Synthesis and evaluation of polyisobutylene (PIB)-based fuel additives for controlling carbon deposit in motorcycle engine
Polyisobutylene (PIB)-based deposit-control additives are polymeric substances that function as additives in engine fuel to prevent gum and sludge formation in the combustion process and reduce the release of impurities associated with severe performance and environmental issues. This work synthesiz...
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| creator | Pebriani, Siska Sukirno Febriantini, Dwi Nugraha, Aji Satria Purnomo, Bambang Usman |
| description | Polyisobutylene (PIB)-based deposit-control additives are polymeric substances that function as additives in engine fuel to prevent gum and sludge formation in the combustion process and reduce the release of impurities associated with severe performance and environmental issues. This work synthesized two types of additives by modifying polyisobutylene with diethylenetriamine (PIB-DETA) and pentaethylenehexamine (PIB-PEHA). We performed characterization using Fourier transform-infrared (FT-IR) spectroscopy, UV-vis spectrophotometer, thermogravimetric analysis, and liquid chromatography-electrospray ionization-quadrupole time-of-flight-tandem mass spectrometry (LC– ESI-QTOF-MS/MS) to evaluate the chemical properties of the products. The generation of intake valve deposits (IVD) and combustion chamber deposits (CCD) were observed to ascertain the performance of synthesized dispersants to control deposit formation in the motorcycle engine. The results showed that PIB-DETA has better performance to control CCD generation than PIB-PEHA in IVD. Compared with commercially available PIBA, these two dispersants have less different performance and are potential for industrial application. |
| doi_str_mv | 10.1063/5.0109390 |
| format | Conference Proceeding |
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This work synthesized two types of additives by modifying polyisobutylene with diethylenetriamine (PIB-DETA) and pentaethylenehexamine (PIB-PEHA). We performed characterization using Fourier transform-infrared (FT-IR) spectroscopy, UV-vis spectrophotometer, thermogravimetric analysis, and liquid chromatography-electrospray ionization-quadrupole time-of-flight-tandem mass spectrometry (LC– ESI-QTOF-MS/MS) to evaluate the chemical properties of the products. The generation of intake valve deposits (IVD) and combustion chamber deposits (CCD) were observed to ascertain the performance of synthesized dispersants to control deposit formation in the motorcycle engine. The results showed that PIB-DETA has better performance to control CCD generation than PIB-PEHA in IVD. Compared with commercially available PIBA, these two dispersants have less different performance and are potential for industrial application.</description><identifier>ISSN: 0094-243X</identifier><identifier>EISSN: 1551-7616</identifier><identifier>DOI: 10.1063/5.0109390</identifier><identifier>CODEN: APCPCS</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Chemical properties ; Combustion chambers ; Diethylene triamine ; Dispersants ; Dispersion ; Fourier transforms ; Fuel additives ; Industrial applications ; Infrared analysis ; Infrared spectrophotometers ; Infrared spectroscopy ; Liquid chromatography ; Mass spectrometry ; Motor vehicle engines ; Motorcycles ; Polyisobutylene ; Quadrupoles ; Synthesis ; Thermogravimetric analysis</subject><ispartof>AIP Conference Proceedings, 2022, Vol.2638 (1)</ispartof><rights>Author(s)</rights><rights>2022 Author(s). 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This work synthesized two types of additives by modifying polyisobutylene with diethylenetriamine (PIB-DETA) and pentaethylenehexamine (PIB-PEHA). We performed characterization using Fourier transform-infrared (FT-IR) spectroscopy, UV-vis spectrophotometer, thermogravimetric analysis, and liquid chromatography-electrospray ionization-quadrupole time-of-flight-tandem mass spectrometry (LC– ESI-QTOF-MS/MS) to evaluate the chemical properties of the products. The generation of intake valve deposits (IVD) and combustion chamber deposits (CCD) were observed to ascertain the performance of synthesized dispersants to control deposit formation in the motorcycle engine. The results showed that PIB-DETA has better performance to control CCD generation than PIB-PEHA in IVD. Compared with commercially available PIBA, these two dispersants have less different performance and are potential for industrial application.