Investigation of structural, optical, and thermal properties of 2-amino-4,6-dimethylpyrimidine benzoic acid (2APB) single crystal for non-linear optical (NLO) applications
The 2-amino-4,6-dimethylpyrimidine benzoic acid (2APB) single crystal has been successfully grown by the slow evaporation method by using water as a solvent. The single-crystal X-Ray diffraction (SXRD) analysis gives knowledge about the structure and morphology of the 2APB crystal. The Powder X-ray...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2022-08, Vol.33 (22), p.17780-17792 |
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| creator | Lasalle, B. Sahaya Infant Karuppasamy, P. Pandian, Muthu Senthil Ramasamy, P. |
| description | The 2-amino-4,6-dimethylpyrimidine benzoic acid (2APB) single crystal has been successfully grown by the slow evaporation method by using water as a solvent. The single-crystal X-Ray diffraction (SXRD) analysis gives knowledge about the structure and morphology of the 2APB crystal. The Powder X-ray Diffraction (PXRD) pattern of grinded 2APB crystal was compared with standard CIF file and the peaks were indexed with their corresponding miller indices (hkl). The crystalline perfection of the grown 2APB single crystal was analysed using high-resolution X-ray diffraction (HR-XRD) measurement. The various functional groups and their vibrational assignments were studied using the Fourier-transform infrared (FTIR) spectrum analysis. The 2APB crystal has a lower cut-off wavelength of 325 nm, which is evident from the UV–visible–NIR analysis. The defects and etch pit density of 2APB crystal were examined using chemical etching studies. The 2APB crystal was thermally stable up to 140 °C, which was evident from the thermogravimetric (TG) and differential thermal analysis (DTA). The photoconductivity analysis was carried out to calculate the photo and dark current values. The laser damage threshold (LDT) value was determined using a 532 nm Nd:YAG laser in single shot mode. The third-order non-linear optical (NLO) susceptibility (χ
(3)
) value was calculated from Z-scan technique, which involves open and closed aperture measurements. |
| doi_str_mv | 10.1007/s10854-022-08643-6 |
| format | Article |
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(3)
) value was calculated from Z-scan technique, which involves open and closed aperture measurements.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-022-08643-6</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Benzoic acid ; Characterization and Evaluation of Materials ; Chemical etching ; Chemistry and Materials Science ; Crystal defects ; Crystal growth ; Crystal structure ; Cut off wavelength ; Dark current ; Differential thermal analysis ; Differential thermogravimetric analysis ; Diffraction patterns ; Etch pits ; Functional groups ; Infrared analysis ; Laser damage ; Materials Science ; Mathematical analysis ; Neodymium lasers ; Optical and Electronic Materials ; Optical properties ; Photoconductivity ; Semiconductor lasers ; Single crystals ; Spectrum analysis ; Thermal stability ; Thermodynamic properties ; YAG lasers ; Yield point</subject><ispartof>Journal of materials science. Materials in electronics, 2022-08, Vol.33 (22), p.17780-17792</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-18019dbd15ff1ae3b4431cf3d2d5784ac2a2b29cc70592d15cccae1034d47c3d3</citedby><cites>FETCH-LOGICAL-c319t-18019dbd15ff1ae3b4431cf3d2d5784ac2a2b29cc70592d15cccae1034d47c3d3</cites><orcidid>0000-0003-0513-2996</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-022-08643-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-022-08643-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Lasalle, B. Sahaya Infant</creatorcontrib><creatorcontrib>Karuppasamy, P.</creatorcontrib><creatorcontrib>Pandian, Muthu Senthil</creatorcontrib><creatorcontrib>Ramasamy, P.