High photoluminescence quantum yield near-infrared emission from a lead-free ytterbium-doped double perovskite
When excited by photons with energies greater than 2.2 eV, the bandgap energy, Yb-doped Cs 2 AgBiBr 6 thin films synthesized via physical vapor deposition emit strong near-infrared luminescence centered at ∼1.24 eV via the Yb 3+ 2 F 5/2 → 2 F 7/2 electronic transition. Robust, reproducible, and stab...
Gespeichert in:
| Veröffentlicht in: | Materials horizons 2022-08, Vol.9 (8), p.2191-2197 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2197 |
|---|---|
| container_issue | 8 |
| container_start_page | 2191 |
| container_title | Materials horizons |
| container_volume | 9 |
| creator | Tran, Minh N Cleveland, Iver J Geniesse, Joseph R Aydil, Eray S |
| description | When excited by photons with energies greater than 2.2 eV, the bandgap energy, Yb-doped Cs
2
AgBiBr
6
thin films synthesized
via
physical vapor deposition emit strong near-infrared luminescence centered at ∼1.24 eV
via
the Yb
3+ 2
F
5/2
→
2
F
7/2
electronic transition. Robust, reproducible, and stable photoluminescence quantum yields (PLQY) as high as 82.5% are achieved with Cs
2
AgBiBr
6
films doped with 8% Yb. This high PLQY indicates facile and efficient energy transfer from the perovskite host, Cs
2
AgBiBr
6
, to Yb, making Cs
2
AgBiBr
6
the most promising lead-free down-conversion material.
Yb
3+
ions substitute into Cs
2
AgBiBr
6
, specifically into the AgBr
6
5−
and/or BiBr
6
3−
octahedra, leading to a lead-free halide perovskite that converts UV and blue photons to near infrared photons with record 82.5% photoluminescence quantum yield. |
| doi_str_mv | 10.1039/d2mh00483f |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_proquest_journals_2696831325</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2696831325</sourcerecordid><originalsourceid>FETCH-LOGICAL-c378t-b640977325c09047e5759fef8b003235495767636ed9e75fb1cacd61d4ce2dfb3</originalsourceid><addsrcrecordid>eNpd0cFLHDEYBfAgLVWsl96VQC9SGJtJJsnMUVbtCpZe9Dxkki9udCYZk4mw_33Trm6hpwTy4_HIQ-hLTS5qwrrvhk4bQpqW2QN0RAmvK8E4_7C_N_IQnaT0RAipWcNJSz6hQ8ZF17SCHiG_do8bPG_CEsY8OQ9Jg9eAX7LyS57w1sFosAcVK-dtVBEMhsml5ILHNoYJKzyCMpWNAHi7LBAHl6fKhLlIE_IwAp4hhtf07Bb4jD5aNSY4eTuP0cPN9f1qXd39-nG7uryrNJPtUg2iIZ2UjHJNOtJI4JJ3Fmw7EMIo403HpZCCCTAdSG6HWittRG0aDdTYgR2j813uHMNLhrT0pbOGcVQeQk49FSWwpZyJQr_-R59Cjr60K6oTLatLjaK-7ZSOIaUItp-jm1Tc9jXp_wzRX9Gf679D3BR89haZhwnMnr5_ewGnOxCT3r_-W5L9Bj_OjaI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2696831325</pqid></control><display><type>article</type><title>High photoluminescence quantum yield near-infrared emission from a lead-free ytterbium-doped double perovskite</title><source>Royal Society Of Chemistry Journals</source><source>Alma/SFX Local Collection</source><creator>Tran, Minh N ; Cleveland, Iver J ; Geniesse, Joseph R ; Aydil, Eray S</creator><creatorcontrib>Tran, Minh N ; Cleveland, Iver J ; Geniesse, Joseph R ; Aydil, Eray S</creatorcontrib><description>When excited by photons with energies greater than 2.2 eV, the bandgap energy, Yb-doped Cs
2
AgBiBr
6
thin films synthesized
via
physical vapor deposition emit strong near-infrared luminescence centered at ∼1.24 eV
via
the Yb
3+ 2
F
5/2
→
2
F
7/2
electronic transition. Robust, reproducible, and stable photoluminescence quantum yields (PLQY) as high as 82.5% are achieved with Cs
2
AgBiBr
6
films doped with 8% Yb. This high PLQY indicates facile and efficient energy transfer from the perovskite host, Cs
2
AgBiBr
6
, to Yb, making Cs
2
AgBiBr
6
the most promising lead-free down-conversion material.
