Using Design-Expert to Optimize the Properties of a Polyethersulfone Ultrafiltration Membrane Through the Incorporation of NH2-MIL-53(Fe) and PVP for Maximum Cr(VI) Removal and Flux
In this study, an NH 2 -MIL-53(Fe) functionalized membrane was fabricated for Cr(VI) removal from contaminated groundwater. Design-Expert was employed to determine the optimum membrane structure in order to enhance selective adsorption rate and flux by investigating two factors of metal–organic fram...
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| Veröffentlicht in: | Journal of polymers and the environment 2022-09, Vol.30 (9), p.3875-3889 |
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| creator | Forouzesh Rad, Bahar Mahdavi, Hossein Forouzesh Rad, Mahsa Baghdadi, Majid |
| description | In this study, an NH
2
-MIL-53(Fe) functionalized membrane was fabricated for Cr(VI) removal from contaminated groundwater. Design-Expert was employed to determine the optimum membrane structure in order to enhance selective adsorption rate and flux by investigating two factors of metal–organic framework (MOF: 0–5 wt%) and polyvinylpyrrolidone (PVP: 0.1–1 wt%). NH
2
-MIL-53(Fe) successfully synthesized was proved using FESEM, FTIR, EDS, and XRD analyses. NH
2
-MIL-53(Fe) functionalized membrane was prepared, and the properties were recognized using FESEM, EDS, EDX-mapping, and CA. According to these analyses, the synthesized MOF improved membrane properties such as hydrophilicity and porosity. Moreover, the MOF crystals were well immobilized in the polymer solution and uniformly distributed in the composite membrane. On the basis of the statistical results, PVP had a much more significant effect on adsorption percentage than MOF. In accordance with the Design-Expert result, the optimum structure of the MOF functionalized membrane containing 3.6 wt% of NH
2
-MIL-53(Fe) and 0.4 wt% of PVP exhibited a removal percentage of 87% and flux of 101 L m
−2
h
−1
. Investigation of the effect of TDS did not indicate any interference with Cr(VI) adsorption by the adsorbent. Additionally, membrane repeatability and regeneration tests, used in five cycles, confirmed the membrane's long-term durability and performance. |
| doi_str_mv | 10.1007/s10924-022-02477-3 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2701322216</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2701322216</sourcerecordid><originalsourceid>FETCH-LOGICAL-c249t-ecc9cc9bf0a5af98df1c5ae62e1dbc687485bc1c1c0850bc0308effe9f4a10e3</originalsourceid><addsrcrecordid>eNp9kc1OAjEUhSdGExF9AVdN3Oii2nb-lwZBSUCJQbZNp9xCzcx0bGcM-F6-nwVM3Jne_qT3O-cuThBcUnJLCUnvHCU5izBhzO8oTXF4FPRonDKc5TQ_3r2TBLM4Ck-DM-feCSG5F_aC7zen6xV6AKdXNR5uGrAtag16aVpd6S9A7RrQzJrdvwaHjEICzUy5Bd-wriuVqQG9la0VSu_OVpsaTaEqrPCN-dqabrXeu4xraWxjfhFv9PzE8HQ8wXF4PYIbJOolmi1mSBmLpmKjq65CA3u9GN-gV6jMpyj3yKjsNufBiRKlg4vfux_MR8P54AlPXh7Hg_sJlizKWwxS5r4KRUQsVJ4tFZWxgIQBXRYyydIoiwtJ_SJZTApJQpKBUpCrSFACYT-4Otg21nx04Fr-bjpb-4mcpYSGjDGaeIodKGmNcxYUb6yuhN1ySvguHX5Ih_t0-D4dHnpReBA5D9crsH_W_6h-AEUxlMY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2701322216</pqid></control><display><type>article</type><title>Using Design-Expert to Optimize the Properties of a Polyethersulfone Ultrafiltration Membrane Through the Incorporation of NH2-MIL-53(Fe) and PVP for Maximum Cr(VI) Removal and Flux</title><source>SpringerLink Journals</source><creator>Forouzesh Rad, Bahar ; Mahdavi, Hossein ; Forouzesh Rad, Mahsa ; Baghdadi, Majid</creator><creatorcontrib>Forouzesh Rad, Bahar ; Mahdavi, Hossein ; Forouzesh Rad, Mahsa ; Baghdadi, Majid</creatorcontrib><description>In this study, an NH
2
