Alkane Oxidation with H2O2 Catalyzed by Dicopper Complex with 6-hpa Ligand: Mechanistic Insights as Key Features for Methane Oxidation

Alkane oxidations with H2O2 catalyzed by copper complexes [Cu2(µ-OH)(6-hpa)]3+ (1) and [Cu(MeCN)(tpa)]2+ (2) were examined. In the oxidation of cyclohexane (CyH), cyclohexyl hydroperoxide (CyO2H) was formed as the first product and converted to cyclohexanol (CyOH) with PPh3. The turnover frequency (...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2022-08, Vol.95 (8), p.1148-1155
Hauptverfasser:	Takahashi, Hiroto, Wada, Kazuhito, Tanaka, Kosei, Fujikawa, Kyosuke, Hitomi, Yutaka, Endo, Takatsugu, Kodera, Masahito
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkanes Catalytic activity Copper Copper compounds Cyclohexane Hydrogen bonds Hydrogen peroxide Isotope effect Methane Oxidation Reagents
Online-Zugang:	Volltext
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