Sustainable Afterglow Room‐Temperature Phosphorescence Emission Materials Generated Using Natural Phenolics
Long‐lived afterglow room‐temperature phosphorescence (RTP) from natural phenolics has seldom been reported yet this is essential for the development of sustainable afterglow RTP materials. With this research, we have prepared sustainable afterglow RTP materials (GA@SA) with a lifetime of up to ≈934...
Gespeichert in:
| Veröffentlicht in: | Angewandte Chemie 2022-08, Vol.134 (31), p.n/a |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | n/a |
|---|---|
| container_issue | 31 |
| container_start_page | |
| container_title | Angewandte Chemie |
| container_volume | 134 |
| creator | Wan, Keliang Zhai, Yingxiang Liu, Shouxin Li, Jian Li, Shujun Strehmel, Bernd Chen, Zhijun James, Tony D. |
| description | Long‐lived afterglow room‐temperature phosphorescence (RTP) from natural phenolics has seldom been reported yet this is essential for the development of sustainable afterglow RTP materials. With this research, we have prepared sustainable afterglow RTP materials (GA@SA) with a lifetime of up to ≈934.7 ms by embedding gallic acid (GA) within a Ca2+‐crosslinked sodium alginate (SA) matrix. Theoretical simulations indicate that the restricted carbonyl moieties of the GA and H‐type aggregates of GA in a SA matrix promoted the spin orbit coupling (SOC) of GA and induced afterglow emission. Moreover, afterglow RTP emission could be produced by embedding different types of natural phenolics such as, tannic acid, caffeic acid and chlorogenic acid into Ca2+‐crosslinked networks of SA. As an illustration of potential applications, GA@SA was used to prepare anti‐counterfeit afterglow clothing and paper. This work provides an innovative method for the activation of long‐lived afterglow RTP from sustainable phenolics.
Sustainable organic afterglow room‐temperature phosphorescence (RTP) with long lifetime is a particularly attractive phenomenon but remains difficult to achieve. Here, we prepared sustainable afterglow RTP materials (GA@SA) with a lifetime up to 934.7 ms by embedding gallic acid (GA) within a Ca2+‐crosslinked sodium alginate (SA) matrix. |
| doi_str_mv | 10.1002/ange.202202760 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2693699591</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2693699591</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2020-cf2b14e8ccc2ae8180eab8de866c7816ea5d545ecca4069c611dc21322f9fca03</originalsourceid><addsrcrecordid>eNqFkEFLwzAUx4MoOKdXzwHPnUnaps1xyJzCnKLbOWTp65bRNjXpGLv5EfyMfhJTJnoUHrzL7_d_jz9C15SMKCHsVjVrGDHCwmScnKABTRmN4izNTtGAkCSJcpaIc3Th_ZYQwlkmBqh-2_lOmUatKsDjsgO3ruwev1pbf318LqBuwalu5wC_bKxvN9aB19BowJPaeG9sg59UsIyqPJ5C09NQ4KU3zRrPe1NVQYXGVkb7S3RWBhCufvYQLe8ni7uHaPY8fbwbzyIdnieRLtmKJpBrrZmCnOYE1CovIOdcZznloNIiTVLQWiWEC80pLTSjMWOlKLUi8RDdHHNbZ9934Du5tTvXhJOScRFzIVJBAzU6UtpZ7x2UsnWmVu4gKZF9pbKvVP5WGgRxFPamgsM_tBzPp5M_9xtyjn5M</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2693699591</pqid></control><display><type>article</type><title>Sustainable Afterglow Room‐Temperature Phosphorescence Emission Materials Generated Using Natural Phenolics</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Wan, Keliang ; Zhai, Yingxiang ; Liu, Shouxin ; Li, Jian ; Li, Shujun ; Strehmel, Bernd ; Chen, Zhijun ; James, Tony D.</creator><creatorcontrib>Wan, Keliang ; Zhai, Yingxiang ; Liu, Shouxin ; Li, Jian ; Li, Shujun ; Strehmel, Bernd ; Chen, Zhijun ; James, Tony D.</creatorcontrib><description>Long‐lived afterglow room‐temperature phosphorescence (RTP) from natural phenolics has seldom been reported yet this is essential for the development of sustainable afterglow RTP materials. With this research, we have prepared sustainable afterglow RTP materials (GA@SA) with a lifetime of up to ≈934.7 ms by embedding gallic acid (GA) within a Ca2+‐crosslinked sodium alginate (SA) matrix. Theoretical simulations indicate that the restricted carbonyl moieties of the GA and H‐type aggregates of GA in a SA matrix promoted the spin orbit coupling (SOC) of GA and induced afterglow emission. Moreover, afterglow RTP emission could be produced by embedding different types of natural phenolics such as, tannic acid, caffeic acid and chlorogenic acid into Ca2+‐crosslinked networks of SA. As an illustration of potential applications, GA@SA was used to prepare anti‐counterfeit afterglow clothing and paper. This work provides an innovative method for the activation of long‐lived afterglow RTP from sustainable phenolics.