-MIL-53(Fe) functionalized membrane was fabricated for Cr(VI) removal from contaminated groundwater. Design-Expert was employed to determine the optimum membrane structure in order to enhance selective adsorption rate and flux by investigating two factors of metal–organic framework (MOF: 0–5 wt%) and polyvinylpyrrolidone (PVP: 0.1–1 wt%). NH
2
-MIL-53(Fe) successfully synthesized was proved using FESEM, FTIR, EDS, and XRD analyses. NH
2
-MIL-53(Fe) functionalized membrane was prepared, and the properties were recognized using FESEM, EDS, EDX-mapping, and CA. According to these analyses, the synthesized MOF improved membrane properties such as hydrophilicity and porosity. Moreover, the MOF crystals were well immobilized in the polymer solution and uniformly distributed in the composite membrane. On the basis of the statistical results, PVP had a much more significant effect on adsorption percentage than MOF. In accordance with the Design-Expert result, the optimum structure of the MOF functionalized membrane containing 3.6 wt% of NH
2
-MIL-53(Fe) and 0.4 wt% of PVP exhibited a removal percentage of 87% and flux of 101 L m
−2
h
−1
. Investigation of the effect of TDS did not indicate any interference with Cr(VI) adsorption by the adsorbent. Additionally, membrane repeatability and regeneration tests, used in five cycles, confirmed the membrane's long-term durability and performance.</description><identifier>ISSN: 1566-2543</identifier><identifier>EISSN: 1572-8919</identifier><identifier>DOI: 10.1007/s10924-022-02477-3</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorption ; Chemistry ; Chemistry and Materials Science ; Chromium ; Crystals ; Design ; Design optimization ; Environmental Chemistry ; Environmental Engineering/Biotechnology ; Fluctuations ; Groundwater ; Groundwater pollution ; Industrial Chemistry/Chemical Engineering ; Iron ; Materials Science ; Membrane structure ; Membrane structures ; Membranes ; Metal-organic frameworks ; Original Paper ; Polyethersulfones ; Polymer Sciences ; Polymers ; Polyvinylpyrrolidone ; Porosity ; Selective adsorption ; Synthesis ; Ultrafiltration</subject><ispartof>Journal of polymers and the environment, 2022-09, Vol.30 (9), p.3875-3889</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-ecc9cc9bf0a5af98df1c5ae62e1dbc687485bc1c1c0850bc0308effe9f4a10e3</citedby><cites>FETCH-LOGICAL-c249t-ecc9cc9bf0a5af98df1c5ae62e1dbc687485bc1c1c0850bc0308effe9f4a10e3</cites><orcidid>0000-0001-9816-764X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10924-022-02477-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10924-022-02477-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Forouzesh Rad, Bahar</creatorcontrib><creatorcontrib>Mahdavi, Hossein</creatorcontrib><creatorcontrib>Forouzesh Rad, Mahsa</creatorcontrib><creatorcontrib>Baghdadi, Majid</creatorcontrib><title>Using Design-Expert to Optimize the Properties of a Polyethersulfone Ultrafiltration Membrane Through the Incorporation of NH2-MIL-53(Fe) and PVP for Maximum Cr(VI) Removal and Flux</title><title>Journal of polymers and the environment</title><addtitle>J Polym Environ</addtitle><description>In this study, an NH
2
-MIL-53(Fe) functionalized membrane was fabricated for Cr(VI) removal from contaminated groundwater. Design-Expert was employed to determine the optimum membrane structure in order to enhance selective adsorption rate and flux by investigating two factors of metal–organic framework (MOF: 0–5 wt%) and polyvinylpyrrolidone (PVP: 0.1–1 wt%). NH
2
-MIL-53(Fe) successfully synthesized was proved using FESEM, FTIR, EDS, and XRD analyses. NH
2
