Effect of carbon on microstructure, mechanical properties and wear resistance of non-equiatomic Fe70Co7.5Cr7.5Ni7.5V7.5 medium-entropy alloys fabricated by powder metallurgy

In this study, non-equiatomic Fe 70 Co 7.5 Cr 7.5 Ni 7.5 V 7.5 medium-entropy alloys (MEAs) with different carbon contents were prepared via mechanical ball-milling, cold pressing and vacuum sintering. The microstructural evolution, mechanical properties and wear resistance of the MEAs were investig...

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Veröffentlicht in:Journal of Central South University 2022-06, Vol.29 (6), p.1799-1810
Hauptverfasser: Yang, Bao-zhen, Xiong, Xiang, Liu, Ru-tie, Chen, Jie
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Xiong, Xiang
Liu, Ru-tie
Chen, Jie
description In this study, non-equiatomic Fe 70 Co 7.5 Cr 7.5 Ni 7.5 V 7.5 medium-entropy alloys (MEAs) with different carbon contents were prepared via mechanical ball-milling, cold pressing and vacuum sintering. The microstructural evolution, mechanical properties and wear resistance of the MEAs were investigated Fe 70 Co 7.5 Cr 7.5 Ni 7.5 V 7.5 exhibited a body-centered cubic (bcc) structure with σ phase precipitation. After adding 4 at% and 8 at% carbon, the phase composition of the alloys was transformed to bcc+MC+ σ and bcc+MC+M 23 C 6 , respectively. The mechanical properties and wear resistance were observed to be significantly enhanced by the formation of carbides. Increasing the carbon content, the corresponding bending strength and hardness increased from 1520 to 3245 MPa and HRC 57.2 to HRC 61.4, respectively. Further, the dominant wear mechanism changed from the adhesion wear to the abrasion wear. Owing to the evenly distributed carbides and precipitated nanocarbides, Fe 64.4 Co 6.9 Cr 6.9 Ni 6.9 V 6.9 C 8 revealed an extremely low specific wear rate of 1.3×10 −6 mm 2 /(N·m) under a load of 10 N.
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The microstructural evolution, mechanical properties and wear resistance of the MEAs were investigated Fe 70 Co 7.5 Cr 7.5 Ni 7.5 V 7.5 exhibited a body-centered cubic (bcc) structure with σ phase precipitation. After adding 4 at% and 8 at% carbon, the phase composition of the alloys was transformed to bcc+MC+ σ and bcc+MC+M 23 C 6 , respectively. The mechanical properties and wear resistance were observed to be significantly enhanced by the formation of carbides. Increasing the carbon content, the corresponding bending strength and hardness increased from 1520 to 3245 MPa and HRC 57.2 to HRC 61.4, respectively. Further, the dominant wear mechanism changed from the adhesion wear to the abrasion wear. Owing to the evenly distributed carbides and precipitated nanocarbides, Fe 64.4 Co 6.9 Cr 6.9 Ni 6.9 V 6.9 C 8 revealed an extremely low specific wear rate of 1.3×10 −6 mm 2 /(N·m) under a load of 10 N.</description><identifier>ISSN: 2095-2899</identifier><identifier>EISSN: 2227-5223</identifier><identifier>DOI: 10.1007/s11771-022-5057-y</identifier><language>eng</language><publisher>Changsha: Central South University</publisher><subject>Abrasion ; Alloy powders ; Ball milling ; Bend strength ; Carbides ; Carbon content ; Cold pressing ; Engineering ; Mechanical properties ; Medium entropy alloys ; Metallic Materials ; Metallurgical analysis ; Microstructure ; Phase composition ; Powder metallurgy ; Sigma phase precipitation ; Sintering (powder metallurgy) ; Vacuum sintering ; Wear mechanisms ; Wear rate ; Wear resistance</subject><ispartof>Journal of Central