AN INVESTIGATION INTO THE IMPACT OF INTRODUCED THIOCYANATE ANIONS ON THE TRINUCLEAR Co(II) SALAMO-BASED COMPLEX
The reaction of Co(OAc) 2 ·4H 2 O with multisite coordinated salamo-based ligand H 2 L containning six coordinating sites in presence of co-ligand NCS – anions afforded successfully a trinuclear Co(II) complex [Co 3 (L) 2 (NCS) 2 ]. The trinuclear Co(II) complex has been characterized by elemental a...
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| Veröffentlicht in: | Journal of structural chemistry 2022-08, Vol.63 (8), p.1262-1273 |
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| container_title | Journal of structural chemistry |
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| creator | Xie, K.-F. Huang, Y. Li, S.-Z. Li, L.-L. Dong, W.-K. |
| description | The reaction of Co(OAc)
2
·4H
2
O with multisite coordinated salamo-based ligand H
2
L containning six coordinating sites in presence of co-ligand NCS
–
anions afforded successfully a trinuclear Co(II) complex [Co
3
(L)
2
(NCS)
2
]. The trinuclear Co(II) complex has been characterized by elemental analyses, UV-Vis, Fourier transform infrared spectroscopic methods and DFT calculation. In addition, the structure of the Co(II) complex has been confirmed by single crystal X-ray crystallography. X-ray crystal structure analysis of the Co(II) complex revealed that the Co(II) complex consists of three Co(II) atoms coordinated by two fully deprotonated ligand (L)
2–
units and co-ligand NCS
–
anions. The close surveillance of the crystal structure of the Co(II) complex discloses some notable non-covalent interactions like H-bonding, C-H⋯π and π⋯π. The luminescent property of the Co(II) complex has been studied in methanol solution. Apart from, as a complementary revelation, intermolecular interactions with respect to percentages of hydrogen bondings in the X-ray crystal structure of the trinuclear Co(II) complex was quantified by analyses of Hirshfeld surfaces and fingerprint plots. |
| doi_str_mv | 10.1134/S0022476622080078 |
| format | Article |
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2
·4H
2
O with multisite coordinated salamo-based ligand H
2
L containning six coordinating sites in presence of co-ligand NCS
–
anions afforded successfully a trinuclear Co(II) complex [Co
3
(L)
2
(NCS)
2
]. The trinuclear Co(II) complex has been characterized by elemental analyses, UV-Vis, Fourier transform infrared spectroscopic methods and DFT calculation. In addition, the structure of the Co(II) complex has been confirmed by single crystal X-ray crystallography. X-ray crystal structure analysis of the Co(II) complex revealed that the Co(II) complex consists of three Co(II) atoms coordinated by two fully deprotonated ligand (L)
2–
units and co-ligand NCS
–
anions. The close surveillance of the crystal structure of the Co(II) complex discloses some notable non-covalent interactions like H-bonding, C-H⋯π and π⋯π. The luminescent property of the Co(II) complex has been studied in methanol solution. Apart from, as a complementary revelation, intermolecular interactions with respect to percentages of hydrogen bondings in the X-ray crystal structure of the trinuclear Co(II) complex was quantified by analyses of Hirshfeld surfaces and fingerprint plots.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476622080078</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anions ; Atomic ; Atomic/Molecular Structure and Spectra ; Chemical bonds ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Crystallography ; Fourier transforms ; Infrared analysis ; Inorganic Chemistry ; Ligands ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Single crystals ; Solid State Physics ; Structural analysis ; Thiocyanates</subject><ispartof>Journal of structural chemistry, 2022-08, Vol.63 (8), p.1262-1273</ispartof><rights>Pleiades Publishing, Ltd. 2022</rights><rights>Pleiades Publishing, Ltd. 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-dc5c39d4847a86ef42cc05021cda7e6c45b19cf3ae7191f5466216b3e02badb43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476622080078$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476622080078$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27931,27932,41495,42564,51326</link.rule.ids></links><search><creatorcontrib>Xie, K.-F.</creatorcontrib><creatorcontrib>Huang, Y.</creatorcontrib><creatorcontrib>Li, S.-Z.</creatorcontrib><creatorcontrib>Li, L.-L.</creatorcontrib><creatorcontrib>Dong, W.-K.</creatorcontrib><title>AN INVESTIGATION INTO THE IMPACT OF INTRODUCED THIOCYANATE ANIONS ON THE TRINUCLEAR Co(II) SALAMO-BASED COMPLEX</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>The reaction of Co(OAc)
2
·4H
2
O with multisite coordinated salamo-based ligand H
2
L containning six coordinating sites in presence of co-ligand NCS
–
anions afforded successfully a trinuclear Co(II) complex [Co
3
(L)
2
(NCS)
2
]. The trinuclear Co(II) complex has been characterized by elemental analyses, UV-Vis, Fourier transform infrared spectroscopic methods and DFT calculation. In addition, the structure of the Co(II) complex has been confirmed by single crystal X-ray crystallography. X-ray crystal structure analysis of the Co(II) complex revealed that the Co(II) complex consists of three Co(II) atoms coordinated by two fully deprotonated ligand (L)