Sustainable organic afterglow room‐temperature phosphorescence (RTP) with long lifetime is a particularly attractive phenomenon but remains difficult to achieve. Here, we prepared sustainable afterglow RTP materials (GA@SA) with a lifetime up to 934.7 ms by embedding gallic acid (GA) within a Ca2+‐crosslinked sodium alginate (SA) matrix.</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.202202760</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Afterglow Emission ; Afterglows ; Alginic acid ; Caffeic acid ; Calcium alginate ; Calcium ions ; Carbonyl compounds ; Carbonyls ; Chemistry ; Chlorogenic acid ; Counterfeit ; Crosslinking ; Embedding ; Emission ; Emissions ; Gallic acid ; Long Lifetime ; Natural Phenolics ; Phenols ; Phosphorescence ; Sodium Alginate ; Sustainability ; Sustainable development ; Tannic acid</subject><ispartof>Angewandte Chemie, 2022-08, Vol.134 (31), p.n/a</ispartof><rights>2022 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2020-cf2b14e8ccc2ae8180eab8de866c7816ea5d545ecca4069c611dc21322f9fca03</citedby><cites>FETCH-LOGICAL-c2020-cf2b14e8ccc2ae8180eab8de866c7816ea5d545ecca4069c611dc21322f9fca03</cites><orcidid>0000-0002-4095-2191</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fange.202202760$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fange.202202760$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,778,782,1414,27911,27912,45561,45562</link.rule.ids></links><search><creatorcontrib>Wan, Keliang</creatorcontrib><creatorcontrib>Zhai, Yingxiang</creatorcontrib><creatorcontrib>Liu, Shouxin</creatorcontrib><creatorcontrib>Li, Jian</creatorcontrib><creatorcontrib>Li, Shujun</creatorcontrib><creatorcontrib>Strehmel, Bernd</creatorcontrib><creatorcontrib>Chen, Zhijun</creatorcontrib><creatorcontrib>James, Tony D.</creatorcontrib><title>Sustainable Afterglow Room‐Temperature Phosphorescence Emission Materials Generated Using Natural Phenolics</title><title>Angewandte Chemie</title><description>Long‐lived afterglow room‐temperature phosphorescence (RTP) from natural phenolics has seldom been reported yet this is essential for the development of sustainable afterglow RTP materials. With this research, we have prepared sustainable afterglow RTP materials (GA@SA) with a lifetime of up to ≈934.7 ms by embedding gallic acid (GA) within a Ca2+‐crosslinked sodium alginate (SA) matrix. Theoretical simulations indicate that the restricted carbonyl moieties of the GA and H‐type aggregates of GA in a SA matrix promoted the spin orbit coupling (SOC) of GA and induced afterglow emission. Moreover, afterglow RTP emission could be produced by embedding different types of natural phenolics such as, tannic acid, caffeic acid and chlorogenic acid into Ca2+‐crosslinked networks of SA. As an illustration of potential applications, GA@SA was used to prepare anti‐counterfeit afterglow clothing and paper. This work provides an innovative method for the activation of long‐lived afterglow RTP from sustainable phenolics.