</creatorcontrib><title>Investigation of structural, optical, and thermal properties of 2-amino-4,6-dimethylpyrimidine benzoic acid (2APB) single crystal for non-linear optical (NLO) applications</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>The 2-amino-4,6-dimethylpyrimidine benzoic acid (2APB) single crystal has been successfully grown by the slow evaporation method by using water as a solvent. The single-crystal X-Ray diffraction (SXRD) analysis gives knowledge about the structure and morphology of the 2APB crystal. The Powder X-ray Diffraction (PXRD) pattern of grinded 2APB crystal was compared with standard CIF file and the peaks were indexed with their corresponding miller indices (hkl). The crystalline perfection of the grown 2APB single crystal was analysed using high-resolution X-ray diffraction (HR-XRD) measurement. The various functional groups and their vibrational assignments were studied using the Fourier-transform infrared (FTIR) spectrum analysis. The 2APB crystal has a lower cut-off wavelength of 325 nm, which is evident from the UV–visible–NIR analysis. The defects and etch pit density of 2APB crystal were examined using chemical etching studies. The 2APB crystal was thermally stable up to 140 °C, which was evident from the thermogravimetric (TG) and differential thermal analysis (DTA). The photoconductivity analysis was carried out to calculate the photo and dark current values. The laser damage threshold (LDT) value was determined using a 532 nm Nd:YAG laser in single shot mode. The third-order non-linear optical (NLO) susceptibility (χ
(3)
) value was calculated from Z-scan technique, which involves open and closed aperture measurements.</description><subject>Benzoic acid</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical etching</subject><subject>Chemistry and Materials Science</subject><subject>Crystal defects</subject><subject>Crystal growth</subject><subject>Crystal structure</subject><subject>Cut off wavelength</subject><subject>Dark current</subject><subject>Differential thermal analysis</subject><subject>Differential thermogravimetric analysis</subject><subject>Diffraction patterns</subject><subject>Etch pits</subject><subject>Functional groups</subject><subject>Infrared analysis</subject><subject>Laser damage</subject><subject>Materials Science</subject><subject>Mathematical analysis</subject><subject>Neodymium lasers</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Photoconductivity</subject><subject>Semiconductor lasers</subject><subject>Single crystals</subject><subject>Spectrum analysis</subject><subject>Thermal stability</subject><subject>Thermodynamic properties</subject><subject>YAG lasers</subject><subject>Yield point</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kctKAzEYhYMoWKsv4CrgpkKjuc1tWYs3KOpCwV1Ik0yNTJMxSYX6Sr6kqVXcuUoC3znn_3MAOCb4jGBcnUeC64IjTCnCdckZKnfAgBQVQ7ymz7tggJuiQrygdB8cxPiKMc5UPQCft-7dxGQXMlnvoG9hTGGl0irIbgx9n6zaXKTTML2YsJQd7IPvTUjWxA1OkVxa5xEfl0jbpUkv665fB7u02joD58Z9eKugVFbDEZ08XJzCaN2iM1CFdUzZr_UBOu9Ql3kZfjPh6G52fwpl33f5uRkuHoK9VnbRHP2cQ_B0dfk4vUGz--vb6WSGFCNNQqTGpNFzTYq2JdKwOeeMqJZpqouq5lJRSee0UarCRUMzppSShmDGNa8U02wITra-edO3Vf4d8epXweVIQcumLFhOYJmiW0oFH2Mwrejz1jKsBcFiU4rYliJyKeK7FFFmEduKYobdwoQ_639UXzBSkgA</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>Lasalle, B. Sahaya Infant</creator><creator>Karuppasamy, P.</creator><creator>Pandian, Muthu Senthil</creator><creator>Ramasamy, P.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>S0W</scope><orcidid>https://orcid.org/0000-0003-0513-2996</orcidid></search><sort><creationdate>20220801</creationdate><title>Investigation of structural, optical, and thermal properties of 2-amino-4,6-dimethylpyrimidine benzoic acid (2APB) single crystal for non-linear optical (NLO) applications</title><author>Lasalle, B. Sahaya Infant ; Karuppasamy, P. ; Pandian, Muthu Senthil ; Ramasamy, P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-18019dbd15ff1ae3b4431cf3d2d5784ac2a2b29cc70592d15cccae1034d47c3d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Benzoic acid</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical etching</topic><topic>Chemistry and Materials Science</topic><topic>Crystal defects</topic><topic>Crystal growth</topic><topic>Crystal structure</topic><topic>Cut off wavelength</topic><topic>Dark current</topic><topic>Differential thermal