-MIL-53(Fe) functionalized membrane was prepared, and the properties were recognized using FESEM, EDS, EDX-mapping, and CA. According to these analyses, the synthesized MOF improved membrane properties such as hydrophilicity and porosity. Moreover, the MOF crystals were well immobilized in the polymer solution and uniformly distributed in the composite membrane. On the basis of the statistical results, PVP had a much more significant effect on adsorption percentage than MOF. In accordance with the Design-Expert result, the optimum structure of the MOF functionalized membrane containing 3.6 wt% of NH
2
-MIL-53(Fe) and 0.4 wt% of PVP exhibited a removal percentage of 87% and flux of 101 L m
−2
h
−1
. Investigation of the effect of TDS did not indicate any interference with Cr(VI) adsorption by the adsorbent. Additionally, membrane repeatability and regeneration tests, used in five cycles, confirmed the membrane's long-term durability and performance.</description><subject>Adsorption</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromium</subject><subject>Crystals</subject><subject>Design</subject><subject>Design optimization</subject><subject>Environmental Chemistry</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Fluctuations</subject><subject>Groundwater</subject><subject>Groundwater pollution</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Iron</subject><subject>Materials Science</subject><subject>Membrane structure</subject><subject>Membrane structures</subject><subject>Membranes</subject><subject>Metal-organic frameworks</subject><subject>Original Paper</subject><subject>Polyethersulfones</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Polyvinylpyrrolidone</subject><subject>Porosity</subject><subject>Selective adsorption</subject><subject>Synthesis</subject><subject>Ultrafiltration</subject><issn>1566-2543</issn><issn>1572-8919</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kc1OAjEUhSdGExF9AVdN3Oii2nb-lwZBSUCJQbZNp9xCzcx0bGcM-F6-nwVM3Jne_qT3O-cuThBcUnJLCUnvHCU5izBhzO8oTXF4FPRonDKc5TQ_3r2TBLM4Ck-DM-feCSG5F_aC7zen6xV6AKdXNR5uGrAtag16aVpd6S9A7RrQzJrdvwaHjEICzUy5Bd-wriuVqQG9la0VSu_OVpsaTaEqrPCN-dqabrXeu4xraWxjfhFv9PzE8HQ8wXF4PYIbJOolmi1mSBmLpmKjq65CA3u9GN-gV6jMpyj3yKjsNufBiRKlg4vfux_MR8P54AlPXh7Hg_sJlizKWwxS5r4KRUQsVJ4tFZWxgIQBXRYyydIoiwtJ_SJZTApJQpKBUpCrSFACYT-4Otg21nx04Fr-bjpb-4mcpYSGjDGaeIodKGmNcxYUb6yuhN1ySvguHX5Ih_t0-D4dHnpReBA5D9crsH_W_6h-AEUxlMY</recordid><startdate>20220901</startdate><enddate>20220901</enddate><creator>Forouzesh Rad, Bahar</creator><creator>Mahdavi, Hossein</creator><creator>Forouzesh Rad, Mahsa</creator><creator>Baghdadi, Majid</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8AO</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><orcidid>https://orcid.org/0000-0001-9816-764X</orcidid></search><sort><creationdate>20220901</creationdate><title>Using Design-Expert to Optimize the Properties of a Polyethersulfone Ultrafiltration Membrane Through the Incorporation of NH2-MIL-53(Fe) and PVP for Maximum Cr(VI) Removal and Flux</title><author>Forouzesh Rad, Bahar ; Mahdavi, Hossein ; Forouzesh Rad, Mahsa ; Baghdadi, Majid</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-ecc9cc9bf0a5af98df1c5ae62e1dbc687485bc1c1c0850bc0308effe9f4a10e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Adsorption</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromium</topic><topic>Crystals</topic><topic>Design</topic><topic>Design optimization</topic><topic>Environmental Chemistry</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Fluctuations</topic><topic>Groundwater</topic><topic>Groundwater pollution</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Iron</topic><topic>Materials Science</topic><topic>Membrane structure</topic><topic>Membrane