Photoinduced Copper‐Catalyzed Asymmetric C(sp3)−H Alkynylation of Cyclic Amines by Intramolecular 1,5‐Hydrogen Atom Transfer

The development of a mild and general method for C(sp3)−H functionalization of cyclic amines has been an ongoing challenge. In this work, we describe the copper‐catalyzed enantioselective C(sp3)−H alkynylation of unactivated cyclic 2‐iodo‐benzamide under photo‐irradiation by intramolecular 1,5‐hydro...

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Veröffentlicht in:	Angewandte Chemie 2022-08, Vol.134 (34), p.n/a
Hauptverfasser:	Guo, Rui, Xiao, Haijing, Li, Sijia, Luo, Yixin, Bai, Jiahui, Zhang, Mengzhen, Guo, Yinlong, Qi, Xiaotian, Zhang, Guozhu
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines Asymmetric Synthesis Benzamide Catalysts Chemistry Computer applications Copper Copper Catalysis Copper compounds Enantiomers Hydrogen Atom Transfer Hydrogen atoms Irradiation Photochemistry Radiation Stereoselectivity Substrates
Online-Zugang:	Volltext
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