Synthesis and characterization of eggshell membrane polymer-TiO2 nanocomposite for newly synthesized ionic liquid release
This work includes the synthesis of a new ionic liquid (IL) derived from benzisothiazolinon (Bit) by the reaction of benzisothiazolinon with HCl at room temperature. This ionic liquid (BitIL) was characterized using FTIR, 1 HNMR, 13 C-NMR, and elemental analysis. Furthermore, eggshell membrane prote...
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| Veröffentlicht in: | Journal of the Iranian Chemical Society 2022-09, Vol.19 (9), p.4005-4015 |
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| container_title | Journal of the Iranian Chemical Society |
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| creator | Alheety, Mustafa A. Majeed, Abdulwahhab H. Ali, Aisha H. Mohammed, Leqaa A. Destagul, Ali Singh, Pramod K. |
| description | This work includes the synthesis of a new ionic liquid (IL) derived from benzisothiazolinon (Bit) by the reaction of benzisothiazolinon with HCl at room temperature. This ionic liquid (BitIL) was characterized using FTIR,
1
HNMR,
13
C-NMR, and elemental analysis. Furthermore, eggshell membrane protein polymer (ESMP) was used as a natural polymer to prepare its nanocomposite with titanium oxide nanoparticles (TiO
2
NPs) (ESMP-TiO
2
). At the end of the synthesis route, the as-prepared benzisothiazolinon ionic liquid (BitIL) was grafted on the surface of the nanocomposite to synthesis benzisothiazolinon ionic liquid@ eggshell membrane protein polymer–titanium oxide (BitIL@ESMP-TiO
2
) nanocomposite by the one-pot method. The BitIL@ESMP-TiO
2
nanocomposite was characterized using FTIR, XRD, and TEM. Moreover, the kinetics of in vitro release of BitIL from BitIL@ESMP-TiO
2
was studied using Korsmeyer and Peppas equation at two different temperatures and pHs. From the results, it was found that the BitIL released from ESMP-TiO
2
was about 85%, at 37 °C. Furthermore, the pH = 1.2 (stomach acidity) produced
n
values of 0.645 and 0.761, indicating the prevalence of anomalous type, whereas the pH = 7.2 (blood acidity) produced quasi-Fickian type diffusion. |
| doi_str_mv | 10.1007/s13738-022-02584-x |
| format | Article |
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1
HNMR,
13
C-NMR, and elemental analysis. Furthermore, eggshell membrane protein polymer (ESMP) was used as a natural polymer to prepare its nanocomposite with titanium oxide nanoparticles (TiO
2
NPs) (ESMP-TiO
2
). At the end of the synthesis route, the as-prepared benzisothiazolinon ionic liquid (BitIL) was grafted on the surface of the nanocomposite to synthesis benzisothiazolinon ionic liquid@ eggshell membrane protein polymer–titanium oxide (BitIL@ESMP-TiO
2
) nanocomposite by the one-pot method. The BitIL@ESMP-TiO
2
nanocomposite was characterized using FTIR, XRD, and TEM. Moreover, the kinetics of in vitro release of BitIL from BitIL@ESMP-TiO
2
was studied using Korsmeyer and Peppas equation at two different temperatures and pHs. From the results, it was found that the BitIL released from ESMP-TiO
2
was about 85%, at 37 °C. Furthermore, the pH = 1.2 (stomach acidity) produced
n
values of 0.645 and 0.761, indicating the prevalence of anomalous type, whereas the pH = 7.2 (blood acidity) produced quasi-Fickian type diffusion.