Pervasive Listwaenitization: The Role of Subducted Sediments within Mantle Wedge, W. Chalkidiki Ophiolites, N. Greece
Listwaenitization processes have significantly altered the mantle section of the West Chalkidiki ophiolites, generating the second largest magnesite deposit in Greece. Although research studies have been conducted in the region, the post-magmatic processes, and especially the geotectonic settings un...
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| Veröffentlicht in: | Minerals (Basel) 2022-08, Vol.12 (8), p.1000 |
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| creator | Sideridis, Alkiviadis Koutsovitis, Petros Tsikouras, Basilios Karkalis, Christos Hauzenberger, Christoph Zaccarini, Federica Tsitsanis, Pavlos Lazaratou, Christina Skliros, Vasilios Panagiotaras, Dionisios Papoulis, Dimitrios Hatzipanagiotou, Konstantin |
| description | Listwaenitization processes have significantly altered the mantle section of the West Chalkidiki ophiolites, generating the second largest magnesite deposit in Greece. Although research studies have been conducted in the region, the post-magmatic processes, and especially the geotectonic settings under which listwaenitization took place, remain unclear. In this study, minerals and rocks were studied applying XRD, clay fraction, SEM, EMPA, ICP-MS, INAA, LA-ICP-MS, and thermodynamic modeling. The results revealed that alteration processes significantly affected the mantle wedge peridotite protoliths leading to the following chemical changes (a) SiO2 increase with decreasing MgO, (b) Cs, Pb, As, and V enrichments, (c) limited alteration of magnesiochromite hosted within listwaenitized chromitites and (d) enrichment in PPGE and Au in listwaenitized chromitites and desulfurized laurite. Alteration was induced by fluids deriving from subducted Mesozoic sediments, represented by the Prinochori Formation or chemically similar formations. The final product of completely silicified peridotite (silica listwaenite) is thermodynamically stable in Earth-surface conditions, with dolomite and phyllosilicates transforming into clay minerals. Based on detailed petrographical observations, peridotites were subjected to serpentinization, and subsequently, serpentine interacted with CO2, silica and calcium-bearing fluids, leading to its transformation into amorphous rusty-silica mass and/or tremolite. |
| doi_str_mv | 10.3390/min12081000 |
| format | Article |
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Chalkidiki Ophiolites, N. Greece</title><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>EZB-FREE-00999 freely available EZB journals</source><source>Alma/SFX Local Collection</source><creator>Sideridis, Alkiviadis ; Koutsovitis, Petros ; Tsikouras, Basilios ; Karkalis, Christos ; Hauzenberger, Christoph ; Zaccarini, Federica ; Tsitsanis, Pavlos ; Lazaratou, Christina ; Skliros, Vasilios ; Panagiotaras, Dionisios ; Papoulis, Dimitrios ; Hatzipanagiotou, Konstantin</creator><creatorcontrib>Sideridis, Alkiviadis ; Koutsovitis, Petros ; Tsikouras, Basilios ; Karkalis, Christos ; Hauzenberger, Christoph ; Zaccarini, Federica ; Tsitsanis, Pavlos ; Lazaratou, Christina ; Skliros, Vasilios ; Panagiotaras, Dionisios ; Papoulis, Dimitrios ; Hatzipanagiotou, Konstantin</creatorcontrib><description>Listwaenitization processes have significantly altered the mantle section of the West Chalkidiki ophiolites, generating the second largest magnesite deposit in Greece. Although research studies have been conducted in the region, the post-magmatic processes, and especially the geotectonic settings under which listwaenitization took place, remain unclear. In this study, minerals and rocks were studied applying XRD, clay fraction, SEM, EMPA, ICP-MS, INAA, LA-ICP-MS, and thermodynamic modeling. The results revealed that alteration processes significantly affected the mantle wedge peridotite protoliths leading to the following chemical changes (a) SiO2 increase with decreasing MgO, (b) Cs, Pb, As, and V enrichments, (c) limited alteration of magnesiochromite hosted within listwaenitized chromitites and (d) enrichment in PPGE and Au in listwaenitized chromitites and desulfurized laurite. Alteration was induced by fluids deriving from subducted Mesozoic sediments, represented by the Prinochori Formation or chemically similar formations. The final product of completely silicified peridotite (silica listwaenite) is thermodynamically stable in Earth-surface conditions, with dolomite and phyllosilicates transforming into clay minerals. Based on detailed petrographical observations, peridotites were subjected to serpentinization, and subsequently, serpentine interacted with CO2, silica and calcium-bearing fluids, leading to its transformation into amorphous rusty-silica mass and/or tremolite.