Effect of conducting polymer incorporated heterostructure morphology of MgCo2O4@PPy nanosheets: a novel cathode material for asymmetric supercapacitor applications
In this study,the facile hydrothermal synthesis of Magnesium–cobalttite MgCo 2 O 4 spinel with different morphologies, such as nanosheets and nanospheres has been investigated. The structural, morphological, textural, and chemical composition of the materials were examined using powdered X-ray diffr...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2022-09, Vol.33 (27), p.21600-21614 |
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| creator | Sathishkumar, S. Karthik, M. Boopathiraja, R. Parthibavarman, M. Nirmaladevi, S. Sathishkumar, S. |
| description | In this study,the facile hydrothermal synthesis of Magnesium–cobalttite MgCo
2
O
4
spinel with different morphologies, such as nanosheets and nanospheres has been investigated. The structural, morphological, textural, and chemical composition of the materials were examined using powdered X-ray diffraction (XRD), scanning electron microscopy (SEM), Transition electron mictroscopy (TEM), N
2
adsorption–desorption isotherm and X-ray photoelectron spectroscopy (XPS). The produced materials have heterostructure morphology with a nanospherical surface-coated nanosheet-like morphology that is clearly visible in the results of FESEM and TEM. The results of N2 adsorption–desorption reveal that MgCo
2
O
4
@PPy has a larger specific area of 103 m
2
g
−1
than MgCo
2
O
4
, which has a specific area of 73 m
2
g
−1
. The synthesized electrode material with inventive nanoarchitectures showed attractive electrochemical performance in a variety of applications. The heterostructure MgCo
2
O
4
@Ppy electrode produced an impressive capacitive retention of 93% at current density 5 Ag
−1
and a high specific capacitacne of 988 Fg
−1
after 10,000 cycles. The assembled ASC cell MgCo
2
O
4
@Ppy//AC provided remarkable high capacitance retention of 84% after 10,000 cycles at 5 Ag
−1
, intensely high energy density of 40 Whkg
−1
, and power density of 1544 Wkg
−1
. |
| doi_str_mv | 10.1007/s10854-022-08949-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2715907388</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2715907388</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-7ee833ba906baf473afeb0b2f91d573c6eb7fc89155a771a922ca563dd1542db3</originalsourceid><addsrcrecordid>eNp9kc1q3DAUhUVJoJOkL9CVIGs3-rFGVlcpQ9oUUjKLBLoTsnw148GWXEku-HnyotF0CtlldRfnfOfCOQh9puQLJUTeJEoaUVeEsYo0qlaV-IBWVEhe1Q37fYZWRAlZ1YKxj-gipQMhZF3zZoVe7pwDm3Fw2AbfzTb3foenMCwjRNx7G-IUosnQ4T1kiCHlWExzBDwWaR-GsFuO9K_dJrDH-na7XbA3PqQ9QE5fscE-_IUBW5P3oStUyYq9GbALEZu0jCPk2Fuc5gmiNZOxfT4q0zT0hemDT1fo3Jkhwaf_9xI9f7972txXD48_fm6-PVSWU5UrCdBw3hpF1q1xteTGQUta5hTtShN2Da10tlFUCCMlNYoxa8Sadx0VNetafomuT7lTDH9mSFkfwhx9eamZpEIRyZumuNjJZUsZKYLTU-xHExdNiT6OoU9j6DKG_jeGFgXiJygVs99BfIt-h3oFthGSSQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2715907388</pqid></control><display><type>article</type><title>Effect of conducting polymer incorporated heterostructure morphology of MgCo2O4@PPy nanosheets: a novel cathode material for asymmetric supercapacitor applications</title><source>Springer Nature - Complete Springer Journals</source><creator>Sathishkumar, S. ; Karthik, M. ; Boopathiraja, R. ; Parthibavarman, M. ; Nirmaladevi, S. ; Sathishkumar, S.</creator><creatorcontrib>Sathishkumar, S. ; Karthik, M. ; Boopathiraja, R. ; Parthibavarman, M. ; Nirmaladevi, S. ; Sathishkumar, S.</creatorcontrib><description>In this study,the facile hydrothermal synthesis of Magnesium–cobalttite MgCo
2
O
4
spinel with different morphologies, such as nanosheets and nanospheres has been investigated. The structural, morphological, textural, and chemical composition of the materials were examined using powdered X-ray diffraction (XRD), scanning electron microscopy (SEM), Transition electron mictroscopy (TEM), N
2
adsorption–desorption isotherm and X-ray photoelectron spectroscopy (XPS). The produced materials have heterostructure morphology with a nanospherical surface-coated nanosheet-like morphology that is clearly visible in the results of FESEM and TEM. The results of N2 adsorption–desorption reveal that MgCo
2
O
4
@PPy has a larger specific area of 103 m
2
g
−1
than MgCo
2
O
4
, which has a specific area of 73 m
2
g
−1
. The synthesized electrode material with inventive nanoarchitectures showed attractive electrochemical performance in a variety of applications. The heterostructure MgCo
2
O
4
@Ppy electrode produced an impressive capacitive retention of 93% at current density 5 Ag