Sustainable organic afterglow room‐temperature phosphorescence (RTP) with long lifetime is a particularly attractive phenomenon but remains difficult to achieve. Here, we prepared sustainable afterglow RTP materials (GA@SA) with a lifetime up to 934.7 ms by embedding gallic acid (GA) within a Ca2+‐crosslinked sodium alginate (SA) matrix.</description><subject>Afterglow Emission</subject><subject>Afterglows</subject><subject>Alginic acid</subject><subject>Caffeic acid</subject><subject>Calcium alginate</subject><subject>Calcium ions</subject><subject>Carbonyl compounds</subject><subject>Carbonyls</subject><subject>Chemistry</subject><subject>Chlorogenic acid</subject><subject>Counterfeit</subject><subject>Crosslinking</subject><subject>Embedding</subject><subject>Emission</subject><subject>Emissions</subject><subject>Gallic acid</subject><subject>Long Lifetime</subject><subject>Natural Phenolics</subject><subject>Phenols</subject><subject>Phosphorescence</subject><subject>Sodium Alginate</subject><subject>Sustainability</subject><subject>Sustainable development</subject><subject>Tannic acid</subject><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqFkEFLwzAUx4MoOKdXzwHPnUnaps1xyJzCnKLbOWTp65bRNjXpGLv5EfyMfhJTJnoUHrzL7_d_jz9C15SMKCHsVjVrGDHCwmScnKABTRmN4izNTtGAkCSJcpaIc3Th_ZYQwlkmBqh-2_lOmUatKsDjsgO3ruwev1pbf318LqBuwalu5wC_bKxvN9aB19BowJPaeG9sg59UsIyqPJ5C09NQ4KU3zRrPe1NVQYXGVkb7S3RWBhCufvYQLe8ni7uHaPY8fbwbzyIdnieRLtmKJpBrrZmCnOYE1CovIOdcZznloNIiTVLQWiWEC80pLTSjMWOlKLUi8RDdHHNbZ9934Du5tTvXhJOScRFzIVJBAzU6UtpZ7x2UsnWmVu4gKZF9pbKvVP5WGgRxFPamgsM_tBzPp5M_9xtyjn5M</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>Wan, Keliang</creator><creator>Zhai, Yingxiang</creator><creator>Liu, Shouxin</creator><creator>Li, Jian</creator><creator>Li, Shujun</creator><creator>Strehmel, Bernd</creator><creator>Chen, Zhijun</creator><creator>James, Tony D.</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-4095-2191</orcidid></search><sort><creationdate>20220801</creationdate><title>Sustainable Afterglow Room‐Temperature Phosphorescence Emission Materials Generated Using Natural Phenolics</title><author>Wan, Keliang ; Zhai, Yingxiang ; Liu, Shouxin ; Li, Jian ; Li, Shujun ; Strehmel, Bernd ; Chen, Zhijun ; James, Tony D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2020-cf2b14e8ccc2ae8180eab8de866c7816ea5d545ecca4069c611dc21322f9fca03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Afterglow Emission</topic><topic>Afterglows</topic><topic>Alginic acid</topic><topic>Caffeic acid</topic><topic>Calcium alginate</topic><topic>Calcium ions</topic><topic>Carbonyl compounds</topic><topic>Carbonyls</topic><topic>Chemistry</topic><topic>Chlorogenic acid</topic><topic>Counterfeit</topic><topic>Crosslinking</topic><topic>Embedding</topic><topic>Emission</topic><topic>Emissions</topic><topic>Gallic acid</topic><topic>Long Lifetime</topic><topic>Natural Phenolics</topic><topic>Phenols</topic><topic>Phosphorescence</topic><topic>Sodium Alginate</topic><topic>Sustainability</topic><topic>Sustainable development</topic><topic>Tannic acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wan, Keliang</creatorcontrib><creatorcontrib>Zhai, Yingxiang</creatorcontrib><creatorcontrib>Liu, Shouxin</creatorcontrib><creatorcontrib>Li, Jian</creatorcontrib><creatorcontrib>Li, Shujun</creatorcontrib><creatorcontrib>Strehmel, Bernd</creatorcontrib><creatorcontrib>Chen, Zhijun</creatorcontrib><creatorcontrib>James, Tony D.