Hydrolytic polycondensation of diethoxymethylsilane under pressure
The process of hydrolytic polycondensation of diethoxymethylsilane in water under pressure was investigated without the use of organic solvents in non-catalytic conditions and in carbonic acid. It is demonstrated that in both cases the process of the formation of methylsiloxane polymers proceeds wit...
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| Veröffentlicht in: | Russian chemical bulletin 2022-08, Vol.71 (8), p.1648-1655 |
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| container_title | Russian chemical bulletin |
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| creator | Kalinina, A. A. Pryakhina, T. A. Talalaeva, E. V. Vasilenko, N. G. Pigaleva, M. A. Elmanovich, I. V. Gallyamov, M. O. Muzafarov, A. M. |
| description | The process of hydrolytic polycondensation of diethoxymethylsilane in water under pressure was investigated without the use of organic solvents in non-catalytic conditions and in carbonic acid. It is demonstrated that in both cases the process of the formation of methylsiloxane polymers proceeds with 100% conversion of the monomer and complete preservation of hydrosilyl groups. The conditions for the selective production of linear products were found. |
| doi_str_mv | 10.1007/s11172-022-3574-3 |
| format | Article |
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| subjects | Carbonic acid Chemistry Chemistry and Materials Science Chemistry/Food Science Full Articles Inorganic Chemistry Organic Chemistry |
| title | Hydrolytic polycondensation of diethoxymethylsilane under pressure |
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