkerova, I. P. ; Kayumova, D. B. ; Belova, E. V. ; Shmelev, M. A. ; Sidorov, A. A. ; Alikhanyan, A. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-4e2116d650cbc50758b5934f9446bc2385b25636035a642f69b17fcc4473ad293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemical analysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Enthalpy</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Knudsen effusion</topic><topic>Physical Chemistry</topic><topic>Pyridines</topic><topic>Spectrum analysis</topic><topic>Sublimation</topic><topic>Vapor phases</topic><topic>Vaporization</topic><topic>X-ray diffraction</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Malkerova, I. P.</creatorcontrib><creatorcontrib>Kayumova, D. B.</creatorcontrib><creatorcontrib>Belova, E. V.</creatorcontrib><creatorcontrib>Shmelev, M. A.</creatorcontrib><creatorcontrib>Sidorov, A. A.</creatorcontrib><creatorcontrib>Alikhanyan, A. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Malkerova, I. P.</au><au>Kayumova, D. B.</au><au>Belova, E. V.</au><au>Shmelev, M. A.</au><au>Sidorov, A. A.</au><au>Alikhanyan, A. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zinc Pentafluorobenzoate [Zn2(H2O)(C6F5COO)4(Py)4]: Synthesis, Structure, and Thermodynamic Characteristics</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2022-10-01</date><risdate>2022</risdate><volume>48</volume><issue>10</issue><spage>608</spage><epage>614</epage><pages>608-614</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>The reaction of zinc pentafluorobenzoate [Zn(H
2
O)(C
6
F
5
COO)
2
]
n
with a pyridine excess (Py, ratio Zn : Py = 1 : 4) affords crystals of complex [Zn
2
(H
2
O)(C
6
F
5
COO)
4
(Py)
4
] (
I
). The crystal packing of complex
I
is stabilized by numerous intra- and intermolecular interactions π…π, O…H, F…π, C–H…F, and С–H…O. The compound is characterized by the data of X-ray diffraction (XRD) (CIF file ССDС no. 2157445), IR spectroscopy, C,H,N elemental analysis, and phase XRD analysis. The vaporization of [Zn
2
(H
2
O)(C
6
F
5
COO)
4
(Py)
4
] is studied by the Knudsen effusion method with mass spectral analysis of the gas phase. This process is found to proceed in three stages with the consecutive transition of pyridine molecules to the vapor, partial hydrolysis, and congruent sublimation of zinc pentafluorobenzoate to form free molecules of Zn(C
6
F
5
)
2
and СО
2
. The absolute partial pressures of saturated vapor and standard enthalpies of formation are calculated:
(Zn(C
6
F
5
COO)
2
, s) ≤ –2634.1 ± 32.2 kJ/mol and
(Zn(С
6
F
5
)
2
, g) ≤ –1422.6 ± 31.3 kJ/mol.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328422100037</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1070-3284 |
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| issn | 1070-3284 1608-3318 |
| language | eng |
| recordid | cdi_proquest_journals_2717330707 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Chemical analysis Chemistry Chemistry and Materials Science Enthalpy Infrared spectroscopy Inorganic Chemistry Knudsen effusion Physical Chemistry Pyridines Spectrum analysis Sublimation Vapor phases Vaporization X-ray diffraction Zinc |
| title | Zinc Pentafluorobenzoate [Zn2(H2O)(C6F5COO)4(Py)4]: Synthesis, Structure, and Thermodynamic Characteristics |
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