−1
and a high specific capacitacne of 988 Fg
−1
after 10,000 cycles. The assembled ASC cell MgCo
2
O
4
@Ppy//AC provided remarkable high capacitance retention of 84% after 10,000 cycles at 5 Ag
−1
, intensely high energy density of 40 Whkg
−1
, and power density of 1544 Wkg
−1
.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-022-08949-5</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorption ; Characterization and Evaluation of Materials ; Chemical composition ; Chemistry and Materials Science ; Conducting polymers ; Desorption ; Electrochemical analysis ; Electrode materials ; Electrodes ; Heterostructures ; Magnesium ; Materials Science ; Morphology ; Nanosheets ; Nanospheres ; Optical and Electronic Materials ; Photoelectrons ; Transmission electron microscopy ; X ray photoelectron spectroscopy</subject><ispartof>Journal of materials science. Materials in electronics, 2022-09, Vol.33 (27), p.21600-21614</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-7ee833ba906baf473afeb0b2f91d573c6eb7fc89155a771a922ca563dd1542db3</citedby><cites>FETCH-LOGICAL-c319t-7ee833ba906baf473afeb0b2f91d573c6eb7fc89155a771a922ca563dd1542db3</cites><orcidid>0000-0002-5802-1504</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-022-08949-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-022-08949-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Sathishkumar, S.</creatorcontrib><creatorcontrib>Karthik, M.</creatorcontrib><creatorcontrib>Boopathiraja, R.</creatorcontrib><creatorcontrib>Parthibavarman, M.</creatorcontrib><creatorcontrib>Nirmaladevi, S.</creatorcontrib><creatorcontrib>Sathishkumar, S.</creatorcontrib><title>Effect of conducting polymer incorporated heterostructure morphology of MgCo2O4@PPy nanosheets: a novel cathode material for asymmetric supercapacitor applications</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>In this study,the facile hydrothermal synthesis of Magnesium–cobalttite MgCo
2
O
4
spinel with different morphologies, such as nanosheets and nanospheres has been investigated. The structural, morphological, textural, and chemical composition of the materials were examined using powdered X-ray diffraction (XRD), scanning electron microscopy (SEM), Transition electron mictroscopy (TEM), N
2
adsorption–desorption isotherm and X-ray photoelectron spectroscopy (XPS). The produced materials have heterostructure morphology with a nanospherical surface-coated nanosheet-like morphology that is clearly visible in the results of FESEM and TEM. The results of N2 adsorption–desorption reveal that MgCo
2
O
4
@PPy has a larger specific area of 103 m
2
g
−1
than MgCo
2
O
4
, which has a specific area of 73 m
2
g
−1
. The synthesized electrode material with inventive nanoarchitectures showed attractive electrochemical performance in a variety of applications. The heterostructure MgCo
2
O
4
@Ppy electrode produced an impressive capacitive retention of 93% at current density 5 Ag
−1
and a high specific capacitacne of 988 Fg
−1
after 10,000 cycles. The assembled ASC cell MgCo
2
O
4
@Ppy//AC provided remarkable high capacitance retention of 84% after 10,000 cycles at 5 Ag
−1
, intensely high energy density of 40 Whkg
−1
, and power density of 1544 Wkg
−1
.</description><subject>Adsorption</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical composition</subject><subject>Chemistry and Materials Science</subject><subject>Conducting polymers</subject><subject>Desorption</subject><subject>Electrochemical analysis</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Heterostructures</subject><subject>Magnesium</subject><subject>Materials Science</subject><subject>Morphology</subject><subject>Nanosheets</subject><subject>Nanospheres</subject><subject>Optical and Electronic Materials</subject><subject>Photoelectrons</subject><subject>Transmission electron microscopy</subject><subject>X ray photoelectron spectroscopy</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kc1q3DAUhUVJoJOkL9CVIGs3-rFGVlcpQ9oUUjKLBLoTsnw148GWXEku-HnyotF0CtlldRfnfOfCOQh9puQLJUTeJEoaUVeEsYo0qlaV-IBWVEhe1Q37fYZWRAlZ1YKxj-gipQMhZF3zZoVe7pwDm3Fw2AbfzTb3foenMCwjRNx7G-IUosnQ4T1kiCHlWExzBDwWaR-GsFuO9K_dJrDH-na7XbA3PqQ9QE5fscE-_IUBW5P3oStUyYq9GbALEZu0jCPk2Fuc5gmiNZOxfT4q0zT0hemDT1fo3Jkhwaf_9xI9f7972txXD48_fm6-PVSWU5UrCdBw3hpF1q1xteTGQUta5hTtShN2Da10tlFUCCMlNYoxa8Sadx0VNetafomuT7lTDH9mSFkfwhx9eamZpEIRyZumuNjJZUsZKYLTU-xHExdNiT6OoU9j6DKG_jeGFgXiJygVs99BfIt-h3oFthGSSQ</recordid><startdate>20220901</startdate><enddate>20220901</enddate><creator>Sathishkumar, S.</creator><creator>Karthik, M.</creator><creator>Boopathiraja, R.