Yb
3+
ions substitute into Cs
2
AgBiBr
6
, specifically into the AgBr
6
5−
and/or BiBr
6
3−
octahedra, leading to a lead-free halide perovskite that converts UV and blue photons to near infrared photons with record 82.5% photoluminescence quantum yield.</description><identifier>ISSN: 2051-6347</identifier><identifier>EISSN: 2051-6355</identifier><identifier>DOI: 10.1039/d2mh00483f</identifier><identifier>PMID: 35694862</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Energy gap ; Energy transfer ; Lead free ; Near infrared radiation ; Perovskites ; Photoluminescence ; Physical vapor deposition ; Thin films ; Ytterbium</subject><ispartof>Materials horizons, 2022-08, Vol.9 (8), p.2191-2197</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c378t-b640977325c09047e5759fef8b003235495767636ed9e75fb1cacd61d4ce2dfb3</citedby><cites>FETCH-LOGICAL-c378t-b640977325c09047e5759fef8b003235495767636ed9e75fb1cacd61d4ce2dfb3</cites><orcidid>0000-0001-9519-9435 ; 0000-0002-8377-9480</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27928,27929</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35694862$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Tran, Minh N</creatorcontrib><creatorcontrib>Cleveland, Iver J</creatorcontrib><creatorcontrib>Geniesse, Joseph R</creatorcontrib><creatorcontrib>Aydil, Eray S</creatorcontrib><title>High photoluminescence quantum yield near-infrared emission from a lead-free ytterbium-doped double perovskite</title><title>Materials horizons</title><addtitle>Mater Horiz</addtitle><description>When excited by photons with energies greater than 2.2 eV, the bandgap energy, Yb-doped Cs
2
AgBiBr
6
thin films synthesized
via
physical vapor deposition emit strong near-infrared luminescence centered at ∼1.24 eV
via
the Yb
3+ 2
F
5/2
→
2
F
7/2
electronic transition. Robust, reproducible, and stable photoluminescence quantum yields (PLQY) as high as 82.5% are achieved with Cs
2
AgBiBr
6
films doped with 8% Yb. This high PLQY indicates facile and efficient energy transfer from the perovskite host, Cs
2
AgBiBr
6
, to Yb, making Cs
2
AgBiBr
6
the most promising lead-free down-conversion material.
Yb
3+
ions substitute into Cs
2
AgBiBr
6
, specifically into the AgBr
6
5−
and/or BiBr
6
3−
octahedra, leading to a lead-free halide perovskite that converts UV and blue photons to near infrared photons with record 82.5% photoluminescence quantum yield.</description><subject>Energy gap</subject><subject>Energy transfer</subject><subject>Lead free</subject><subject>Near infrared radiation</subject><subject>Perovskites</subject><subject>Photoluminescence</subject><subject>Physical vapor deposition</subject><subject>Thin films</subject><subject>Ytterbium</subject><issn>2051-6347</issn><issn>2051-6355</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpd0cFLHDEYBfAgLVWsl96VQC9SGJtJJsnMUVbtCpZe9Dxkki9udCYZk4mw_33Trm6hpwTy4_HIQ-hLTS5qwrrvhk4bQpqW2QN0RAmvK8E4_7C_N_IQnaT0RAipWcNJSz6hQ8ZF17SCHiG_do8bPG_CEsY8OQ9Jg9eAX7LyS57w1sFosAcVK-dtVBEMhsml5ILHNoYJKzyCMpWNAHi7LBAHl6fKhLlIE_IwAp4hhtf07Bb4jD5aNSY4eTuP0cPN9f1qXd39-nG7uryrNJPtUg2iIZ2UjHJNOtJI4JJ3Fmw7EMIo403HpZCCCTAdSG6HWittRG0aDdTYgR2j813uHMNLhrT0pbOGcVQeQk49FSWwpZyJQr_-R59Cjr60K6oTLatLjaK-7ZSOIaUItp-jm1Tc9jXp_wzRX9Gf679D3BR89haZhwnMnr5_ewGnOxCT3r_-W5L9Bj_OjaI</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>Tran, Minh N</creator><creator>Cleveland, Iver J</creator><creator>Geniesse, Joseph R</creator><creator>Aydil, Eray S</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-9519-9435</orcidid><orcidid>https://orcid.org/0000-0002-8377-9480</orcidid></search><sort><creationdate>20220801</creationdate><title>High photoluminescence quantum yield near-infrared