Dearomative oxyphosphorylation of indoles enables facile access to 2,2-disubstituted indolin-3-ones

A highly efficient oxidative dearomatization of indoles with H -phosphorus oxides in the presence of TEMPO oxoammonium salt has been demonstrated. Through the intramolecular oxidative dearomatization of indoles and subsequent intermolecular nucleophilic addition with phosphorus nucleophile, a variet...

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Veröffentlicht in:	Organic & biomolecular chemistry 2022-07, Vol.2 (29), p.5721-5725
Hauptverfasser:	Xiong, Ting, Zhou, Xingcui, Jiang, Jun
Format:	Artikel
Sprache:	eng
Schlagworte:	Indoles Nucleophiles Phosphorus Phosphorus oxides Substrates
Online-Zugang:	Volltext
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