Synthesis, Thermal Stability and Magnetic Properties of an Interpenetrated Mn(II) Triazolate Coordination Framework
Coordination frameworks and metal‐organic frameworks built from simple triazole ligands such as 1H‐1,2,3‐triazole (H‐ta) have recently inspired great interest owing to physical phenomena such as electronic conductivity, phase transitions and their magnetic behavior. In line of our endeavors we repor...
Gespeichert in:
| Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 2022-08, Vol.648 (16), p.n/a |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | n/a |
|---|---|
| container_issue | 16 |
| container_start_page | |
| container_title | Zeitschrift für anorganische und allgemeine Chemie (1950) |
| container_volume | 648 |
| creator | Röß‐Ohlenroth, Richard Hirrle, Marcel Kraft, Maryana Kalytta‐Mewes, Andreas Jesche, Anton Krug von Nidda, Hans‐Albrecht Volkmer, Dirk |
| description | Coordination frameworks and metal‐organic frameworks built from simple triazole ligands such as 1H‐1,2,3‐triazole (H‐ta) have recently inspired great interest owing to physical phenomena such as electronic conductivity, phase transitions and their magnetic behavior. In line of our endeavors we report on the solvothermal reaction of MnCl2 ⋅ 4H2O with H‐ta ligand in isopropyl alcohol leading to the the novel CFA‐23 (((propan‐2‐yl)oxidanium)+[Mn6Cl5(ta)8]−; CFA‐23=Coordination Framework Augsburg University‐23) coordination framework. Single‐crystal X‐ray diffraction (SC‐XRD) reveals that it crystallizes in the tetragonal space group P42/nnm (134) exhibiting a two‐fold interpenetrated framework with the topologies of a dia net with point (Schläfli) symbol 66. The thermal stability of this compound was investigated using variable temperature X‐ray powder diffraction and thermogravimetric analysis. The magnetic properties of CFA‐23 differ from a similar non‐interpenetrated literature structure of the composition (H[Mn6(bta)8Cl5] ⋅ (H2O)4) built from 1H‐1,2,3‐benzotriazole, thus, indicating that sterically induced lattice changes might be an adjustment parameter for magnetic properties in such frameworks. |
| doi_str_mv | 10.1002/zaac.202200153 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2706929911</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2706929911</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3573-6a12b5d05af7ae5651866b5bf8bb1188822e1dad650f4e522378e092ba6757ef3</originalsourceid><addsrcrecordid>eNqFkE1Lw0AQhhdRsFavnhe8KJi6u8nm41iC1YCi0HrxEibJxG5Ns3F3S0l_vSkVPXoamPd5Z-Ah5JKzCWdM3O0AyolgQjDGpX9ERlwK7vlRkByTEWNB4Amf-6fkzNoVGxgm5YjYed-6JVplb-liiWYNDZ07KFSjXE-hregzfLToVElfje7QOIWW6nqIaNY6NB0OqQGHA9leZ9kNXRgFO90MK5pqbSrVglO6pTMDa9xq83lOTmpoLF78zDF5m90v0kfv6eUhS6dPXunLyPdC4KKQFZNQR4AylDwOw0IWdVwUnMdxLATyCqpQsjpAKYQfxcgSUUAYyQhrf0yuDnc7o782aF2-0hvTDi9zEbEwEUnC-UBNDlRptLUG67wzag2mzznL92Lzvdj8V-xQSA6FrWqw_4fO36fT9K_7DUvJfUA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2706929911</pqid></control><display><type>article</type><title>Synthesis, Thermal Stability and Magnetic Properties of an Interpenetrated Mn(II) Triazolate Coordination Framework</title><source>Access via Wiley Online Library</source><creator>Röß‐Ohlenroth, Richard ; Hirrle, Marcel ; Kraft, Maryana ; Kalytta‐Mewes, Andreas ; Jesche, Anton ; Krug von Nidda, Hans‐Albrecht ; Volkmer, Dirk</creator><creatorcontrib>Röß‐Ohlenroth, Richard ; Hirrle, Marcel ; Kraft, Maryana ; Kalytta‐Mewes, Andreas ; Jesche, Anton ; Krug von Nidda, Hans‐Albrecht ; Volkmer, Dirk</creatorcontrib><description>Coordination frameworks and metal‐organic frameworks built from simple triazole ligands such