An acrylate-based quasi-solid polymer electrolyte incorporating a novel dinitrile poly(ethylene glycol) plasticizer for lithium-ion batteries
The performance of solid polymer electrolytes is characterized by lower ionic conductivity than conventional liquid electrolytes but provides advantages in terms of operational safety. A quasi-solid polymer electrolyte (QSPE) based on a new plasticizer 4,7,10,13-tetraoxahexadecane-1,16-dinitrile (bC...
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| Veröffentlicht in: | Journal of materials science 2022-07, Vol.57 (28), p.13496-13514 |
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| creator | Leš, Kristian Schönewerk, Jens Glenneberg, Jens Jordan, Carmen-Simona |
| description | The performance of solid polymer electrolytes is characterized by lower ionic conductivity than conventional liquid electrolytes but provides advantages in terms of operational safety. A quasi-solid polymer electrolyte (QSPE) based on a new plasticizer 4,7,10,13-tetraoxahexadecane-1,16-dinitrile (bCN-PEG4) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) incorporated into a polyacrylates matrix was successfully prepared via UV-induced copolymerization. The matrix consists of units of trimethylolpropane ethoxylate triacrylate (ETPTA), poly(ethylene glycol) diacrylate (PEGDA), and the monoacrylate poly(ethylene glycol) methyl ether acrylate (mPEGa). The QSPE containing 55 wt% bCN-PEG4 exhibits highly uniform morphology, thermal stability > 200 °C, ionic conductivity of 1.8 × 10
−4
S cm
−1
at 30 °C, and 1.3 × 10
−3
S cm
−1
at 80 °C, coupled with very high electrochemical stability (> 5 V vs. Li/Li
+
) and a low glass transition temperature (− 55.7 °C). A cycling experiment in a Li/QPSE/Li cell setup demonstrated the compatibility toward lithium metal additionally. The bCN-PEG4 offers an overall satisfying performance as a plasticizer in a poly(ethylene oxide)-based solid polymer electrolyte. The new QSPE is an alternative to dinitrile-based (e.g., succinonitrile) or glycol ether-based (e.g., tetraglyme) plasticizers with application potential in high-voltage lithium-ion batteries.
Graphical abstract |
| doi_str_mv | 10.1007/s10853-022-07431-1 |
| format | Article |
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−4
S cm
−1
at 30 °C, and 1.3 × 10
−3
S cm
−1
at 80 °C, coupled with very high electrochemical stability (> 5 V vs. Li/Li
+
) and a low glass transition temperature (− 55.7 °C). A cycling experiment in a Li/QPSE/Li cell setup demonstrated the compatibility toward lithium metal additionally. The bCN-PEG4 offers an overall satisfying performance as a plasticizer in a poly(ethylene oxide)-based solid polymer electrolyte. The new QSPE is an alternative to dinitrile-based (e.g., succinonitrile) or glycol ether-based (e.g., tetraglyme) plasticizers with application potential in high-voltage lithium-ion batteries.
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−4
S cm
−1
at 30 °C, and 1.3 × 10
−3
S cm
−1
at 80 °C, coupled with very high electrochemical stability (> 5 V vs. Li/Li
+
) and a low glass transition temperature (− 55.7 °C). A cycling experiment in a Li/QPSE/Li cell setup demonstrated the compatibility toward lithium metal additionally. The bCN-PEG4 offers an overall satisfying performance as a plasticizer in a poly(ethylene oxide)-based solid polymer electrolyte. The new QSPE is an alternative to dinitrile-based (e.g., succinonitrile) or glycol ether-based (e.g., tetraglyme) plasticizers with application potential in high-voltage lithium-ion batteries.
