One‐Step Synthesis of Arylacetaldehydes from Aryl Aldehydes or Diaryl Ketones via One‐Carbon Extension by Using the System of DMSO/KOH/Zinc

A one‐step protocol is described for the synthesis of arylacetaldehydes from aryl aldehydes or diaryl ketones by using the system of DMSO/KOH/zinc. In this transformation, DMSO provides a methine fragment that converts the −CHO structure in aryl aldehydes or the −CO− structure in diaryl ketones to t...

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Veröffentlicht in:	Advanced synthesis & catalysis 2022-09, Vol.364 (17), p.2989-2995
Hauptverfasser:	Nie, Zhiwen, Yang, Tonglin, Su, Miaodong, Luo, Weiping, Liu, Qiang, Guo, Cancheng
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetals Aldehydes Aromatic compounds Aryl aldehydes or Diaryl ketones Arylacetaldehydes Carbon Diols DMSO Ketones KOH One-Carbon Extension Reaction mechanisms Synthesis Zinc
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