</description><subject>Chemical properties</subject><subject>Combustion chambers</subject><subject>Diethylene triamine</subject><subject>Dispersants</subject><subject>Dispersion</subject><subject>Fourier transforms</subject><subject>Fuel additives</subject><subject>Industrial applications</subject><subject>Infrared analysis</subject><subject>Infrared spectrophotometers</subject><subject>Infrared spectroscopy</subject><subject>Liquid chromatography</subject><subject>Mass spectrometry</subject><subject>Motor vehicle engines</subject><subject>Motorcycles</subject><subject>Polyisobutylene</subject><subject>Quadrupoles</subject><subject>Synthesis</subject><subject>Thermogravimetric analysis</subject><issn>0094-243X</issn><issn>1551-7616</issn><fulltext>true</fulltext><rsrctype>conference_proceeding</rsrctype><creationdate>2022</creationdate><recordtype>conference_proceeding</recordtype><recordid>eNp9kUtLxDAUhYMoOI4u_AcBNyp0TJqmj6UOPgYGFFRwV9LkZszQSWqSDtRfb3UEd67u5jvnwHcROqVkRknOrviMUFKxiuyhCeWcJkVO8300IaTKkjRjb4foKIQ1IWlVFOUEfT4PNr5DMAELqzBsRduLaJzFTuPOtYMJrunj0IIFfP60uLlIGhFAYd1Di4VSJpotBKydx9LZ6F3bGrvCUvhmLFHQuWAiNhZvXHReDrIFDHZlLByjAy3aACe_d4pe725f5g_J8vF-Mb9eJl1KGElYpkUpS52VDae80gRUKriucipVmrOmVKIsVUFpwwUUqpAZ4bRhIGlepUAzNkVnu97Ou48eQqzXrvd2nKzTgrDRD8vYSF3uqCBN_DFQd95shB_qrfM1r3-91p3S_8GU1N-P-AuwL_B_fBI</recordid><startdate>20220818</startdate><enddate>20220818</enddate><creator>Pebriani, Siska</creator><creator>Sukirno</creator><creator>Febriantini, Dwi</creator><creator>Nugraha, Aji Satria</creator><creator>Purnomo, Bambang</creator><creator>Usman</creator><general>American Institute of Physics</general><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20220818</creationdate><title>Synthesis and evaluation of polyisobutylene (PIB)-based fuel additives for controlling carbon deposit in motorcycle engine</title><author>Pebriani, Siska ; Sukirno ; Febriantini, Dwi ; Nugraha, Aji Satria ; Purnomo, Bambang ; Usman</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p2030-34fa8c8f48b5159f0ed2a5f961cd263b8da88d711b5ae7d7c4051b3ec1692e143</frbrgroupid><rsrctype>conference_proceedings</rsrctype><prefilter>conference_proceedings</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemical properties</topic><topic>Combustion chambers</topic><topic>Diethylene triamine</topic><topic>Dispersants</topic><topic>Dispersion</topic><topic>Fourier transforms</topic><topic>Fuel additives</topic><topic>Industrial applications</topic><topic>Infrared analysis</topic><topic>Infrared spectrophotometers</topic><topic>Infrared spectroscopy</topic><topic>Liquid chromatography</topic><topic>Mass spectrometry</topic><topic>Motor vehicle engines</topic><topic>Motorcycles</topic><topic>Polyisobutylene</topic><topic>Quadrupoles</topic><topic>Synthesis</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pebriani, Siska</creatorcontrib><creatorcontrib>Sukirno</creatorcontrib><creatorcontrib>Febriantini, Dwi</creatorcontrib><creatorcontrib>Nugraha, Aji Satria</creatorcontrib><creatorcontrib>Purnomo, Bambang</creatorcontrib><creatorcontrib>Usman</creatorcontrib><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pebriani, Siska</au><au>Sukirno</au><au>Febriantini, Dwi</au><au>Nugraha, Aji Satria</au><au>Purnomo, Bambang</au><au>Usman</au><au>Hadisaputra, Saprizal</au><au>Savalas, Lalu Rudyat Telly</au><format>book</format><genre>proceeding</genre><ristype>CONF</ristype><atitle>Synthesis and evaluation of polyisobutylene (PIB)-based fuel additives for controlling carbon deposit in motorcycle engine</atitle><btitle>AIP Conference Proceedings</btitle><date>2022-08-18</date><risdate>2022</risdate><volume>2638</volume><issue>1</issue><issn>0094-243X</issn><eissn>1551-7616</eissn><coden>APCPCS</coden><abstract>Polyisobutylene (PIB)-based deposit-control additives are polymeric substances that function as additives in engine fuel to prevent gum and sludge formation in the combustion process and reduce the release of impurities associated with severe performance and environmental issues. This work synthesized two types of additives by modifying polyisobutylene with diethylenetriamine (PIB-DETA) and pentaethylenehexamine (PIB-PEHA). We performed characterization using Fourier transform-infrared (FT-IR) spectroscopy, UV-vis spectrophotometer, thermogravimetric analysis, and liquid chromatography-electrospray ionization-quadrupole time-of-flight-tandem mass spectrometry (LC– ESI-QTOF-MS/MS) to evaluate the chemical properties of the products. The generation of intake valve deposits (IVD) and combustion chamber deposits (CCD) were observed to ascertain the performance of synthesized dispersants to control deposit formation in the motorcycle engine. The results showed that PIB-DETA has better performance to control CCD generation than PIB-PEHA in IVD. Compared with commercially available PIBA, these two dispersants have less different performance and are potential for industrial application.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/5.0109390</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0094-243X |
| ispartof | AIP Conference Proceedings, 2022, Vol.2638 (1) |
| issn | 0094-243X 1551-7616 |
| language | eng |
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| source | AIP Journals Complete |
| subjects | Chemical properties Combustion chambers Diethylene triamine Dispersants Dispersion Fourier transforms Fuel additives Industrial applications Infrared analysis Infrared spectrophotometers Infrared spectroscopy Liquid chromatography Mass spectrometry Motor vehicle engines Motorcycles Polyisobutylene Quadrupoles Synthesis Thermogravimetric analysis |
| title | Synthesis and evaluation of polyisobutylene (PIB)-based fuel additives for controlling carbon deposit in motorcycle engine |
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