RETRACTED ARTICLE: Porous NiO via pulsed electrodeposition towards enhanced electrochromic properties

Herein, a facile pulse electrodeposition procedure with a 1 s off-time between pulses is reported for a successful fabrication of porous nickel oxide (NiO) films on an indium tin oxide substrate. Large transmittance modulation of 39.2% at 550 nm, fast switching speed (coloring and bleaching of 5.2 s...

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Veröffentlicht in:Journal of applied electrochemistry 2022, Vol.52 (9), p.1343-1351
Hauptverfasser: Pham, Nguyen Sy, Phan, Phuong Thi Que, Le, Vinh Xuan
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Phan, Phuong Thi Que
Le, Vinh Xuan
description Herein, a facile pulse electrodeposition procedure with a 1 s off-time between pulses is reported for a successful fabrication of porous nickel oxide (NiO) films on an indium tin oxide substrate. Large transmittance modulation of 39.2% at 550 nm, fast switching speed (coloring and bleaching of 5.2 s and 2.3 s), high coloration efficiency of 20.01 cm 2 C −1 , and long-term stability over 750 cycles were achieved. In comparison to the NiO films synthesized by continuous electrodeposition, the porous morphology of the NiO fabricated by pulsed electrodeposition facilitates charge transfer and electrolyte infiltration, as well as reduces the expansion/shrinkage of the NiO lattice during OH − insertion/extraction, resulting in an outstanding electrochromic performance. These results show that pulsed electrodeposition is a promising method for manufacturing NiO films with enhanced EC performance. Graphical abstract
doi_str_mv 10.1007/s10800-022-01716-8
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Large transmittance modulation of 39.2% at 550 nm, fast switching speed (coloring and bleaching of 5.2 s and 2.3 s), high coloration efficiency of 20.01 cm 2 C −1 , and long-term stability over 750 cycles were achieved. In comparison to the NiO films synthesized by continuous electrodeposition, the porous morphology of the NiO fabricated by pulsed electrodeposition facilitates charge transfer and electrolyte infiltration, as well as reduces the expansion/shrinkage of the NiO lattice during OH − insertion/extraction, resulting in an outstanding electrochromic performance. These results show that pulsed electrodeposition is a promising method for manufacturing NiO films with enhanced EC performance. 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subjects Chemistry
Chemistry and Materials Science
Electrochemistry
Electrodeposition
Industrial Chemistry/Chemical Engineering
Physical Chemistry
Research Article
title RETRACTED ARTICLE: Porous NiO via pulsed electrodeposition towards enhanced electrochromic properties
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