Graphical abstract</description><subject>Acrylic resins</subject><subject>Batteries</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Copolymerization</subject><subject>Crystallography and Scattering Methods</subject><subject>Electric properties</subject><subject>Electrolytes</subject><subject>Energy Materials</subject><subject>Ethylene glycol</subject><subject>Ethylene oxide</subject><subject>Glass transition temperature</subject><subject>Glycol ethers</subject><subject>Ion currents</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Materials Science</subject><subject>Methyl ether</subject><subject>Molten salt electrolytes</subject><subject>Plasticizers</subject><subject>Polyelectrolytes</subject><subject>Polyethylene glycol monomethyl ether acrylate</subject><subject>Polyethylene oxide</subject><subject>Polymer industry</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Rechargeable batteries</subject><subject>Solid electrolytes</subject><subject>Solid Mechanics</subject><subject>Succinonitrile</subject><subject>Thermal stability</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>BENPR</sourceid><recordid>eNp9kc9q3DAQxkVpods0L5CToJf2oFSS9cc-LqFpA4FemrOQ5fFGQSs5krbgvkPfOUpc6C3MYRjm-4008yF0weglo1R_LYz2siOUc0K16Bhhb9COSd0R0dPuLdrR5xYXir1HH0p5oJRKzdkO_d1HbF1eg61ARltgwo8nWzwpKfgJLymsR8gYAriaW1EB--hSXlK21ccDtjim3xDw5KOv2Qd4YT5DvV8DRMCHsLoUvuAl2FK983_atDllHHy996cj8Sni0dYK2UP5iN7NNhQ4_5fP0N31t19XP8jtz-83V_tb4gTllUxOuV6qXkltmQahlKRKDaOl8-Ac19ApK9ig1CRkP2ihJyn0OE-azdM4qqE7Q5-2uUtOjyco1TykU47tScPVIBjlveqb6nJTHWwA4-OcarauxQRH71KEua1r9poxyXS7ZwP4BricSskwmyX7o82rYdQ8-2Q2n0wzw7z4ZFiDug0qTRwPkP__5RXqCaVnmGA</recordid><startdate>20220701</startdate><enddate>20220701</enddate><creator>Leš, Kristian</creator><creator>Schönewerk, Jens</creator><creator>Glenneberg, Jens</creator><creator>Jordan, Carmen-Simona</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-8361-3720</orcidid><orcidid>https://orcid.org/0000-0002-4354-4484</orcidid><orcidid>https://orcid.org/0000-0003-2713-2989</orcidid></search><sort><creationdate>20220701</creationdate><title>An acrylate-based quasi-solid polymer electrolyte incorporating a novel dinitrile poly(ethylene glycol) plasticizer for lithium-ion batteries</title><author>Leš, Kristian ; Schönewerk, Jens ; Glenneberg, Jens ; Jordan, Carmen-Simona</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c402t-dc6c8568657a17e46650669ba0f9cc27e36a41966d4589747d547bfd71fdbb693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Acrylic resins</topic><topic>Batteries</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Copolymerization</topic><topic>Crystallography and Scattering Methods</topic><topic>Electric properties</topic><topic>Electrolytes</topic><topic>Energy Materials</topic><topic>Ethylene glycol</topic><topic>Ethylene oxide</topic><topic>Glass transition temperature</topic><topic>Glycol ethers</topic><topic>Ion currents</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Materials Science</topic><topic>Methyl ether</topic><topic>Molten salt electrolytes</topic><topic>Plasticizers</topic><topic>Polyelectrolytes</topic><topic>Polyethylene glycol monomethyl ether acrylate</topic><topic>Polyethylene oxide</topic><topic>Polymer industry</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Rechargeable batteries</topic><topic>Solid electrolytes</topic><topic>Solid Mechanics</topic><topic>Succinonitrile</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Leš, Kristian</creatorcontrib><creatorcontrib>Schönewerk, Jens</creatorcontrib><creatorcontrib>Glenneberg, Jens</creatorcontrib><creatorcontrib>Jordan, Carmen-Simona</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Leš, Kristian</au><au>Schönewerk, Jens</au><au>Glenneberg, Jens</au><au>Jordan, Carmen-Simona</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An acrylate-based quasi-solid polymer electrolyte incorporating a novel dinitrile poly(ethylene glycol) plasticizer for lithium-ion batteries</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2022-07-01</date><risdate>2022</risdate><volume>57</volume><issue>28</issue><spage>13496</spage><epage>13514</epage><pages>13496-13514</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>The performance of solid polymer electrolytes is characterized by lower ionic conductivity than conventional liquid electrolytes but provides advantages in terms of operational safety. A quasi-solid polymer electrolyte (QSPE) based on a new plasticizer 4,7,10,13-tetraoxahexadecane-1,16-dinitrile (bCN-PEG4) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) incorporated into a polyacrylates matrix was successfully prepared via UV-induced copolymerization. The matrix consists of units of trimethylolpropane ethoxylate triacrylate (ETPTA), poly(ethylene glycol) diacrylate (PEGDA), and the monoacrylate poly(ethylene glycol) methyl ether acrylate (mPEGa). The QSPE containing 55 wt% bCN-PEG4 exhibits highly uniform morphology, thermal stability > 200 °C, ionic conductivity of 1.8 × 10
−4
S cm
−1
at 30 °C, and 1.3 × 10
−3
S cm
−1
at 80 °C, coupled with very high electrochemical stability (> 5 V vs. Li/Li
+
) and a low glass transition temperature (− 55.7 °C). A cycling experiment in a Li/QPSE/Li cell setup demonstrated the compatibility toward lithium metal additionally. The bCN-PEG4 offers an overall satisfying performance as a plasticizer in a poly(ethylene oxide)-based solid polymer electrolyte. The new QSPE is an alternative to dinitrile-based (e.g., succinonitrile) or glycol ether-based (e.g., tetraglyme) plasticizers with application potential in high-voltage lithium-ion batteries.
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| subjects | Acrylic resins Batteries Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Copolymerization Crystallography and Scattering Methods Electric properties Electrolytes Energy Materials Ethylene glycol Ethylene oxide Glass transition temperature Glycol ethers Ion currents Lithium Lithium-ion batteries Materials Science Methyl ether Molten salt electrolytes Plasticizers Polyelectrolytes Polyethylene glycol monomethyl ether acrylate Polyethylene oxide Polymer industry Polymer Sciences Polymers Rechargeable batteries Solid electrolytes Solid Mechanics Succinonitrile Thermal stability |
| title | An acrylate-based quasi-solid polymer electrolyte incorporating a novel dinitrile poly(ethylene glycol) plasticizer for lithium-ion batteries |
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