</description><identifier>ISSN: 2075-163X</identifier><identifier>EISSN: 2075-163X</identifier><identifier>DOI: 10.3390/min12081000</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Calcium ; Carbon dioxide ; Clay ; Clay minerals ; Dolomite ; Dolostone ; Earth mantle ; Fluids ; Geochemistry ; Geology ; Magnesite ; Magnesium carbonate ; Mesozoic ; Minerals ; Morphology ; Ophiolites ; Peridotite ; Quartz ; Scanning electron microscopy ; Sediment ; Sediments ; Serpentine ; Serpentinization ; Silica ; Silicon dioxide ; Thermodynamic models ; Trace elements ; Tremolite</subject><ispartof>Minerals (Basel), 2022-08, Vol.12 (8), p.1000</ispartof><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c364t-e5e4d1a188c986b6c482af8bc265dce441e1018c088e832c5afc2790f5da84b33</citedby><cites>FETCH-LOGICAL-c364t-e5e4d1a188c986b6c482af8bc265dce441e1018c088e832c5afc2790f5da84b33</cites><orcidid>0000-0003-1949-8673 ; 0000-0003-4301-6363 ; 0000-0003-1734-4726 ; 0000-0003-3580-2196 ; 0000-0002-4393-0908</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Sideridis, Alkiviadis</creatorcontrib><creatorcontrib>Koutsovitis, Petros</creatorcontrib><creatorcontrib>Tsikouras, Basilios</creatorcontrib><creatorcontrib>Karkalis, Christos</creatorcontrib><creatorcontrib>Hauzenberger, Christoph</creatorcontrib><creatorcontrib>Zaccarini, Federica</creatorcontrib><creatorcontrib>Tsitsanis, Pavlos</creatorcontrib><creatorcontrib>Lazaratou, Christina</creatorcontrib><creatorcontrib>Skliros, Vasilios</creatorcontrib><creatorcontrib>Panagiotaras, Dionisios</creatorcontrib><creatorcontrib>Papoulis, Dimitrios</creatorcontrib><creatorcontrib>Hatzipanagiotou, Konstantin</creatorcontrib><title>Pervasive Listwaenitization: The Role of Subducted Sediments within Mantle Wedge, W. Chalkidiki Ophiolites, N. Greece</title><title>Minerals (Basel)</title><description>Listwaenitization processes have significantly altered the mantle section of the West Chalkidiki ophiolites, generating the second largest magnesite deposit in Greece. Although research studies have been conducted in the region, the post-magmatic processes, and especially the geotectonic settings under which listwaenitization took place, remain unclear. In this study, minerals and rocks were studied applying XRD, clay fraction, SEM, EMPA, ICP-MS, INAA, LA-ICP-MS, and thermodynamic modeling. The results revealed that alteration processes significantly affected the mantle wedge peridotite protoliths leading to the following chemical changes (a) SiO2 increase with decreasing MgO, (b) Cs, Pb, As, and V enrichments, (c) limited alteration of magnesiochromite hosted within listwaenitized chromitites and (d) enrichment in PPGE and Au in listwaenitized chromitites and desulfurized laurite. Alteration was induced by fluids deriving from subducted Mesozoic sediments, represented by the Prinochori Formation or chemically similar formations. The final product of completely silicified peridotite (silica listwaenite) is thermodynamically stable in Earth-surface conditions, with dolomite and phyllosilicates transforming into clay minerals. Based on detailed petrographical observations, peridotites were subjected to serpentinization, and subsequently, serpentine interacted with CO2, silica and calcium-bearing fluids, leading to its transformation into amorphous rusty-silica mass and/or tremolite.</description><subject>Calcium</subject><subject>Carbon dioxide</subject><subject>Clay</subject><subject>Clay minerals</subject><subject>Dolomite</subject><subject>Dolostone</subject><subject>Earth mantle</subject><subject>Fluids</subject><subject>Geochemistry</subject><subject>Geology</subject><subject>Magnesite</subject><subject>Magnesium carbonate</subject><subject>Mesozoic</subject><subject>Minerals</subject><subject>Morphology</subject><subject>Ophiolites</subject><subject>Peridotite</subject><subject>Quartz</subject><subject>Scanning electron microscopy</subject><subject>Sediment</subject><subject>Sediments</subject><subject>Serpentine</subject><subject>Serpentinization</subject><subject>Silica</subject><subject>Silicon dioxide</subject><subject>Thermodynamic models</subject><subject>Trace