2–
units and co-ligand NCS
–
anions. The close surveillance of the crystal structure of the Co(II) complex discloses some notable non-covalent interactions like H-bonding, C-H⋯π and π⋯π. The luminescent property of the Co(II) complex has been studied in methanol solution. Apart from, as a complementary revelation, intermolecular interactions with respect to percentages of hydrogen bondings in the X-ray crystal structure of the trinuclear Co(II) complex was quantified by analyses of Hirshfeld surfaces and fingerprint plots.</description><subject>Anions</subject><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemical bonds</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Fourier transforms</subject><subject>Infrared analysis</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Single crystals</subject><subject>Solid State Physics</subject><subject>Structural analysis</subject><subject>Thiocyanates</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kEFPgzAUxxujiXP6Abw18aIHtC2FlmNlbGvC6DI6oycCpRgXHRO2g9_ekpl4MJ5e-v6_33vpA-Aao3uMffqQI0QIZWFICOIIMX4CRjhgvscZi07BaIi9IT8HF32_QQhFPApHoBUZlNlTkms5E1qq4aUV1PMEysVSxBqq6dBaqck6TiYukCp-EZnQCRSZ43PonAHXK5mt4zQRKxi3t1LewVykYqG8R5E7MVaLZZo8X4Kzpnzv7dVPHYP1NNHx3EvVTMYi9QwJ-d6rTWD8qKacspKHtqHEGBQggk1dMhsaGlQ4Mo1fWoYj3ATUfRyHlW8Rqcq6ov4Y3Bzn7rr282D7fbFpD93WrSwIQxGilIfEUfhIma7t-842xa57-yi7rwKjYrhr8eeuziFHp3fs9tV2v5P_l74Bg9RvlQ</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>Xie, K.-F.</creator><creator>Huang, Y.</creator><creator>Li, S.-Z.</creator><creator>Li, L.-L.</creator><creator>Dong, W.-K.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220801</creationdate><title>AN INVESTIGATION INTO THE IMPACT OF INTRODUCED THIOCYANATE ANIONS ON THE TRINUCLEAR Co(II) SALAMO-BASED COMPLEX</title><author>Xie, K.-F. ; Huang, Y. ; Li, S.-Z. ; Li, L.-L. ; Dong, W.-K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-dc5c39d4847a86ef42cc05021cda7e6c45b19cf3ae7191f5466216b3e02badb43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Anions</topic><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemical bonds</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Crystallography</topic><topic>Fourier transforms</topic><topic>Infrared analysis</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Single crystals</topic><topic>Solid State Physics</topic><topic>Structural analysis</topic><topic>Thiocyanates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xie, K.-F.</creatorcontrib><creatorcontrib>Huang, Y.</creatorcontrib><creatorcontrib>Li, S.-Z.</creatorcontrib><creatorcontrib>Li, L.-L.</creatorcontrib><creatorcontrib>Dong, W.-K.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xie, K.-F.</au><au>Huang, Y.</au><au>Li, S.-Z.</au><au>Li, L.-L.</au><au>Dong, W.-K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>AN INVESTIGATION INTO THE IMPACT OF INTRODUCED THIOCYANATE ANIONS ON THE TRINUCLEAR Co(II) SALAMO-BASED COMPLEX</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2022-08-01</date><risdate>2022</risdate><volume>63</volume><issue>8</issue><spage>1262</spage><epage>1273</epage><pages>1262-1273</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>The reaction of Co(OAc)
2
·4H
2
O with multisite coordinated salamo-based ligand H
2
L containning six coordinating sites in presence of co-ligand NCS
–
anions afforded successfully a trinuclear Co(II) complex [Co
3
(L)
2
(NCS)
2
]. The trinuclear Co(II) complex has been characterized by elemental analyses, UV-Vis, Fourier transform infrared spectroscopic methods and DFT calculation. In addition, the structure of the Co(II) complex has been confirmed by single crystal X-ray crystallography. X-ray crystal structure analysis of the Co(II) complex revealed that the Co(II) complex consists of three Co(II) atoms coordinated by two fully deprotonated ligand (L)
2–
units and co-ligand NCS
–
anions. The close surveillance of the crystal structure of the Co(II) complex discloses some notable non-covalent interactions like H-bonding, C-H⋯π and π⋯π. The luminescent property of the Co(II) complex has been studied in methanol solution. Apart from, as a complementary revelation, intermolecular interactions with respect to percentages of hydrogen bondings in the X-ray crystal structure of the trinuclear Co(II) complex was quantified by analyses of Hirshfeld surfaces and fingerprint plots.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476622080078</doi><tpages>12</tpages></addata></record> |
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| language | eng |
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| source | SpringerNature Journals |
| subjects | Anions Atomic Atomic/Molecular Structure and Spectra Chemical bonds Chemistry Chemistry and Materials Science Crystal structure Crystallography Fourier transforms Infrared analysis Inorganic Chemistry Ligands Molecular Optical and Plasma Physics Physical Chemistry Single crystals Solid State Physics Structural analysis Thiocyanates |
| title | AN INVESTIGATION INTO THE IMPACT OF INTRODUCED THIOCYANATE ANIONS ON THE TRINUCLEAR Co(II) SALAMO-BASED COMPLEX |
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