South University, 2022-06, Vol.29 (6), p.1799-1810</ispartof><rights>Central South University 2022</rights><rights>Central South University 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-4625482476eddf9301bb8a23fe0242811177a135f09fddcd6b6e06fb5e6cfbf03</cites><orcidid>0000-0002-3744-1083 ; 0000-0002-8189-5760</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11771-022-5057-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11771-022-5057-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Yang, Bao-zhen</creatorcontrib><creatorcontrib>Xiong, Xiang</creatorcontrib><creatorcontrib>Liu, Ru-tie</creatorcontrib><creatorcontrib>Chen, Jie</creatorcontrib><title>Effect of carbon on microstructure, mechanical properties and wear resistance of non-equiatomic Fe70Co7.5Cr7.5Ni7.5V7.5 medium-entropy alloys fabricated by powder metallurgy</title><title>Journal of Central South University</title><addtitle>J. Cent. South Univ</addtitle><description>In this study, non-equiatomic Fe 70 Co 7.5 Cr 7.5 Ni 7.5 V 7.5 medium-entropy alloys (MEAs) with different carbon contents were prepared via mechanical ball-milling, cold pressing and vacuum sintering. The microstructural evolution, mechanical properties and wear resistance of the MEAs were investigated Fe 70 Co 7.5 Cr 7.5 Ni 7.5 V 7.5 exhibited a body-centered cubic (bcc) structure with σ phase precipitation. After adding 4 at% and 8 at% carbon, the phase composition of the alloys was transformed to bcc+MC+ σ and bcc+MC+M 23 C 6 , respectively. The mechanical properties and wear resistance were observed to be significantly enhanced by the formation of carbides. Increasing the carbon content, the corresponding bending strength and hardness increased from 1520 to 3245 MPa and HRC 57.2 to HRC 61.4, respectively. Further, the dominant wear mechanism changed from the adhesion wear to the abrasion wear. Owing to the evenly distributed carbides and precipitated nanocarbides, Fe 64.4 Co 6.9 Cr 6.9 Ni 6.9 V 6.9 C 8 revealed an extremely low specific wear rate of 1.3×10 −6 mm 2 /(N·m) under a load of 10 N.</description><subject>Abrasion</subject><subject>Alloy powders</subject><subject>Ball milling</subject><subject>Bend strength</subject><subject>Carbides</subject><subject>Carbon content</subject><subject>Cold pressing</subject><subject>Engineering</subject><subject>Mechanical properties</subject><subject>Medium entropy alloys</subject><subject>Metallic Materials</subject><subject>Metallurgical analysis</subject><subject>Microstructure</subject><subject>Phase composition</subject><subject>Powder metallurgy</subject><subject>Sigma phase precipitation</subject><subject>Sintering (powder metallurgy)</subject><subject>Vacuum sintering</subject><subject>Wear mechanisms</subject><subject>Wear rate</subject><subject>Wear resistance</subject><issn>2095-2899</issn><issn>2227-5223</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kc9qHSEUxofSQkOSB-hO6LameuaqM8tySZpCSDdtt-KfY2q5V2_UIcxD9R3rcAtdFfQo-H2_g-cbhnec3XDG1MfKuVKcMgAqmFB0fTVcAICiAmB83e9sFhSmeX47XNcaLRs5yFHO8mL4fRsCukZyIM4UmxPp6xhdybWVxbWl4AdyRPfTpOjMgZxKPmFpESsxyZMXNIUUrLE2kxxumJQTxeclmpY7h9yhYvusbsS-9PIYe_nRd2f6uBwpptaJKzGHQ14rCcaW3qehJ3Ylp_zisXRp689LeVqvhjfBHCpe_z0vh-93t9_29_Th6-cv-08P1IGcGt1JELsJdkqi92EeGbd2MjAGZLCDiW_jMnwUgc3Be-ellchksAKlCzaw8XJ4f-b27z4vWJv-lZeSeksNcmYK-CR4V_GzaptWLRj0qcSjKavmTG_B6HMwugejt2D02j1w9tSuTU9Y_pH_b_oDQU2TSw</recordid><startdate>20220601</startdate><enddate>20220601</enddate><creator>Yang, Bao-zhen</creator><creator>Xiong, Xiang</creator><creator>Liu, Ru-tie</creator><creator>Chen, Jie</creator><general>Central