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wan, Keliang</au><au>Zhai, Yingxiang</au><au>Liu, Shouxin</au><au>Li, Jian</au><au>Li, Shujun</au><au>Strehmel, Bernd</au><au>Chen, Zhijun</au><au>James, Tony D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sustainable Afterglow Room‐Temperature Phosphorescence Emission Materials Generated Using Natural Phenolics</atitle><jtitle>Angewandte Chemie</jtitle><date>2022-08-01</date><risdate>2022</risdate><volume>134</volume><issue>31</issue><epage>n/a</epage><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>Long‐lived afterglow room‐temperature phosphorescence (RTP) from natural phenolics has seldom been reported yet this is essential for the development of sustainable afterglow RTP materials. With this research, we have prepared sustainable afterglow RTP materials (GA@SA) with a lifetime of up to ≈934.7 ms by embedding gallic acid (GA) within a Ca2+‐crosslinked sodium alginate (SA) matrix. Theoretical simulations indicate that the restricted carbonyl moieties of the GA and H‐type aggregates of GA in a SA matrix promoted the spin orbit coupling (SOC) of GA and induced afterglow emission. Moreover, afterglow RTP emission could be produced by embedding different types of natural phenolics such as, tannic acid, caffeic acid and chlorogenic acid into Ca2+‐crosslinked networks of SA. As an illustration of potential applications, GA@SA was used to prepare anti‐counterfeit afterglow clothing and paper. This work provides an innovative method for the activation of long‐lived afterglow RTP from sustainable phenolics.
Sustainable organic afterglow room‐temperature phosphorescence (RTP) with long lifetime is a particularly attractive phenomenon but remains difficult to achieve. Here, we prepared sustainable afterglow RTP materials (GA@SA) with a lifetime up to 934.7 ms by embedding gallic acid (GA) within a Ca2+‐crosslinked sodium alginate (SA) matrix.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ange.202202760</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-4095-2191</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0044-8249 |
| ispartof | Angewandte Chemie, 2022-08, Vol.134 (31), p.n/a |
| issn | 0044-8249 1521-3757 |
| language | eng |
| recordid | cdi_proquest_journals_2693699591 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Afterglow Emission Afterglows Alginic acid Caffeic acid Calcium alginate Calcium ions Carbonyl compounds Carbonyls Chemistry Chlorogenic acid Counterfeit Crosslinking Embedding Emission Emissions Gallic acid Long Lifetime Natural Phenolics Phenols Phosphorescence Sodium Alginate Sustainability Sustainable development Tannic acid |
| title | Sustainable Afterglow Room‐Temperature Phosphorescence Emission Materials Generated Using Natural Phenolics |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T18%3A03%3A20IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Sustainable%20Afterglow%20Room%E2%80%90Temperature%20Phosphorescence%20Emission%20Materials%20Generated%20Using%20Natural%20Phenolics&rft.jtitle=Angewandte%20Chemie&rft.au=Wan,%20Keliang&rft.date=2022-08-01&rft.volume=134&rft.issue=31&rft.epage=n/a&rft.issn=0044-8249&rft.eissn=1521-3757&rft_id=info:doi/10.1002/ange.202202760&rft_dat=%3Cproquest_cross%3E2693699591%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2693699591&rft_id=info:pmid/&rfr_iscdi=true |