Graphene reinforced hybrid-bioceramic coatings on porous-Ti6Al4V for biomedical applications: morphology, corrosion resistance, and cell viability
The effect of Hydroxyapatite (HA)-based coatings reinforced with reduced graphene oxide (rGO) on porous-Ti6Al4V (P-Ti6Al4V) alloys in terms of electrochemical corrosion and cell viability for potential biomedical applications was investigated in this study. The scaffold-porous surfaces of P-Ti6Al4V...
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Veröffentlicht in: | Journal of materials science 2022-09, Vol.57 (35), p.16858-16874 |
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description | The effect of Hydroxyapatite (HA)-based coatings reinforced with reduced graphene oxide (rGO) on porous-Ti6Al4V (P-Ti6Al4V) alloys in terms of electrochemical corrosion and cell viability for potential biomedical applications was investigated in this study. The scaffold-porous surfaces of P-Ti6Al4V were coated by the biocomposite structure of HA and reduced graphene oxide (rGO) at various porosity rates (40, 50, and 60%) by using the sol–gel dip-coating method. The results of 0.5, 1.0, and 1.5 wt% rGO-HA coatings were compared to coatings that contained only HA (free-rGO). Raman spectroscopy, X-ray diffractometer, and scanning electron microscopy were used for structural and morphological characterizations. The coatings in vitro corrosion susceptibilities were tested in simulated body fluid at 37 °C. Compared to free-rGO coatings, the results showed that rGO reinforcements phases reduced the corrosion rate of the scaffolds. The corrosion rate increased as the porosity content of the scaffolds increased. In vitro cell viability tests revealed that samples of 0.5 and 1.0 wt% rGO-HA coating groups performed better than the control and 1.5 wt% rGO-HA samples.
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doi_str_mv | 10.1007/s10853-022-07695-7 |
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Graphical abstract</description><subject>Alloys</subject><subject>Bioceramics</subject><subject>Biomedical materials</subject><subject>Body fluids</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Composite materials</subject><subject>Corrosion</subject><subject>Corrosion and anti-corrosives</subject><subject>Corrosion cell</subject><subject>Corrosion effects</subject><subject>Corrosion rate</subject><subject>Corrosion resistance</subject><subject>Corrosion tests</subject><subject>Crystallography and Scattering Methods</subject><subject>Dip coatings</subject><subject>Electrochemical corrosion</subject><subject>Graphene</subject><subject>Graphite</subject><subject>Hydroxyapatite</subject><subject>Immersion coating</subject><subject>In vitro methods and tests</subject><subject>Materials for Life Sciences</subject><subject>Materials Science</subject><subject>Morphology</subject><subject>Polymer Sciences</subject><subject>Porosity</subject><subject>Raman spectroscopy</subject><subject>Scaffolds</subject><subject>Sol-gel processes</subject><subject>Solid Mechanics</subject><subject>Surgical implants</subject><subject>Technology application</subject><subject>Titanium base alloys</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kd9qFDEUxoMouFZfwKuAV0JTk8yfZLxbiraFgqDV25DJnJlNySZjMlvc1_CJe9YRpDeSi4ST33fO4fsIeSv4heBcfSiC66ZiXErGVds1TD0jG9GoitWaV8_Jhp--ZN2Kl-RVKfec80ZJsSG_r7KddxCBZvBxTNnBQHfHPvuB9T45yHbvHXXJLj5OhaZI55TTobA7325D_YOihiK5h8E7G6id54CPxadYPtJ9yvMuhTQdz7FHzqlgHUcVXxYbHZxTGwfqIAT64G3vg1-Or8mL0YYCb_7eZ-T75093l9fs9svVzeX2lrlKyoUJJZ3t1SB0I6txAO60rNTQdU73mvetrKDTvOFaNkMLoxh7Vbeyw6LqhR6b6oy8W_vOOf08QFnMfTrkiCONVKIRrZK1ROpipSYbwJwsWrJ1eAZAY1KE0WN9q4TmnRayQ8H7JwJkFvi1TPZQirn59vUpK1fWoTMlw2jm7Pc2H43g5hSsWYM1mJ75E6xRKKpWUUE4TpD_7f0f1SP0fKc5</recordid><startdate>20220901</startdate><enddate>20220901</enddate><creator>Aslan, N.</creator><creator>Aksakal, B.</creator><creator>Dikici, B.</creator><creator>Sinirlioglu, Z. 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A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Graphene reinforced hybrid-bioceramic coatings on porous-Ti6Al4V for biomedical applications: morphology, corrosion resistance, and cell viability</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2022-09-01</date><risdate>2022</risdate><volume>57</volume><issue>35</issue><spage>16858</spage><epage>16874</epage><pages>16858-16874</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>The effect of Hydroxyapatite (HA)-based coatings reinforced with reduced graphene oxide (rGO) on porous-Ti6Al4V (P-Ti6Al4V) alloys in terms of electrochemical corrosion and cell viability for potential biomedical applications was investigated in this study. The scaffold-porous surfaces of P-Ti6Al4V were coated by the biocomposite structure of HA and reduced graphene oxide (rGO) at various porosity rates (40, 50, and 60%) by using the sol–gel dip-coating method. The results of 0.5, 1.0, and 1.5 wt% rGO-HA coatings were compared to coatings that contained only HA (free-rGO). Raman spectroscopy, X-ray diffractometer, and scanning electron microscopy were used for structural and morphological characterizations. The coatings in vitro corrosion susceptibilities were tested in simulated body fluid at 37 °C. Compared to free-rGO coatings, the results showed that rGO reinforcements phases reduced the corrosion rate of the scaffolds. The corrosion rate increased as the porosity content of the scaffolds increased. In vitro cell viability tests revealed that samples of 0.5 and 1.0 wt% rGO-HA coating groups performed better than the control and 1.5 wt% rGO-HA samples.
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subjects | Alloys Bioceramics Biomedical materials Body fluids Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Composite materials Corrosion Corrosion and anti-corrosives Corrosion cell Corrosion effects Corrosion rate Corrosion resistance Corrosion tests Crystallography and Scattering Methods Dip coatings Electrochemical corrosion Graphene Graphite Hydroxyapatite Immersion coating In vitro methods and tests Materials for Life Sciences Materials Science Morphology Polymer Sciences Porosity Raman spectroscopy Scaffolds Sol-gel processes Solid Mechanics Surgical implants Technology application Titanium base alloys |
title | Graphene reinforced hybrid-bioceramic coatings on porous-Ti6Al4V for biomedical applications: morphology, corrosion resistance, and cell viability |
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