South University</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-3744-1083</orcidid><orcidid>https://orcid.org/0000-0002-8189-5760</orcidid></search><sort><creationdate>20220601</creationdate><title>Effect of carbon on microstructure, mechanical properties and wear resistance of non-equiatomic Fe70Co7.5Cr7.5Ni7.5V7.5 medium-entropy alloys fabricated by powder metallurgy</title><author>Yang, Bao-zhen ; Xiong, Xiang ; Liu, Ru-tie ; Chen, Jie</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-4625482476eddf9301bb8a23fe0242811177a135f09fddcd6b6e06fb5e6cfbf03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Abrasion</topic><topic>Alloy powders</topic><topic>Ball milling</topic><topic>Bend strength</topic><topic>Carbides</topic><topic>Carbon content</topic><topic>Cold pressing</topic><topic>Engineering</topic><topic>Mechanical properties</topic><topic>Medium entropy alloys</topic><topic>Metallic Materials</topic><topic>Metallurgical analysis</topic><topic>Microstructure</topic><topic>Phase composition</topic><topic>Powder metallurgy</topic><topic>Sigma phase precipitation</topic><topic>Sintering (powder metallurgy)</topic><topic>Vacuum sintering</topic><topic>Wear mechanisms</topic><topic>Wear rate</topic><topic>Wear resistance</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Bao-zhen</creatorcontrib><creatorcontrib>Xiong, Xiang</creatorcontrib><creatorcontrib>Liu, Ru-tie</creatorcontrib><creatorcontrib>Chen, Jie</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of Central South University</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Bao-zhen</au><au>Xiong, Xiang</au><au>Liu, Ru-tie</au><au>Chen, Jie</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of carbon on microstructure, mechanical properties and wear resistance of non-equiatomic Fe70Co7.5Cr7.5Ni7.5V7.5 medium-entropy alloys fabricated by powder metallurgy</atitle><jtitle>Journal of Central South University</jtitle><stitle>J. Cent. South Univ</stitle><date>2022-06-01</date><risdate>2022</risdate><volume>29</volume><issue>6</issue><spage>1799</spage><epage>1810</epage><pages>1799-1810</pages><issn>2095-2899</issn><eissn>2227-5223</eissn><abstract>In this study, non-equiatomic Fe 70 Co 7.5 Cr 7.5 Ni 7.5 V 7.5 medium-entropy alloys (MEAs) with different carbon contents were prepared via mechanical ball-milling, cold pressing and vacuum sintering. The microstructural evolution, mechanical properties and wear resistance of the MEAs were investigated Fe 70 Co 7.5 Cr 7.5 Ni 7.5 V 7.5 exhibited a body-centered cubic (bcc) structure with σ phase precipitation. After adding 4 at% and 8 at% carbon, the phase composition of the alloys was transformed to bcc+MC+ σ and bcc+MC+M 23 C 6 , respectively. The mechanical properties and wear resistance were observed to be significantly enhanced by the formation of carbides. 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subjects Abrasion
Alloy powders
Ball milling
Bend strength
Carbides
Carbon content
Cold pressing
Engineering
Mechanical properties
Medium entropy alloys
Metallic Materials
Metallurgical analysis
Microstructure
Phase composition
Powder metallurgy
Sigma phase precipitation
Sintering (powder metallurgy)
Vacuum sintering
Wear mechanisms
Wear rate
Wear resistance
title Effect of carbon on microstructure, mechanical properties and wear resistance of non-equiatomic Fe70Co7.5Cr7.5Ni7.5V7.5 medium-entropy alloys fabricated by powder metallurgy
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