Comparative performance and ecotoxicity assessment of Y2(CO3)3, ZnO/TiO2, and Fe3O4 nanoparticles for arsenic removal from water
The application of nanomaterials to remove arsenic from water represents one of the most promising remediation methods nowadays. In this study, three active materials, Y2(CO3)3, ZnO/TiO2, and Fe3O4, with different structural and morphological properties, were evaluated for their As(v) adsorption cap...
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Veröffentlicht in: | Environmental science water research & technology 2022, Vol.8 (8), p.1719-1730 |
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creator | Salazar, H Martins, P M Batista, Daniela Shejale, K P Sharma, R K Krishnapriya, R Ferdov, S Botelho, G Fidalgo-Marijuan, A Cássio, Fernanda Lanceros-Mendez, S |
description | The application of nanomaterials to remove arsenic from water represents one of the most promising remediation methods nowadays. In this study, three active materials, Y2(CO3)3, ZnO/TiO2, and Fe3O4, with different structural and morphological properties, were evaluated for their As(v) adsorption capacity in contaminated water. Thus, the adsorption behaviour was assessed, including the influence of pH, adsorption kinetics, and isotherms. This work demonstrates that the active materials show a high adsorption performance, with adsorption efficiencies always close to 100%, leading to maximum adsorption capacities of 32.8, 37.3, and 35.8 mg g−1 for Y2(CO3)3, ZnO/TiO2, and Fe3O4, respectively. The effects of suspended sorbent nanomaterials on Daphnia magna allowed us to estimate the lethal concentration that kills 50% of the test specimens (LC50) of 6.57 × 103 mg L−1, 28.7 mg L−1, and 1.91 × 106 mg L−1 for Fe3O4, ZnO/TiO2 and Y2(CO3)3, respectively. Overall, this study confirmed the investigated materials' suitability for arsenic water remediation applications. |
doi_str_mv | 10.1039/d1ew00933h |
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In this study, three active materials, Y2(CO3)3, ZnO/TiO2, and Fe3O4, with different structural and morphological properties, were evaluated for their As(v) adsorption capacity in contaminated water. Thus, the adsorption behaviour was assessed, including the influence of pH, adsorption kinetics, and isotherms. This work demonstrates that the active materials show a high adsorption performance, with adsorption efficiencies always close to 100%, leading to maximum adsorption capacities of 32.8, 37.3, and 35.8 mg g−1 for Y2(CO3)3, ZnO/TiO2, and Fe3O4, respectively. The effects of suspended sorbent nanomaterials on Daphnia magna allowed us to estimate the lethal concentration that kills 50% of the test specimens (LC50) of 6.57 × 103 mg L−1, 28.7 mg L−1, and 1.91 × 106 mg L−1 for Fe3O4, ZnO/TiO2 and Y2(CO3)3, respectively. Overall, this study confirmed the investigated materials' suitability for arsenic water remediation applications.</description><identifier>ISSN: 2053-1400</identifier><identifier>EISSN: 2053-1419</identifier><identifier>DOI: 10.1039/d1ew00933h</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Adsorption ; Arsenic ; Arsenic removal ; Freshwater crustaceans ; Iron oxides ; Kinetics ; Lethal limits ; Mortality causes ; Nanomaterials ; Nanoparticles ; Nanotechnology ; Pollutant removal ; Remediation ; Sorbents ; Titanium dioxide ; Toxicity tests ; Water pollution ; Zinc oxide</subject><ispartof>Environmental science water research & technology, 2022, Vol.8 (8), p.1719-1730</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Salazar, H</creatorcontrib><creatorcontrib>Martins, P M</creatorcontrib><creatorcontrib>Batista, Daniela</creatorcontrib><creatorcontrib>Shejale, K