Growth mechanism of silver dendrites on porous silicon by single-step electrochemical synthesis method
Silver micro/nanostructures are often used to enhance surface-enhanced Raman scattering (SERS) due their hotspot effect. In this paper, a single-step electrochemical etching method was used to prepare silver dendrites with stems, branches and leaf morphology on porous silicon. A detailed analysis of...
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container_title | Applied physics. A, Materials science & processing |
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creator | Ge, Daohan Yao, Jun Ding, Jie Babangida, Abubakar A. Zhu, Chenxi Ni, Chao Zhao, Chengxiang Qian, Pengfei Zhang, Liqiang |
description | Silver micro/nanostructures are often used to enhance surface-enhanced Raman scattering (SERS) due their hotspot effect. In this paper, a single-step electrochemical etching method was used to prepare silver dendrites with stems, branches and leaf morphology on porous silicon. A detailed analysis of the evolution and growth mechanism of the silver dendrites on the porous silicon was conducted, based on diffusion-limited aggregation, the anisotropy associated with the solid–liquid interface energy, and taking into account different growth rates. The SERS efficiency of the analyte molecule Rhodamine 6G was evaluated, achieving a low detection limit of up to 10
–11
M concentration. The linear relationship between Rhodamine 6G concentration and Raman peak intensity is good within the concentration range of 10
–4
–10
–11
M, and the linear fitting equation is
y
= − 4479.4 x + 41,952.9 (
R
2
= 0.9815). Therefore, the results indicate that different silver dendrites can be prepared by controlling the time, which is beneficial for the design of silver dendrite-based composites with high SERS performance. |
doi_str_mv | 10.1007/s00339-022-06054-2 |
format | Article |
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–11
M concentration. The linear relationship between Rhodamine 6G concentration and Raman peak intensity is good within the concentration range of 10
–4
–10
–11
M, and the linear fitting equation is
y
= − 4479.4 x + 41,952.9 (
R
2
= 0.9815). Therefore, the results indicate that different silver dendrites can be prepared by controlling the time, which is beneficial for the design of silver dendrite-based composites with high SERS performance.</description><identifier>ISSN: 0947-8396</identifier><identifier>EISSN: 1432-0630</identifier><identifier>DOI: 10.1007/s00339-022-06054-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Anisotropy ; Applied physics ; Characterization and Evaluation of Materials ; Chemical synthesis ; Condensed Matter Physics ; Dendritic structure ; Electrochemical etching ; Liquid-solid interfaces ; Machines ; Manufacturing ; Materials science ; Nanotechnology ; Optical and Electronic Materials ; Physics ; Physics and Astronomy ; Porous silicon ; Processes ; Raman spectra ; Rhodamine 6G ; Surfaces and Interfaces ; Thin Films</subject><ispartof>Applied physics. A, Materials science & processing, 2022-10, Vol.128 (10), Article 908</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-55bf88181e0fc4c588b9ba4a3dfdea12c329062ffd5f64845cefd7baf9a1dbd73</citedby><cites>FETCH-LOGICAL-c319t-55bf88181e0fc4c588b9ba4a3dfdea12c329062ffd5f64845cefd7baf9a1dbd73</cites><orcidid>0000-0002-5722-8298</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00339-022-06054-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00339-022-06054-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Ge, Daohan</creatorcontrib><creatorcontrib>Yao, Jun</creatorcontrib><creatorcontrib>Ding, Jie</creatorcontrib><creatorcontrib>Babangida, Abubakar A.</creatorcontrib><creatorcontrib>Zhu, Chenxi</creatorcontrib><creatorcontrib>Ni, Chao</creatorcontrib><creatorcontrib>Zhao, Chengxiang</creatorcontrib><creatorcontrib>Qian, Pengfei</creatorcontrib><creatorcontrib>Zhang, Liqiang</creatorcontrib><title>Growth mechanism of silver dendrites on porous silicon by single-step electrochemical synthesis method</title><title>Applied physics. A, Materials science & processing</title><addtitle>Appl. Phys. A</addtitle><description>Silver micro/nanostructures are often used to enhance surface-enhanced Raman scattering (SERS) due their hotspot effect. In this paper, a single-step electrochemical etching method was used to prepare silver dendrites with stems, branches and leaf morphology on porous silicon. A detailed analysis of the evolution and growth mechanism of the silver dendrites on the porous silicon was conducted, based on diffusion-limited aggregation, the anisotropy associated with the solid–liquid interface energy, and taking into account different growth rates. The SERS efficiency of the analyte molecule Rhodamine 6G was evaluated, achieving a low detection limit of up to 10
–11
M concentration. The linear relationship between Rhodamine 6G concentration and Raman peak intensity is good within the concentration range of 10
–4
–10
–11
M, and the linear fitting equation is
y
= − 4479.4 x + 41,952.9 (
R
2