elements</subject><subject>Tremolite</subject><issn>2075-163X</issn><issn>2075-163X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpNkEtPwkAYRSdGEwmy8g9M4lKK8-hj6s4QRRMUIxjcNdOZr3agtDgzheivtwYXrO5dnNybHIQuKRlxnpKbjakpI4ISQk5Qj5EkCmjMP06P-jkaOLfqAJJSLiLWQ-0r2J10Zgd4apzfS6iNNz_Sm6a-xYsS8FtTAW4KPG9z3SoPGs9Bmw3U3uG98aWp8bOsfQctQX_CEC9HeFzKam20WRs825amqYwHN8QvIzyxAAou0FkhKweD_-yj94f7xfgxmM4mT-O7aaB4HPoAIgg1lVQIlYo4j1UomCxErlgcaQVhSIESKhQRAgRnKpKFYklKikhLEeac99HVYXdrm68WnM9WTWvr7jJjCYlZEnNCO-r6QCnbOGehyLbWbKT9zijJ_tRmR2r5LzyRa_M</recordid><startdate>20220808</startdate><enddate>20220808</enddate><creator>Sideridis, Alkiviadis</creator><creator>Koutsovitis, Petros</creator><creator>Tsikouras, Basilios</creator><creator>Karkalis, Christos</creator><creator>Hauzenberger, Christoph</creator><creator>Zaccarini, Federica</creator><creator>Tsitsanis, Pavlos</creator><creator>Lazaratou, Christina</creator><creator>Skliros, Vasilios</creator><creator>Panagiotaras, Dionisios</creator><creator>Papoulis, Dimitrios</creator><creator>Hatzipanagiotou, Konstantin</creator><general>MDPI AG</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7TN</scope><scope>7UA</scope><scope>7WY</scope><scope>7WZ</scope><scope>7XB</scope><scope>87Z</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8FL</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F1W</scope><scope>FR3</scope><scope>FRNLG</scope><scope>F~G</scope><scope>H96</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K60</scope><scope>K6~</scope><scope>KB.</scope><scope>KR7</scope><scope>L.-</scope><scope>L.G</scope><scope>M0C</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><orcidid>https://orcid.org/0000-0003-1949-8673</orcidid><orcidid>https://orcid.org/0000-0003-4301-6363</orcidid><orcidid>https://orcid.org/0000-0003-1734-4726</orcidid><orcidid>https://orcid.org/0000-0003-3580-2196</orcidid><orcidid>https://orcid.org/0000-0002-4393-0908</orcidid></search><sort><creationdate>20220808</creationdate><title>Pervasive Listwaenitization: The Role of Subducted Sediments within Mantle Wedge, W. 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Chalkidiki Ophiolites, N. Greece</atitle><jtitle>Minerals (Basel)</jtitle><date>2022-08-08</date><risdate>2022</risdate><volume>12</volume><issue>8</issue><spage>1000</spage><pages>1000-</pages><issn>2075-163X</issn><eissn>2075-163X</eissn><abstract>Listwaenitization processes have significantly altered the mantle section of the West Chalkidiki ophiolites, generating the second largest magnesite deposit in Greece. Although research studies have been conducted in the region, the post-magmatic processes, and especially the geotectonic settings under which listwaenitization took place, remain unclear. In this study, minerals and rocks were studied applying XRD, clay fraction, SEM, EMPA, ICP-MS, INAA, LA-ICP-MS, and thermodynamic modeling. The results revealed that alteration processes significantly affected the mantle wedge peridotite protoliths leading to the following chemical changes (a) SiO2 increase with decreasing MgO, (b) Cs, Pb, As, and V enrichments, (c) limited alteration of magnesiochromite hosted within listwaenitized chromitites and (d) enrichment in PPGE and Au in listwaenitized chromitites and desulfurized laurite. Alteration was induced by fluids deriving from subducted Mesozoic sediments, represented by the Prinochori Formation or chemically similar formations. The final product of completely silicified peridotite (silica listwaenite) is thermodynamically stable in Earth-surface conditions, with dolomite and phyllosilicates transforming into clay minerals. Based on detailed petrographical observations, peridotites were subjected to serpentinization, and subsequently, serpentine interacted with CO2, silica and calcium-bearing fluids, leading to its transformation into amorphous rusty-silica mass and/or tremolite.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/min12081000</doi><orcidid>https://orcid.org/0000-0003-1949-8673</orcidid><orcidid>https://orcid.org/0000-0003-4301-6363</orcidid><orcidid>https://orcid.org/0000-0003-1734-4726</orcidid><orcidid>https://orcid.org/0000-0003-3580-2196</orcidid><orcidid>https://orcid.org/0000-0002-4393-0908</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Calcium Carbon dioxide Clay Clay minerals Dolomite Dolostone Earth mantle Fluids Geochemistry Geology Magnesite Magnesium carbonate Mesozoic Minerals Morphology Ophiolites Peridotite Quartz Scanning electron microscopy Sediment Sediments Serpentine Serpentinization Silica Silicon dioxide Thermodynamic models Trace elements Tremolite |
| title | Pervasive Listwaenitization: The Role of Subducted Sediments within Mantle Wedge, W. Chalkidiki Ophiolites, N. Greece |
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