P</creatorcontrib><creatorcontrib>Sharma, R K</creatorcontrib><creatorcontrib>Krishnapriya, R</creatorcontrib><creatorcontrib>Ferdov, S</creatorcontrib><creatorcontrib>Botelho, G</creatorcontrib><creatorcontrib>Fidalgo-Marijuan, A</creatorcontrib><creatorcontrib>Cássio, Fernanda</creatorcontrib><creatorcontrib>Lanceros-Mendez, S</creatorcontrib><title>Comparative performance and ecotoxicity assessment of Y2(CO3)3, ZnO/TiO2, and Fe3O4 nanoparticles for arsenic removal from water</title><title>Environmental science water research & technology</title><description>The application of nanomaterials to remove arsenic from water represents one of the most promising remediation methods nowadays. In this study, three active materials, Y2(CO3)3, ZnO/TiO2, and Fe3O4, with different structural and morphological properties, were evaluated for their As(v) adsorption capacity in contaminated water. Thus, the adsorption behaviour was assessed, including the influence of pH, adsorption kinetics, and isotherms. This work demonstrates that the active materials show a high adsorption performance, with adsorption efficiencies always close to 100%, leading to maximum adsorption capacities of 32.8, 37.3, and 35.8 mg g−1 for Y2(CO3)3, ZnO/TiO2, and Fe3O4, respectively. The effects of suspended sorbent nanomaterials on Daphnia magna allowed us to estimate the lethal concentration that kills 50% of the test specimens (LC50) of 6.57 × 103 mg L−1, 28.7 mg L−1, and 1.91 × 106 mg L−1 for Fe3O4, ZnO/TiO2 and Y2(CO3)3, respectively. Overall, this study confirmed the investigated materials' suitability for arsenic water remediation applications.</description><subject>Adsorption</subject><subject>Arsenic</subject><subject>Arsenic removal</subject><subject>Freshwater crustaceans</subject><subject>Iron oxides</subject><subject>Kinetics</subject><subject>Lethal limits</subject><subject>Mortality causes</subject><subject>Nanomaterials</subject><subject>Nanoparticles</subject><subject>Nanotechnology</subject><subject>Pollutant removal</subject><subject>Remediation</subject><subject>Sorbents</subject><subject>Titanium dioxide</subject><subject>Toxicity tests</subject><subject>Water pollution</subject><subject>Zinc oxide</subject><issn>2053-1400</issn><issn>2053-1419</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNo9j01LAzEYhIMoWGov_oKAF4WuffOx6eYoi1WhsJd60EvJZt_FLd2kJmmrN3-6i4qnGRjmGYaQSwa3DISeNQyPAFqItxMy4pCLjEmmT_89wDmZxLgBAKbEEIkR-Sp9vzPBpO6AdIeh9aE3ziI1rqFoffIfne3SJzUxYow9ukR9S1_4dVmJGzGlr66arbqKT38aCxSVpM44P0BTZ7cY6YCkJkR0naUBe38wW9oG39OjSRguyFlrthEnfzomz4v7VfmYLauHp_Jume24lCnjTSNrVIXWtlAcgUluiqK1xrK6tq3O8-EOyPlc5DWDea1EAwqtyq00NYdGjMnVL3cX_PseY1pv_D64YXLNlc6lVlwx8Q2f8WED</recordid><startdate>2022</startdate><enddate>2022</enddate><creator>Salazar, H</creator><creator>Martins, P M</creator><creator>Batista, Daniela</creator><creator>Shejale, K P</creator><creator>Sharma, R K</creator><creator>Krishnapriya, R</creator><creator>Ferdov, S</creator><creator>Botelho, G</creator><creator>Fidalgo-Marijuan, A</creator><creator>Cássio, Fernanda</creator><creator>Lanceros-Mendez, S</creator><general>Royal Society of Chemistry</general><scope>7QH</scope><scope>7ST</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H97</scope><scope>L.G</scope><scope>SOI</scope></search><sort><creationdate>2022</creationdate><title>Comparative performance and ecotoxicity assessment of Y2(CO3)3, ZnO/TiO2, and Fe3O4 nanoparticles for arsenic removal from water</title><author>Salazar, H ; Martins, P M ; Batista, Daniela ; Shejale, K P ; Sharma, R K ; Krishnapriya, R ; Ferdov, S ; Botelho, G ; Fidalgo-Marijuan, A ; Cássio, Fernanda ; Lanceros-Mendez, S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p244t-2dd4be6899c862e0142a88fcac1bbcf955193047735b107b63d06ec65c4ab20d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Adsorption</topic><topic>Arsenic</topic><topic>Arsenic removal</topic><topic>Freshwater crustaceans</topic><topic>Iron oxides</topic><topic>Kinetics</topic><topic>Lethal limits</topic><topic>Mortality causes</topic><topic>Nanomaterials</topic><topic>Nanoparticles</topic><topic>Nanotechnology</topic><topic>Pollutant removal</topic><topic>Remediation</topic><topic>Sorbents</topic><topic>Titanium dioxide</topic><topic>Toxicity tests</topic><topic>Water pollution</topic><topic>Zinc oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Salazar, H</creatorcontrib><creatorcontrib>Martins, P M</creatorcontrib><creatorcontrib>Batista, Daniela</creatorcontrib><creatorcontrib>Shejale, K P</creatorcontrib><creatorcontrib>Sharma, R K</creatorcontrib><creatorcontrib>Krishnapriya, R</creatorcontrib><creatorcontrib>Ferdov, S</creatorcontrib><creatorcontrib>Botelho, G</creatorcontrib><creatorcontrib>Fidalgo-Marijuan, A</creatorcontrib><creatorcontrib>Cássio, Fernanda</creatorcontrib><creatorcontrib>Lanceros-Mendez, S</creatorcontrib><collection>Aqualine</collection><collection>Environment Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Environment Abstracts</collection><jtitle>Environmental science water research & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Salazar, H</au><au>Martins, P M</au><au>Batista, Daniela</au><au>Shejale, K P</au><au>Sharma, R K</au><au>Krishnapriya, R</au><au>Ferdov, S</au><au>Botelho, G</au><au>Fidalgo-Marijuan, A</au><au>Cássio, Fernanda</au><au>Lanceros-Mendez, S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Comparative performance and ecotoxicity assessment of Y2(CO3)3, ZnO/TiO2, and Fe3O4 nanoparticles for arsenic removal from water</atitle><jtitle>Environmental science water research & technology</jtitle><date>2022</date><risdate>2022</risdate><volume>8</volume><issue>8</issue><spage>1719</spage><epage>1730</epage><pages>1719-1730</pages><issn>2053-1400</issn><eissn>2053-1419</eissn><abstract>The application of nanomaterials to remove arsenic from water represents one of the most promising remediation methods nowadays. In this study, three active materials, Y2(CO3)3, ZnO/TiO2, and Fe3O4, with different structural and morphological properties, were evaluated for their As(v) adsorption capacity in contaminated water. Thus, the adsorption behaviour was assessed, including the influence of pH, adsorption kinetics, and isotherms. This work demonstrates that the active materials show a high adsorption performance, with adsorption efficiencies always close to 100%, leading to maximum adsorption capacities of 32.8, 37.3, and 35.8 mg g−1 for Y2(CO3)3, ZnO/TiO2, and Fe3O4, respectively. The effects of suspended sorbent nanomaterials on Daphnia magna allowed us to estimate the lethal concentration that kills 50% of the test specimens (LC50) of 6.57 × 103 mg L−1, 28.7 mg L−1, and 1.91 × 106 mg L−1 for Fe3O4, ZnO/TiO2 and Y2(CO3)3, respectively. Overall, this study confirmed the investigated materials' suitability for arsenic water remediation applications.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1ew00933h</doi><tpages>12</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Adsorption Arsenic Arsenic removal Freshwater crustaceans Iron oxides Kinetics Lethal limits Mortality causes Nanomaterials Nanoparticles Nanotechnology Pollutant removal Remediation Sorbents Titanium dioxide Toxicity tests Water pollution Zinc oxide |
title | Comparative performance and ecotoxicity assessment of Y2(CO3)3, ZnO/TiO2, and Fe3O4 nanoparticles for arsenic removal from water |
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