</creator><creator>Parthibavarman, M.</creator><creator>Nirmaladevi, S.</creator><creator>Sathishkumar, S.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>S0W</scope><orcidid>https://orcid.org/0000-0002-5802-1504</orcidid></search><sort><creationdate>20220901</creationdate><title>Effect of conducting polymer incorporated heterostructure morphology of MgCo2O4@PPy nanosheets: a novel cathode material for asymmetric supercapacitor applications</title><author>Sathishkumar, S. ; Karthik, M. ; Boopathiraja, R. ; Parthibavarman, M. ; Nirmaladevi, S. ; Sathishkumar, S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-7ee833ba906baf473afeb0b2f91d573c6eb7fc89155a771a922ca563dd1542db3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Adsorption</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical composition</topic><topic>Chemistry and Materials Science</topic><topic>Conducting polymers</topic><topic>Desorption</topic><topic>Electrochemical analysis</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Heterostructures</topic><topic>Magnesium</topic><topic>Materials Science</topic><topic>Morphology</topic><topic>Nanosheets</topic><topic>Nanospheres</topic><topic>Optical and Electronic Materials</topic><topic>Photoelectrons</topic><topic>Transmission electron microscopy</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sathishkumar, S.</creatorcontrib><creatorcontrib>Karthik, M.</creatorcontrib><creatorcontrib>Boopathiraja, R.</creatorcontrib><creatorcontrib>Parthibavarman, M.</creatorcontrib><creatorcontrib>Nirmaladevi, S.</creatorcontrib><creatorcontrib>Sathishkumar, S.</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sathishkumar, S.</au><au>Karthik, M.</au><au>Boopathiraja, R.</au><au>Parthibavarman, M.</au><au>Nirmaladevi, S.</au><au>Sathishkumar, S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of conducting polymer incorporated heterostructure morphology of MgCo2O4@PPy nanosheets: a novel cathode material for asymmetric supercapacitor applications</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2022-09-01</date><risdate>2022</risdate><volume>33</volume><issue>27</issue><spage>21600</spage><epage>21614</epage><pages>21600-21614</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>In this study,the facile hydrothermal synthesis of Magnesium–cobalttite MgCo
2
O
4
spinel with different morphologies, such as nanosheets and nanospheres has been investigated. The structural, morphological, textural, and chemical composition of the materials were examined using powdered X-ray diffraction (XRD), scanning electron microscopy (SEM), Transition electron mictroscopy (TEM), N
2
adsorption–desorption isotherm and X-ray photoelectron spectroscopy (XPS). The produced materials have heterostructure morphology with a nanospherical surface-coated nanosheet-like morphology that is clearly visible in the results of FESEM and TEM. The results of N2 adsorption–desorption reveal that MgCo
2
O
4
@PPy has a larger specific area of 103 m
2
g
−1
than MgCo
2
O
4
, which has a specific area of 73 m
2
g
−1
. The synthesized electrode material with inventive nanoarchitectures showed attractive electrochemical performance in a variety of applications. The heterostructure MgCo
2
O
4
@Ppy electrode produced an impressive capacitive retention of 93% at current density 5 Ag
−1
and a high specific capacitacne of 988 Fg
−1
after 10,000 cycles. The assembled ASC cell MgCo
2
O
4
@Ppy//AC provided remarkable high capacitance retention of 84% after 10,000 cycles at 5 Ag
−1
, intensely high energy density of 40 Whkg
−1
, and power density of 1544 Wkg
−1
.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-022-08949-5</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0002-5802-1504</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0957-4522 |
| ispartof | Journal of materials science. Materials in electronics, 2022-09, Vol.33 (27), p.21600-21614 |
| issn | 0957-4522 1573-482X |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Adsorption Characterization and Evaluation of Materials Chemical composition Chemistry and Materials Science Conducting polymers Desorption Electrochemical analysis Electrode materials Electrodes Heterostructures Magnesium Materials Science Morphology Nanosheets Nanospheres Optical and Electronic Materials Photoelectrons Transmission electron microscopy X ray photoelectron spectroscopy |
| title | Effect of conducting polymer incorporated heterostructure morphology of MgCo2O4@PPy nanosheets: a novel cathode material for asymmetric supercapacitor applications |
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