Construction of a hollow BiOI/TiO2/ZIF-8 heterojunction: Enhanced photocatalytic performance for norfloxacin degradation and mechanistic insight
The overuse of norfloxacin (NOR) has attracted wide attention because of the persistence and bio-accumulate in ecosystems and the negative impacts on human health. To solve the environmental issue, BiOI/TiO2 p-n heterojunctions have been developed and decorated with a porous ZIF-8 to obtain novel ho...
Gespeichert in:
Veröffentlicht in: | Journal of alloys and compounds 2022-09, Vol.914, p.165326, Article 165326 |
---|---|
Hauptverfasser: | , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | |
---|---|
container_issue | |
container_start_page | 165326 |
container_title | Journal of alloys and compounds |
container_volume | 914 |
creator | Zhu, Yu Xv, Qinyun Wang, Dan Sun, Bingxin Wang, Yujia Han, Zhiguo Gou, Yongbo Liu, Jiayu Li, Bingdong |
description | The overuse of norfloxacin (NOR) has attracted wide attention because of the persistence and bio-accumulate in ecosystems and the negative impacts on human health. To solve the environmental issue, BiOI/TiO2 p-n heterojunctions have been developed and decorated with a porous ZIF-8 to obtain novel hollow BiOI/TiO2/ZIF-8 heterojunctions, which were further characterized by XRD, SEM, HRTEM, XPS, BET, UV–vis DRS, photoluminescence, ESR, photocurrent and EIS analyses. The BiOI/TiO2/ZIF-8 heterojunctions exhibited evidently improved photocatalytic performance compared with pristine BiOI, TiO2 and BiOI/TiO2 composites under visible light irradiation. ZIF-8 plays a key role in both the enhancement of adsorption and the photocatalytic activity in NOR removal. ·O2- and ·OH radicals were the two dominating active species in the photocatalytic process according to the trapping experiments. In 2-BTZ system, large specific surface area, highly effective charge carrier migration with inhibiting recombination, more negative CB and positive VB to generate more active ·O2- and ·OH species resulted in superior photocatalytic activity. This work provides a new idea to design a kind of photocatalytic heterostructure with more active species for potential application in the field of environmental treatment.
•A series of hollow BiOI/TiO2/ZIF-8 heterojunctions have been obtained with improved photocatalytic activities.•The ·O2- and ·OH radicals should be the two dominating active species according to the trapping experiments.•Decorating porous ZIF-8 improves adsorption performance and achieves the more efficient hole-charge transfer.•In 2-BTZ system, it can provide more negative CB and more positive VB to generate more active ·O2- and ·OH species. |
doi_str_mv | 10.1016/j.jallcom.2022.165326 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2689714840</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0925838822017170</els_id><sourcerecordid>2689714840</sourcerecordid><originalsourceid>FETCH-LOGICAL-c337t-13c085e025df2456ed0e56f363a9d6da1950fc77d49ec1070de1ec246f7f1cec3</originalsourceid><addsrcrecordid>eNqFkM1q3DAQx0VoIdu0j1AQ9Oxdfdiy3Utpl6RZCOwlueQixGgUy3ilraRtm7foI9fO5p7TDMz_g_kR8pmzNWdcbcb1aKYJ4mEtmBBrrhop1AVZ8a6VVa1U_46sWC-aqpNdd0k-5Dwyxngv-Yr828aQSzpB8THQ6KihQ5ym-If-8Pvd5t7vxeZxd1N1dMCCKY6n8CL9Sq_DYAKgpcchlgimmOm5eKBHTC6mw3Kj80JDTG6Kfw34QC0-JWPNS5cJlh4Q5hCfF58P2T8N5SN578yU8dPrvCIPN9f329vqbv9zt_1-V4GUbam4BNY1yERjnagbhZZho5xU0vRWWcP7hjloW1v3CJy1zCJHELVyreOAIK_Il3PuMcVfJ8xFj_GUwlypher6ltddzWZVc1ZBijkndPqY_MGkZ82ZXuDrUb_C1wt8fYY_-76dfTi_8Ntj0hk8Lrh8QijaRv9Gwn-H2ZLp</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2689714840</pqid></control><display><type>article</type><title>Construction of a hollow BiOI/TiO2/ZIF-8 heterojunction: Enhanced photocatalytic performance for norfloxacin degradation and mechanistic insight</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Zhu, Yu ; Xv, Qinyun ; Wang, Dan ; Sun, Bingxin ; Wang, Yujia ; Han, Zhiguo ; Gou, Yongbo ; Liu, Jiayu ; Li, Bingdong</creator><creatorcontrib>Zhu, Yu ; Xv, Qinyun ; Wang, Dan ; Sun, Bingxin ; Wang, Yujia ; Han, Zhiguo ; Gou, Yongbo ; Liu, Jiayu ; Li, Bingdong</creatorcontrib><description>The overuse of norfloxacin (NOR) has attracted wide attention because of the persistence and bio-accumulate in ecosystems and the negative impacts on human health. To solve the environmental issue, BiOI/TiO2 p-n heterojunctions have been developed and decorated with a porous ZIF-8 to obtain novel hollow BiOI/TiO2/ZIF-8 heterojunctions, which were further characterized by XRD, SEM, HRTEM, XPS, BET, UV–vis DRS, photoluminescence, ESR, photocurrent and EIS analyses. The BiOI/TiO2/ZIF-8 heterojunctions exhibited evidently improved photocatalytic performance compared with pristine BiOI, TiO2 and BiOI/TiO2 composites under visible light irradiation. ZIF-8 plays a key role in both the enhancement of adsorption and the photocatalytic activity in NOR removal. ·O2- and ·OH radicals were the two dominating active species in the photocatalytic process according to the trapping experiments. In 2-BTZ system, large specific surface area, highly effective charge carrier migration with inhibiting recombination, more negative CB and positive VB to generate more active ·O2- and ·OH species resulted in superior photocatalytic activity. This work provides a new idea to design a kind of photocatalytic heterostructure with more active species for potential application in the field of environmental treatment.