analysis</topic><topic>Differential thermogravimetric analysis</topic><topic>Diffraction patterns</topic><topic>Etch pits</topic><topic>Functional groups</topic><topic>Infrared analysis</topic><topic>Laser damage</topic><topic>Materials Science</topic><topic>Mathematical analysis</topic><topic>Neodymium lasers</topic><topic>Optical and Electronic Materials</topic><topic>Optical properties</topic><topic>Photoconductivity</topic><topic>Semiconductor lasers</topic><topic>Single crystals</topic><topic>Spectrum analysis</topic><topic>Thermal stability</topic><topic>Thermodynamic properties</topic><topic>YAG lasers</topic><topic>Yield point</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lasalle, B. Sahaya Infant</creatorcontrib><creatorcontrib>Karuppasamy, P.</creatorcontrib><creatorcontrib>Pandian, Muthu Senthil</creatorcontrib><creatorcontrib>Ramasamy, P.</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lasalle, B. Sahaya Infant</au><au>Karuppasamy, P.</au><au>Pandian, Muthu Senthil</au><au>Ramasamy, P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation of structural, optical, and thermal properties of 2-amino-4,6-dimethylpyrimidine benzoic acid (2APB) single crystal for non-linear optical (NLO) applications</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2022-08-01</date><risdate>2022</risdate><volume>33</volume><issue>22</issue><spage>17780</spage><epage>17792</epage><pages>17780-17792</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>The 2-amino-4,6-dimethylpyrimidine benzoic acid (2APB) single crystal has been successfully grown by the slow evaporation method by using water as a solvent. The single-crystal X-Ray diffraction (SXRD) analysis gives knowledge about the structure and morphology of the 2APB crystal. The Powder X-ray Diffraction (PXRD) pattern of grinded 2APB crystal was compared with standard CIF file and the peaks were indexed with their corresponding miller indices (hkl). The crystalline perfection of the grown 2APB single crystal was analysed using high-resolution X-ray diffraction (HR-XRD) measurement. The various functional groups and their vibrational assignments were studied using the Fourier-transform infrared (FTIR) spectrum analysis. The 2APB crystal has a lower cut-off wavelength of 325 nm, which is evident from the UV–visible–NIR analysis. The defects and etch pit density of 2APB crystal were examined using chemical etching studies. The 2APB crystal was thermally stable up to 140 °C, which was evident from the thermogravimetric (TG) and differential thermal analysis (DTA). The photoconductivity analysis was carried out to calculate the photo and dark current values. The laser damage threshold (LDT) value was determined using a 532 nm Nd:YAG laser in single shot mode. The third-order non-linear optical (NLO) susceptibility (χ
(3)
) value was calculated from Z-scan technique, which involves open and closed aperture measurements.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-022-08643-6</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0003-0513-2996</orcidid></addata></record> |
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| ispartof | Journal of materials science. Materials in electronics, 2022-08, Vol.33 (22), p.17780-17792 |
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| subjects | Benzoic acid Characterization and Evaluation of Materials Chemical etching Chemistry and Materials Science Crystal defects Crystal growth Crystal structure Cut off wavelength Dark current Differential thermal analysis Differential thermogravimetric analysis Diffraction patterns Etch pits Functional groups Infrared analysis Laser damage Materials Science Mathematical analysis Neodymium lasers Optical and Electronic Materials Optical properties Photoconductivity Semiconductor lasers Single crystals Spectrum analysis Thermal stability Thermodynamic properties YAG lasers Yield point |
| title | Investigation of structural, optical, and thermal properties of 2-amino-4,6-dimethylpyrimidine benzoic acid (2APB) single crystal for non-linear optical (NLO) applications |
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