The High Electrocatalytic Performance of NiFeSe/CFP for Hydrogen Evolution Reaction Derived from a Prussian Blue Analogue
Non-noble-metal-based chalcogenides are promising candidates for hydrogen evolution reaction (HER) by harnessing the architectural design and the synergistic effect between the elements. Herein, a porous bimetallic selenide (NiFeSe) nanocube deposited on carbon fiber paper (NiFeSe/CFP) was synthesiz...
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| Veröffentlicht in: | Catalysts 2022-07, Vol.12 (7), p.739 |
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| creator | Guo, Yajie Liu, Yongjie Liu, Yanrong Zhang, Chunrui Jia, Kelun Su, Jibo Wang, Ke |
| description | Non-noble-metal-based chalcogenides are promising candidates for hydrogen evolution reaction (HER) by harnessing the architectural design and the synergistic effect between the elements. Herein, a porous bimetallic selenide (NiFeSe) nanocube deposited on carbon fiber paper (NiFeSe/CFP) was synthesized through a facile selenization reaction based on Prussian blue analogues (PBAs) as precursors. The NiFeSe/CFP exhibited excellent HER activity with an overpotential of just 186 mV for a current density of 10 mA cm−2 in 1.0 M KOH at ambient temperature, similar to most of the state-of-the-art transition metal chalcogenides. The corresponding Tafel slope was calculated to be 52 mV dec−1, indicating fast discharge of the proton during the HER. Furthermore, the catalyst could endure long-term catalytic tests and showed remarkable durability. The enhanced electrocatalytic performance of NiFeSe/CFP is attributed to the unique 3D porous configuration inherited from the PBA templates, enhanced charge transfer occurring at the heterogeneous interface due to the synergistic effect between the bimetallic phases, and the high conductivity improved by the formation of amorphous carbon shells during the selenization. These findings prove that the combination of inexpensive metal–organic framework precursors and hybrid metallic compounds is a feasible way to realize the performance enhancement of non-noble-metal-based chalcogenides towards alkaline HER. |
| doi_str_mv | 10.3390/catal12070739 |
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Herein, a porous bimetallic selenide (NiFeSe) nanocube deposited on carbon fiber paper (NiFeSe/CFP) was synthesized through a facile selenization reaction based on Prussian blue analogues (PBAs) as precursors. The NiFeSe/CFP exhibited excellent HER activity with an overpotential of just 186 mV for a current density of 10 mA cm−2 in 1.0 M KOH at ambient temperature, similar to most of the state-of-the-art transition metal chalcogenides. The corresponding Tafel slope was calculated to be 52 mV dec−1, indicating fast discharge of the proton during the HER. Furthermore, the catalyst could endure long-term catalytic tests and showed remarkable durability. The enhanced electrocatalytic performance of NiFeSe/CFP is attributed to the unique 3D porous configuration inherited from the PBA templates, enhanced charge transfer occurring at the heterogeneous interface due to the synergistic effect between the bimetallic phases, and the high conductivity improved by the formation of amorphous carbon shells during the selenization. These findings prove that the combination of inexpensive metal–organic framework precursors and hybrid metallic compounds is a feasible way to realize the performance enhancement of non-noble-metal-based chalcogenides towards alkaline HER.</description><identifier>ISSN: 2073-4344</identifier><identifier>EISSN: 2073-4344</identifier><identifier>DOI: 10.3390/catal12070739</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Ambient temperature ; Bimetals ; Carbon ; Carbon fibers ; Catalysts ; Chalcogenides ; Charge transfer ; Chemical properties ; Chemical reactions ; Coordination compounds ; Electric properties ; Electrochemical reactions ; Hydrogen ; Hydrogen evolution reactions ; Metal compounds ; Metal-organic frameworks ; Methods ; Morphology ; Nickel ; Noble metals ; Oxidation ; Performance enhancement ; Pigments ; Precursors ; Production processes ; Synergistic effect ; Transition metal compounds</subject><ispartof>Catalysts, 2022-07, Vol.12 (7), p.739</ispartof><rights>COPYRIGHT 2022 MDPI AG</rights><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c343t-110dcd128bff5eb9185eb68829f2b39de35f20b17ef0771ac7c71f37d492dae43</citedby><cites>FETCH-LOGICAL-c343t-110dcd128bff5eb9185eb68829f2b39de35f20b17ef0771ac7c71f37d492dae43</cites><orcidid>0000-0003-4076-1106</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Guo, Yajie</creatorcontrib><creatorcontrib>Liu, Yongjie</creatorcontrib><creatorcontrib>Liu, Yanrong</creatorcontrib><creatorcontrib>Zhang, Chunrui</creatorcontrib><creatorcontrib>Jia, Kelun</creatorcontrib><creatorcontrib>Su, Jibo</creatorcontrib><creatorcontrib>Wang, Ke</creatorcontrib><title>The High Electrocatalytic Performance of NiFeSe/CFP for Hydrogen Evolution Reaction Derived from a Prussian Blue Analogue</title><title>Catalysts</title><description>Non-noble-metal-based chalcogenides are promising candidates for hydrogen evolution reaction (HER) by harnessing the architectural design and the synergistic effect between the elements. 