Amine-catalyzed site- and stereo-selective coupling of epoxy amines and carbon dioxide to construct oxazolidinones

A non-metal catalyzed coupling of epoxy amines and CO 2 was achieved using readily available tertiary amines, under atmospheric pressure of CO 2 in the absence of any co-catalyst or additive. A high selectivity was obtained, as oxazolidinones were formed almost exclusively in most cases, while negli...

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Veröffentlicht in:	Organic Chemistry Frontiers 2022-08, Vol.9 (16), p.4294-4300
Hauptverfasser:	Qiu, Wenqin, Jin, Feng, Hao, Yanhong, Bao, Xiaoguang, Yuan, Dan, Yao, Yingming
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkoxides Amines Antibiotics Carbon dioxide Carbonates Catalysts Coupling Epoxides Intermediates Linezolid Nucleophiles Organic chemistry Oxazolidinones Ring opening Selectivity
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