structures</topic><topic>Membranes</topic><topic>Metal-organic frameworks</topic><topic>Original Paper</topic><topic>Polyethersulfones</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Polyvinylpyrrolidone</topic><topic>Porosity</topic><topic>Selective adsorption</topic><topic>Synthesis</topic><topic>Ultrafiltration</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Forouzesh Rad, Bahar</creatorcontrib><creatorcontrib>Mahdavi, Hossein</creatorcontrib><creatorcontrib>Forouzesh Rad, Mahsa</creatorcontrib><creatorcontrib>Baghdadi, Majid</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of polymers and the environment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Forouzesh Rad, Bahar</au><au>Mahdavi, Hossein</au><au>Forouzesh Rad, Mahsa</au><au>Baghdadi, Majid</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Using Design-Expert to Optimize the Properties of a Polyethersulfone Ultrafiltration Membrane Through the Incorporation of NH2-MIL-53(Fe) and PVP for Maximum Cr(VI) Removal and Flux</atitle><jtitle>Journal of polymers and the environment</jtitle><stitle>J Polym Environ</stitle><date>2022-09-01</date><risdate>2022</risdate><volume>30</volume><issue>9</issue><spage>3875</spage><epage>3889</epage><pages>3875-3889</pages><issn>1566-2543</issn><eissn>1572-8919</eissn><abstract>In this study, an NH
2
-MIL-53(Fe) functionalized membrane was fabricated for Cr(VI) removal from contaminated groundwater. Design-Expert was employed to determine the optimum membrane structure in order to enhance selective adsorption rate and flux by investigating two factors of metal–organic framework (MOF: 0–5 wt%) and polyvinylpyrrolidone (PVP: 0.1–1 wt%). NH
2
-MIL-53(Fe) successfully synthesized was proved using FESEM, FTIR, EDS, and XRD analyses. NH
2
-MIL-53(Fe) functionalized membrane was prepared, and the properties were recognized using FESEM, EDS, EDX-mapping, and CA. According to these analyses, the synthesized MOF improved membrane properties such as hydrophilicity and porosity. Moreover, the MOF crystals were well immobilized in the polymer solution and uniformly distributed in the composite membrane. On the basis of the statistical results, PVP had a much more significant effect on adsorption percentage than MOF. In accordance with the Design-Expert result, the optimum structure of the MOF functionalized membrane containing 3.6 wt% of NH
2
-MIL-53(Fe) and 0.4 wt% of PVP exhibited a removal percentage of 87% and flux of 101 L m
−2
h
−1
. Investigation of the effect of TDS did not indicate any interference with Cr(VI) adsorption by the adsorbent. Additionally, membrane repeatability and regeneration tests, used in five cycles, confirmed the membrane's long-term durability and performance.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10924-022-02477-3</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0001-9816-764X</orcidid></addata></record> |
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| subjects | Adsorption Chemistry Chemistry and Materials Science Chromium Crystals Design Design optimization Environmental Chemistry Environmental Engineering/Biotechnology Fluctuations Groundwater Groundwater pollution Industrial Chemistry/Chemical Engineering Iron Materials Science Membrane structure Membrane structures Membranes Metal-organic frameworks Original Paper Polyethersulfones Polymer Sciences Polymers Polyvinylpyrrolidone Porosity Selective adsorption Synthesis Ultrafiltration |
| title | Using Design-Expert to Optimize the Properties of a Polyethersulfone Ultrafiltration Membrane Through the Incorporation of NH2-MIL-53(Fe) and PVP for Maximum Cr(VI) Removal and Flux |
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