as 1H‐1,2,3‐triazole (H‐ta) have recently inspired great interest owing to physical phenomena such as electronic conductivity, phase transitions and their magnetic behavior. In line of our endeavors we report on the solvothermal reaction of MnCl2 ⋅ 4H2O with H‐ta ligand in isopropyl alcohol leading to the the novel CFA‐23 (((propan‐2‐yl)oxidanium)+[Mn6Cl5(ta)8]−; CFA‐23=Coordination Framework Augsburg University‐23) coordination framework. Single‐crystal X‐ray diffraction (SC‐XRD) reveals that it crystallizes in the tetragonal space group P42/nnm (134) exhibiting a two‐fold interpenetrated framework with the topologies of a dia net with point (Schläfli) symbol 66. The thermal stability of this compound was investigated using variable temperature X‐ray powder diffraction and thermogravimetric analysis. The magnetic properties of CFA‐23 differ from a similar non‐interpenetrated literature structure of the composition (H[Mn6(bta)8Cl5] ⋅ (H2O)4) built from 1H‐1,2,3‐benzotriazole, thus, indicating that sterically induced lattice changes might be an adjustment parameter for magnetic properties in such frameworks.</description><identifier>ISSN: 0044-2313</identifier><identifier>EISSN: 1521-3749</identifier><identifier>DOI: 10.1002/zaac.202200153</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Benzotriazole ; Coordination ; coordination framework ; Diffraction ; Isopropanol ; Ligands ; Magnetic properties ; manganese ; metal-organic framework ; microporous materials ; Phase transitions ; Thermal stability ; Thermogravimetric analysis ; Topology ; Triazoles</subject><ispartof>Zeitschrift für anorganische und allgemeine Chemie (1950), 2022-08, Vol.648 (16), p.n/a</ispartof><rights>2022 The Authors. Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH</rights><rights>2022. This article is published under http://creativecommons.org/licenses/by-nc-nd/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3573-6a12b5d05af7ae5651866b5bf8bb1188822e1dad650f4e522378e092ba6757ef3</citedby><cites>FETCH-LOGICAL-c3573-6a12b5d05af7ae5651866b5bf8bb1188822e1dad650f4e522378e092ba6757ef3</cites><orcidid>0000-0002-1437-4762 ; 0000-0001-9167-0752 ; 0000-0002-8105-2157 ; 0000-0001-5215-7673</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fzaac.202200153$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fzaac.202200153$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Röß‐Ohlenroth, Richard</creatorcontrib><creatorcontrib>Hirrle, Marcel</creatorcontrib><creatorcontrib>Kraft, Maryana</creatorcontrib><creatorcontrib>Kalytta‐Mewes, Andreas</creatorcontrib><creatorcontrib>Jesche, Anton</creatorcontrib><creatorcontrib>Krug von Nidda, Hans‐Albrecht</creatorcontrib><creatorcontrib>Volkmer, Dirk</creatorcontrib><title>Synthesis, Thermal Stability and Magnetic Properties of an Interpenetrated Mn(II) Triazolate Coordination Framework</title><title>Zeitschrift für anorganische und allgemeine Chemie (1950)</title><description>Coordination frameworks and metal‐organic frameworks built from simple triazole ligands such as 1H‐1,2,3‐triazole (H‐ta) have recently inspired great interest owing to physical phenomena such as electronic conductivity, phase transitions and their magnetic behavior. In line of our endeavors we report on the solvothermal reaction of MnCl2 ⋅ 4H2O with H‐ta ligand in isopropyl alcohol leading to the the novel CFA‐23 (((propan‐2‐yl)oxidanium)+[Mn6Cl5(ta)8]−; CFA‐23=Coordination Framework Augsburg University‐23) coordination framework. Single‐crystal X‐ray diffraction (SC‐XRD) reveals that it crystallizes in the tetragonal space group P42/nnm (134) exhibiting a