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The enhanced electrocatalytic performance of NiFeSe/CFP is attributed to the unique 3D porous configuration inherited from the PBA templates, enhanced charge transfer occurring at the heterogeneous interface due to the synergistic effect between the bimetallic phases, and the high conductivity improved by the formation of amorphous carbon shells during the selenization. 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Liu, Yongjie ; Liu, Yanrong ; Zhang, Chunrui ; Jia, Kelun ; Su, Jibo ; Wang, Ke</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c343t-110dcd128bff5eb9185eb68829f2b39de35f20b17ef0771ac7c71f37d492dae43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Ambient temperature</topic><topic>Bimetals</topic><topic>Carbon</topic><topic>Carbon fibers</topic><topic>Catalysts</topic><topic>Chalcogenides</topic><topic>Charge transfer</topic><topic>Chemical properties</topic><topic>Chemical reactions</topic><topic>Coordination compounds</topic><topic>Electric properties</topic><topic>Electrochemical reactions</topic><topic>Hydrogen</topic><topic>Hydrogen evolution reactions</topic><topic>Metal compounds</topic><topic>Metal-organic frameworks</topic><topic>Methods</topic><topic>Morphology</topic><topic>Nickel</topic><topic>Noble metals</topic><topic>Oxidation</topic><topic>Performance enhancement</topic><topic>Pigments</topic><topic>Precursors</topic><topic>Production processes</topic><topic>Synergistic effect</topic><topic>Transition metal compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guo, Yajie</creatorcontrib><creatorcontrib>Liu, Yongjie</creatorcontrib><creatorcontrib>Liu, Yanrong</creatorcontrib><creatorcontrib>Zhang, Chunrui</creatorcontrib><creatorcontrib>Jia, Kelun</creatorcontrib><creatorcontrib>Su, Jibo</creatorcontrib><creatorcontrib>Wang, Ke</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysts</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guo, Yajie</au><au>Liu, Yongjie</au><au>Liu, Yanrong</au><au>Zhang, Chunrui</au><au>Jia, Kelun</au><au>Su, Jibo</au><au>Wang, Ke</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The High Electrocatalytic Performance of NiFeSe/CFP for Hydrogen Evolution Reaction Derived from a Prussian Blue Analogue</atitle><jtitle>Catalysts</jtitle><date>2022-07-04</date><risdate>2022</risdate><volume>12</volume><issue>7</issue><spage>739</spage><pages>739-</pages><issn>2073-4344</issn><eissn>2073-4344</eissn><abstract>Non-noble-metal-based chalcogenides are promising candidates for hydrogen evolution reaction (HER) by harnessing the architectural design and the synergistic effect between the elements. Herein, a porous bimetallic selenide (NiFeSe) nanocube deposited on carbon fiber paper (NiFeSe/CFP) was synthesized through a facile selenization reaction based on Prussian blue analogues (PBAs) as precursors. The NiFeSe/CFP exhibited excellent HER activity with an overpotential of just 186 mV for a current density of 10 mA cm−2 in 1.0 M KOH at ambient temperature, similar to most of the state-of-the-art transition metal chalcogenides. The corresponding Tafel slope was calculated to be 52 mV dec−1, indicating fast discharge of the proton during the HER. Furthermore, the catalyst could endure long-term catalytic tests and showed remarkable durability. The enhanced electrocatalytic performance of NiFeSe/CFP is attributed to the unique 3D porous configuration inherited from the PBA templates, enhanced charge transfer occurring at the heterogeneous interface due to the synergistic effect between the bimetallic phases, and the high conductivity improved by the formation of amorphous carbon shells during the selenization. These findings prove that the combination of inexpensive metal–organic framework precursors and hybrid metallic compounds is a feasible way to realize the performance enhancement of non-noble-metal-based chalcogenides towards alkaline HER.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/catal12070739</doi><orcidid>https://orcid.org/0000-0003-4076-1106</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Ambient temperature Bimetals Carbon Carbon fibers Catalysts Chalcogenides Charge transfer Chemical properties Chemical reactions Coordination compounds Electric properties Electrochemical reactions Hydrogen Hydrogen evolution reactions Metal compounds Metal-organic frameworks Methods Morphology Nickel Noble metals Oxidation Performance enhancement Pigments Precursors Production processes Synergistic effect Transition metal compounds |
| title | The High Electrocatalytic Performance of NiFeSe/CFP for Hydrogen Evolution Reaction Derived from a Prussian Blue Analogue |
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