</description><identifier>ISSN: 1735-207X</identifier><identifier>EISSN: 1735-2428</identifier><identifier>DOI: 10.1007/s13738-022-02584-x</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Biochemistry ; Chemical analysis ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Ionic liquids ; Ions ; Membranes ; Nanocomposites ; Nanoparticles ; Natural polymers ; NMR ; Nuclear magnetic resonance ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polymers ; Proteins ; Room temperature ; Titanium dioxide ; Titanium oxides</subject><ispartof>Journal of the Iranian Chemical Society, 2022-09, Vol.19 (9), p.4005-4015</ispartof><rights>Iranian Chemical Society 2022</rights><rights>Iranian Chemical Society 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-5578be2cc9556e1bdfd3186a27ffbd424f8d5bb5e7102db9065fa81170a049a53</citedby><cites>FETCH-LOGICAL-c249t-5578be2cc9556e1bdfd3186a27ffbd424f8d5bb5e7102db9065fa81170a049a53</cites><orcidid>0000-0002-1314-2150</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13738-022-02584-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13738-022-02584-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Alheety, Mustafa A.</creatorcontrib><creatorcontrib>Majeed, Abdulwahhab H.</creatorcontrib><creatorcontrib>Ali, Aisha H.</creatorcontrib><creatorcontrib>Mohammed, Leqaa A.</creatorcontrib><creatorcontrib>Destagul, Ali</creatorcontrib><creatorcontrib>Singh, Pramod K.</creatorcontrib><title>Synthesis and characterization of eggshell membrane polymer-TiO2 nanocomposite for newly synthesized ionic liquid release</title><title>Journal of the Iranian Chemical Society</title><addtitle>J IRAN CHEM SOC</addtitle><description>This work includes the synthesis of a new ionic liquid (IL) derived from benzisothiazolinon (Bit) by the reaction of benzisothiazolinon with HCl at room temperature. This ionic liquid (BitIL) was characterized using FTIR,
1
HNMR,
13
C-NMR, and elemental analysis. Furthermore, eggshell membrane protein polymer (ESMP) was used as a natural polymer to prepare its nanocomposite with titanium oxide nanoparticles (TiO
2
NPs) (ESMP-TiO
2
). At the end of the synthesis route, the as-prepared benzisothiazolinon ionic liquid (BitIL) was grafted on the surface of the nanocomposite to synthesis benzisothiazolinon ionic liquid@ eggshell membrane protein polymer–titanium oxide (BitIL@ESMP-TiO
2
) nanocomposite by the one-pot method. The BitIL@ESMP-TiO
2
nanocomposite was characterized using FTIR, XRD, and TEM. Moreover, the kinetics of in vitro release of BitIL from BitIL@ESMP-TiO
2
was studied using Korsmeyer and Peppas equation at two different temperatures and pHs. From the results, it was found that the BitIL released from ESMP-TiO
2
was about 85%, at 37 °C. Furthermore, the pH = 1.2 (stomach acidity) produced
n
values of 0.645 and 0.761, indicating the prevalence of anomalous type, whereas the pH = 7.2 (blood acidity) produced quasi-Fickian type diffusion.</description><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Chemical analysis</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Membranes</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Natural polymers</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polymers</subject><subject>Proteins</subject><subject>Room temperature</subject><subject>Titanium dioxide</subject><subject>Titanium oxides</subject><issn>1735-207X</issn><issn>1735-2428</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kM9LwzAUx4MoOKf_gKeA52qSNk17lOEvGOzgBG8hbV-2jDbpkg7X_fV2duLNw-O9w_f7efBB6JaSe0qIeAg0FnEWEcaG4VkS7c_QhIqYRyxh2fnvTcTnJboKYUMIF4QnE9S_97ZbQzABK1vhcq28Kjvw5qA64yx2GsNqFdZQ17iBpvDKAm5d3Tfgo6VZMGyVdaVrWhdMB1g7jy181T0OJ_ABKjyQTIlrs92ZCnuoQQW4Rhda1QFuTnuKPp6flrPXaL54eZs9zqOSJXkXcS6yAlhZ5pynQItKVzHNUsWE1kWVsERnFS8KDoISVhU5SblWGaWCKJLkisdTdDdyW--2Owid3Lidt8NLydJcpDkn4phiY6r0LgQPWrbeNMr3khJ5VCxHxXJQLH8Uy_1QisdSGMJ2Bf4P_U_rG1kzgp8</recordid><startdate>20220901</startdate><enddate>20220901</enddate><creator>Alheety, Mustafa A.</creator><creator>Majeed, Abdulwahhab H.</creator><creator>Ali, Aisha H.</creator><creator>Mohammed, Leqaa A.</creator><creator>Destagul, Ali</creator><creator>Singh, Pramod K.