emission from a lead-free ytterbium-doped double perovskite</title><author>Tran, Minh N ; Cleveland, Iver J ; Geniesse, Joseph R ; Aydil, Eray S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c378t-b640977325c09047e5759fef8b003235495767636ed9e75fb1cacd61d4ce2dfb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Energy gap</topic><topic>Energy transfer</topic><topic>Lead free</topic><topic>Near infrared radiation</topic><topic>Perovskites</topic><topic>Photoluminescence</topic><topic>Physical vapor deposition</topic><topic>Thin films</topic><topic>Ytterbium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tran, Minh N</creatorcontrib><creatorcontrib>Cleveland, Iver J</creatorcontrib><creatorcontrib>Geniesse, Joseph R</creatorcontrib><creatorcontrib>Aydil, Eray S</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Materials horizons</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tran, Minh N</au><au>Cleveland, Iver J</au><au>Geniesse, Joseph R</au><au>Aydil, Eray S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High photoluminescence quantum yield near-infrared emission from a lead-free ytterbium-doped double perovskite</atitle><jtitle>Materials horizons</jtitle><addtitle>Mater Horiz</addtitle><date>2022-08-01</date><risdate>2022</risdate><volume>9</volume><issue>8</issue><spage>2191</spage><epage>2197</epage><pages>2191-2197</pages><issn>2051-6347</issn><eissn>2051-6355</eissn><abstract>When excited by photons with energies greater than 2.2 eV, the bandgap energy, Yb-doped Cs
2
AgBiBr
6
thin films synthesized
via
physical vapor deposition emit strong near-infrared luminescence centered at ∼1.24 eV
via
the Yb
3+ 2
F
5/2
→
2
F
7/2
electronic transition. Robust, reproducible, and stable photoluminescence quantum yields (PLQY) as high as 82.5% are achieved with Cs
2
AgBiBr
6
films doped with 8% Yb. This high PLQY indicates facile and efficient energy transfer from the perovskite host, Cs
2
AgBiBr
6
, to Yb, making Cs
2
AgBiBr
6
the most promising lead-free down-conversion material.
Yb
3+
ions substitute into Cs
2
AgBiBr
6
, specifically into the AgBr
6
5−
and/or BiBr
6
3−
octahedra, leading to a lead-free halide perovskite that converts UV and blue photons to near infrared photons with record 82.5% photoluminescence quantum yield.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35694862</pmid><doi>10.1039/d2mh00483f</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-9519-9435</orcidid><orcidid>https://orcid.org/0000-0002-8377-9480</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2051-6347 |
| ispartof | Materials horizons, 2022-08, Vol.9 (8), p.2191-2197 |
| issn | 2051-6347 2051-6355 |
| language | eng |
| recordid | cdi_proquest_journals_2696831325 |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Energy gap Energy transfer Lead free Near infrared radiation Perovskites Photoluminescence Physical vapor deposition Thin films Ytterbium |
| title | High photoluminescence quantum yield near-infrared emission from a lead-free ytterbium-doped double perovskite |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-17T08%3A04%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=High%20photoluminescence%20quantum%20yield%20near-infrared%20emission%20from%20a%20lead-free%20ytterbium-doped%20double%20perovskite&rft.jtitle=Materials%20horizons&rft.au=Tran,%20Minh%20N&rft.date=2022-08-01&rft.volume=9&rft.issue=8&rft.spage=2191&rft.epage=2197&rft.pages=2191-2197&rft.issn=2051-6347&rft.eissn=2051-6355&rft_id=info:doi/10.1039/d2mh00483f&rft_dat=%3Cproquest_rsc_p%3E2696831325%3C/proquest_rsc_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2696831325&rft_id=info:pmid/35694862&rfr_iscdi=true |