two‐fold interpenetrated framework with the topologies of a dia net with point (Schläfli) symbol 66. The thermal stability of this compound was investigated using variable temperature X‐ray powder diffraction and thermogravimetric analysis. The magnetic properties of CFA‐23 differ from a similar non‐interpenetrated literature structure of the composition (H[Mn6(bta)8Cl5] ⋅ (H2O)4) built from 1H‐1,2,3‐benzotriazole, thus, indicating that sterically induced lattice changes might be an adjustment parameter for magnetic properties in such frameworks.</description><subject>Benzotriazole</subject><subject>Coordination</subject><subject>coordination framework</subject><subject>Diffraction</subject><subject>Isopropanol</subject><subject>Ligands</subject><subject>Magnetic properties</subject><subject>manganese</subject><subject>metal-organic framework</subject><subject>microporous materials</subject><subject>Phase transitions</subject><subject>Thermal stability</subject><subject>Thermogravimetric analysis</subject><subject>Topology</subject><subject>Triazoles</subject><issn>0044-2313</issn><issn>1521-3749</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNqFkE1Lw0AQhhdRsFavnhe8KJi6u8nm41iC1YCi0HrxEibJxG5Ns3F3S0l_vSkVPXoamPd5Z-Ah5JKzCWdM3O0AyolgQjDGpX9ERlwK7vlRkByTEWNB4Amf-6fkzNoVGxgm5YjYed-6JVplb-liiWYNDZ07KFSjXE-hregzfLToVElfje7QOIWW6nqIaNY6NB0OqQGHA9leZ9kNXRgFO90MK5pqbSrVglO6pTMDa9xq83lOTmpoLF78zDF5m90v0kfv6eUhS6dPXunLyPdC4KKQFZNQR4AylDwOw0IWdVwUnMdxLATyCqpQsjpAKYQfxcgSUUAYyQhrf0yuDnc7o782aF2-0hvTDi9zEbEwEUnC-UBNDlRptLUG67wzag2mzznL92Lzvdj8V-xQSA6FrWqw_4fO36fT9K_7DUvJfUA</recordid><startdate>20220826</startdate><enddate>20220826</enddate><creator>Röß‐Ohlenroth, Richard</creator><creator>Hirrle, Marcel</creator><creator>Kraft, Maryana</creator><creator>Kalytta‐Mewes, Andreas</creator><creator>Jesche, Anton</creator><creator>Krug von Nidda, Hans‐Albrecht</creator><creator>Volkmer, Dirk</creator><general>Wiley Subscription Services, Inc</general><scope>24P</scope><scope>WIN</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-1437-4762</orcidid><orcidid>https://orcid.org/0000-0001-9167-0752</orcidid><orcidid>https://orcid.org/0000-0002-8105-2157</orcidid><orcidid>https://orcid.org/0000-0001-5215-7673</orcidid></search><sort><creationdate>20220826</creationdate><title>Synthesis, Thermal Stability and Magnetic Properties of an Interpenetrated Mn(II) Triazolate Coordination Framework</title><author>Röß‐Ohlenroth, Richard ; Hirrle, Marcel ; Kraft, Maryana ; Kalytta‐Mewes, Andreas ; Jesche, Anton ; Krug von Nidda, Hans‐Albrecht ; Volkmer, Dirk</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3573-6a12b5d05af7ae5651866b5bf8bb1188822e1dad650f4e522378e092ba6757ef3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Benzotriazole</topic><topic>Coordination</topic><topic>coordination framework</topic><topic>Diffraction</topic><topic>Isopropanol</topic><topic>Ligands</topic><topic>Magnetic properties</topic><topic>manganese</topic><topic>metal-organic framework</topic><topic>microporous materials</topic><topic>Phase transitions</topic><topic>Thermal stability</topic><topic>Thermogravimetric analysis</topic><topic>Topology</topic><topic>Triazoles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Röß‐Ohlenroth, Richard</creatorcontrib><creatorcontrib>Hirrle, Marcel</creatorcontrib><creatorcontrib>Kraft, Maryana</creatorcontrib><creatorcontrib>Kalytta‐Mewes, Andreas</creatorcontrib><creatorcontrib>Jesche, Anton</creatorcontrib><creatorcontrib>Krug von Nidda, Hans‐Albrecht</creatorcontrib><creatorcontrib>Volkmer, Dirk</creatorcontrib><collection>Wiley Online Library (Open Access Collection)</collection><collection>Wiley Online Library Free Content</collection><collection>CrossRef</collection><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Röß‐Ohlenroth, Richard</au><au>Hirrle, Marcel</au><au>Kraft, Maryana</au><au>Kalytta‐Mewes, Andreas</au><au>Jesche, Anton</au><au>Krug von Nidda, Hans‐Albrecht</au><au>Volkmer, Dirk</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Thermal Stability and Magnetic Properties of an Interpenetrated Mn(II) Triazolate Coordination Framework</atitle><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle><date>2022-08-26</date><risdate>2022</risdate><volume>648</volume><issue>16</issue><epage>n/a</epage><issn>0044-2313</issn><eissn>1521-3749</eissn><abstract>Coordination frameworks and metal‐organic frameworks built from simple triazole ligands such as 1H‐1,2,3‐triazole (H‐ta) have recently inspired great interest owing to physical phenomena such as electronic conductivity, phase transitions and their magnetic behavior. In line of our endeavors we report on the solvothermal reaction of MnCl2 ⋅ 4H2O with H‐ta ligand in isopropyl alcohol leading to the the novel CFA‐23 (((propan‐2‐yl)oxidanium)+[Mn6Cl5(ta)8]−; CFA‐23=Coordination Framework Augsburg University‐23) coordination framework. Single‐crystal X‐ray diffraction (SC‐XRD) reveals that it crystallizes in the tetragonal space group P42/nnm (134) exhibiting a two‐fold interpenetrated framework with the topologies of a dia net with point (Schläfli) symbol 66. The thermal stability of this compound was investigated using variable temperature X‐ray powder diffraction and thermogravimetric analysis. The magnetic properties of CFA‐23 differ from a similar non‐interpenetrated literature structure of the composition (H[Mn6(bta)8Cl5] ⋅ (H2O)4) built from 1H‐1,2,3‐benzotriazole, thus, indicating that sterically induced lattice changes might be an adjustment parameter for magnetic properties in such frameworks.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/zaac.202200153</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-1437-4762</orcidid><orcidid>https://orcid.org/0000-0001-9167-0752</orcidid><orcidid>https://orcid.org/0000-0002-8105-2157</orcidid><orcidid>https://orcid.org/0000-0001-5215-7673</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0044-2313 |
| ispartof | Zeitschrift für anorganische und allgemeine Chemie (1950), 2022-08, Vol.648 (16), p.n/a |
| issn | 0044-2313 1521-3749 |
| language | eng |
| recordid | cdi_proquest_journals_2706929911 |
| source | Access via Wiley Online Library |
| subjects | Benzotriazole Coordination coordination framework Diffraction Isopropanol Ligands Magnetic properties manganese metal-organic framework microporous materials Phase transitions Thermal stability Thermogravimetric analysis Topology Triazoles |
| title | Synthesis, Thermal Stability and Magnetic Properties of an Interpenetrated Mn(II) Triazolate Coordination Framework |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-22T13%3A47%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis,%20Thermal%20Stability%20and%20Magnetic%20Properties%20of%20an%20Interpenetrated%20Mn(II)%20Triazolate%20Coordination%20Framework&rft.jtitle=Zeitschrift%20f%C3%BCr%20anorganische%20und%20allgemeine%20Chemie%20(1950)&rft.au=R%C3%B6%C3%9F%E2%80%90Ohlenroth,%20Richard&rft.date=2022-08-26&rft.volume=648&rft.issue=16&rft.epage=n/a&rft.issn=0044-2313&rft.eissn=1521-3749&rft_id=info:doi/10.1002/zaac.202200153&rft_dat=%3Cproquest_cross%3E2706929911%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2706929911&rft_id=info:pmid/&rfr_iscdi=true |