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-1314-2150</orcidid></search><sort><creationdate>20220901</creationdate><title>Synthesis and characterization of eggshell membrane polymer-TiO2 nanocomposite for newly synthesized ionic liquid release</title><author>Alheety, Mustafa A. ; Majeed, Abdulwahhab H. ; Ali, Aisha H. ; Mohammed, Leqaa A. ; Destagul, Ali ; Singh, Pramod K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-5578be2cc9556e1bdfd3186a27ffbd424f8d5bb5e7102db9065fa81170a049a53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Chemical analysis</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Membranes</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Natural polymers</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polymers</topic><topic>Proteins</topic><topic>Room temperature</topic><topic>Titanium dioxide</topic><topic>Titanium oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Alheety, Mustafa A.</creatorcontrib><creatorcontrib>Majeed, Abdulwahhab H.</creatorcontrib><creatorcontrib>Ali, Aisha H.</creatorcontrib><creatorcontrib>Mohammed, Leqaa A.</creatorcontrib><creatorcontrib>Destagul, Ali</creatorcontrib><creatorcontrib>Singh, Pramod K.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the Iranian Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alheety, Mustafa A.</au><au>Majeed, Abdulwahhab H.</au><au>Ali, Aisha H.</au><au>Mohammed, Leqaa A.</au><au>Destagul, Ali</au><au>Singh, Pramod K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of eggshell membrane polymer-TiO2 nanocomposite for newly synthesized ionic liquid release</atitle><jtitle>Journal of the Iranian Chemical Society</jtitle><stitle>J IRAN CHEM SOC</stitle><date>2022-09-01</date><risdate>2022</risdate><volume>19</volume><issue>9</issue><spage>4005</spage><epage>4015</epage><pages>4005-4015</pages><issn>1735-207X</issn><eissn>1735-2428</eissn><abstract>This work includes the synthesis of a new ionic liquid (IL) derived from benzisothiazolinon (Bit) by the reaction of benzisothiazolinon with HCl at room temperature. This ionic liquid (BitIL) was characterized using FTIR,
1
HNMR,
13
C-NMR, and elemental analysis. Furthermore, eggshell membrane protein polymer (ESMP) was used as a natural polymer to prepare its nanocomposite with titanium oxide nanoparticles (TiO
2
NPs) (ESMP-TiO
2
). At the end of the synthesis route, the as-prepared benzisothiazolinon ionic liquid (BitIL) was grafted on the surface of the nanocomposite to synthesis benzisothiazolinon ionic liquid@ eggshell membrane protein polymer–titanium oxide (BitIL@ESMP-TiO
2
) nanocomposite by the one-pot method. The BitIL@ESMP-TiO
2
nanocomposite was characterized using FTIR, XRD, and TEM. Moreover, the kinetics of in vitro release of BitIL from BitIL@ESMP-TiO
2
was studied using Korsmeyer and Peppas equation at two different temperatures and pHs. From the results, it was found that the BitIL released from ESMP-TiO
2
was about 85%, at 37 °C. Furthermore, the pH = 1.2 (stomach acidity) produced
n
values of 0.645 and 0.761, indicating the prevalence of anomalous type, whereas the pH = 7.2 (blood acidity) produced quasi-Fickian type diffusion.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13738-022-02584-x</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-1314-2150</orcidid></addata></record> |
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| subjects | Analytical Chemistry Biochemistry Chemical analysis Chemical synthesis Chemistry Chemistry and Materials Science Inorganic Chemistry Ionic liquids Ions Membranes Nanocomposites Nanoparticles Natural polymers NMR Nuclear magnetic resonance Organic Chemistry Original Paper Physical Chemistry Polymers Proteins Room temperature Titanium dioxide Titanium oxides |
| title | Synthesis and characterization of eggshell membrane polymer-TiO2 nanocomposite for newly synthesized ionic liquid release |
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