= 0.9815). Therefore, the results indicate that different silver dendrites can be prepared by controlling the time, which is beneficial for the design of silver dendrite-based composites with high SERS performance.</description><subject>Anisotropy</subject><subject>Applied physics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical synthesis</subject><subject>Condensed Matter Physics</subject><subject>Dendritic structure</subject><subject>Electrochemical etching</subject><subject>Liquid-solid interfaces</subject><subject>Machines</subject><subject>Manufacturing</subject><subject>Materials science</subject><subject>Nanotechnology</subject><subject>Optical and Electronic Materials</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Porous silicon</subject><subject>Processes</subject><subject>Raman spectra</subject><subject>Rhodamine 6G</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><issn>0947-8396</issn><issn>1432-0630</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWD_-gKeA52i-9iNHKVqFghc9h2wy6W7Z3azJVum_N7WCN-cyM8z7vgMPQjeM3jFKq_tEqRCKUM4JLWkhCT9BCybFYRX0FC2okhWphSrP0UVKW5pLcr5AfhXD19ziAWxrxi4NOHicuv4TInYwutjNkHAY8RRi2KXDqbN5bfZ5HDc9kDTDhKEHO8dgWxg6a3qc9uPcQupSDp7b4K7QmTd9guvffonenx7fls9k_bp6WT6siRVMzaQoGl_XrGZAvZW2qOtGNUYa4bwDw7gVXNGSe-8KX8paFha8qxrjlWGucZW4RLfH3CmGjx2kWW_DLo75peYVK1WluCyzih9VNoaUIng9xW4wca8Z1Qee-shTZ576h6fm2SSOppTF4wbiX_Q_rm__jntu</recordid><startdate>20221001</startdate><enddate>20221001</enddate><creator>Ge, Daohan</creator><creator>Yao, Jun</creator><creator>Ding, Jie</creator><creator>Babangida, Abubakar A.</creator><creator>Zhu, Chenxi</creator><creator>Ni, Chao</creator><creator>Zhao, Chengxiang</creator><creator>Qian, Pengfei</creator><creator>Zhang, Liqiang</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-5722-8298</orcidid></search><sort><creationdate>20221001</creationdate><title>Growth mechanism of silver dendrites on porous silicon by single-step electrochemical synthesis method</title><author>Ge, Daohan ; Yao, Jun ; Ding, Jie ; Babangida, Abubakar A. ; Zhu, Chenxi ; Ni, Chao ; Zhao, Chengxiang ; Qian, Pengfei ; Zhang, Liqiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-55bf88181e0fc4c588b9ba4a3dfdea12c329062ffd5f64845cefd7baf9a1dbd73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Anisotropy</topic><topic>Applied physics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical synthesis</topic><topic>Condensed Matter Physics</topic><topic>Dendritic structure</topic><topic>Electrochemical etching</topic><topic>Liquid-solid interfaces</topic><topic>Machines</topic><topic>Manufacturing</topic><topic>Materials science</topic><topic>Nanotechnology</topic><topic>Optical and Electronic Materials</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Porous silicon</topic><topic>Processes</topic><topic>Raman spectra</topic><topic>Rhodamine 6G</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ge, Daohan</creatorcontrib><creatorcontrib>Yao, Jun</creatorcontrib><creatorcontrib>Ding, Jie</creatorcontrib><creatorcontrib>Babangida, Abubakar A.</creatorcontrib><creatorcontrib>Zhu, Chenxi</creatorcontrib><creatorcontrib>Ni, Chao</creatorcontrib><creatorcontrib>Zhao, Chengxiang</creatorcontrib><creatorcontrib>Qian, Pengfei</creatorcontrib><creatorcontrib>Zhang, Liqiang</creatorcontrib><collection>CrossRef</collection><jtitle>Applied physics. A, Materials science & processing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ge, Daohan</au><au>Yao, Jun</au><au>Ding, Jie</au><au>Babangida, Abubakar A.</au><au>Zhu, Chenxi</au><au>Ni, Chao</au><au>Zhao, Chengxiang</au><au>Qian, Pengfei</au><au>Zhang, Liqiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Growth mechanism of silver dendrites on porous silicon by single-step electrochemical synthesis method</atitle><jtitle>Applied physics. A, Materials science & processing</jtitle><stitle>Appl. Phys. A</stitle><date>2022-10-01</date><risdate>2022</risdate><volume>128</volume><issue>10</issue><artnum>908</artnum><issn>0947-8396</issn><eissn>1432-0630</eissn><abstract>Silver micro/nanostructures are often used to enhance surface-enhanced Raman scattering (SERS) due their hotspot effect. In this paper, a single-step electrochemical etching method was used to prepare silver dendrites with stems, branches and leaf morphology on porous silicon. A detailed analysis of the evolution and growth mechanism of the silver dendrites on the porous silicon was conducted, based on diffusion-limited aggregation, the anisotropy associated with the solid–liquid interface energy, and taking into account different growth rates. The SERS efficiency of the analyte molecule Rhodamine 6G was evaluated, achieving a low detection limit of up to 10
–11
M concentration. The linear relationship between Rhodamine 6G concentration and Raman peak intensity is good within the concentration range of 10
–4
–10
–11
M, and the linear fitting equation is
y
= − 4479.4 x + 41,952.9 (
R
2
= 0.9815). Therefore, the results indicate that different silver dendrites can be prepared by controlling the time, which is beneficial for the design of silver dendrite-based composites with high SERS performance.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00339-022-06054-2</doi><orcidid>https://orcid.org/0000-0002-5722-8298</orcidid></addata></record> |
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subjects | Anisotropy Applied physics Characterization and Evaluation of Materials Chemical synthesis Condensed Matter Physics Dendritic structure Electrochemical etching Liquid-solid interfaces Machines Manufacturing Materials science Nanotechnology Optical and Electronic Materials Physics Physics and Astronomy Porous silicon Processes Raman spectra Rhodamine 6G Surfaces and Interfaces Thin Films |
title | Growth mechanism of silver dendrites on porous silicon by single-step electrochemical synthesis method |
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