•A series of hollow BiOI/TiO2/ZIF-8 heterojunctions have been obtained with improved photocatalytic activities.•The ·O2- and ·OH radicals should be the two dominating active species according to the trapping experiments.•Decorating porous ZIF-8 improves adsorption performance and achieves the more efficient hole-charge transfer.•In 2-BTZ system, it can provide more negative CB and more positive VB to generate more active ·O2- and ·OH species.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2022.165326</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>BiOI ; Carrier recombination ; Catalytic activity ; Current carriers ; Heterojunctions ; Heterostructures ; Light irradiation ; Metal organic framework ; Norfloxacin ; P-n heterojunction ; P-n junctions ; Performance degradation ; Photocatalysis ; Photocatalytic degradation ; Photodegradation ; Photoelectric effect ; Photoluminescence ; Titanium dioxide ; X ray photoelectron spectroscopy</subject><ispartof>Journal of alloys and compounds, 2022-09, Vol.914, p.165326, Article 165326</ispartof><rights>2022 Elsevier B.V.</rights><rights>Copyright Elsevier BV Sep 5, 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-13c085e025df2456ed0e56f363a9d6da1950fc77d49ec1070de1ec246f7f1cec3</citedby><cites>FETCH-LOGICAL-c337t-13c085e025df2456ed0e56f363a9d6da1950fc77d49ec1070de1ec246f7f1cec3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jallcom.2022.165326$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Zhu, Yu</creatorcontrib><creatorcontrib>Xv, Qinyun</creatorcontrib><creatorcontrib>Wang, Dan</creatorcontrib><creatorcontrib>Sun, Bingxin</creatorcontrib><creatorcontrib>Wang, Yujia</creatorcontrib><creatorcontrib>Han, Zhiguo</creatorcontrib><creatorcontrib>Gou, Yongbo</creatorcontrib><creatorcontrib>Liu, Jiayu</creatorcontrib><creatorcontrib>Li, Bingdong</creatorcontrib><title>Construction of a hollow BiOI/TiO2/ZIF-8 heterojunction: Enhanced photocatalytic performance for norfloxacin degradation and mechanistic insight</title><title>Journal of alloys and compounds</title><description>The overuse of norfloxacin (NOR) has attracted wide attention because of the persistence and bio-accumulate in ecosystems and the negative impacts on human health. To solve the environmental issue, BiOI/TiO2 p-n heterojunctions have been developed and decorated with a porous ZIF-8 to obtain novel hollow BiOI/TiO2/ZIF-8 heterojunctions, which were further characterized by XRD, SEM, HRTEM, XPS, BET, UV–vis DRS, photoluminescence, ESR, photocurrent and EIS analyses. The BiOI/TiO2/ZIF-8 heterojunctions exhibited evidently improved photocatalytic performance compared with pristine BiOI, TiO2 and BiOI/TiO2 composites under visible light irradiation. ZIF-8 plays a key role in both the enhancement of adsorption and the photocatalytic activity in NOR removal. ·O2- and ·OH radicals were the two dominating active species in the photocatalytic process according to the trapping experiments. In 2-BTZ system, large specific surface area, highly effective charge carrier migration with inhibiting recombination, more negative CB and positive VB to generate more active ·O2- and ·OH species resulted in superior photocatalytic activity. This work provides a new idea to design a kind of photocatalytic heterostructure with more active species for potential application in the field of environmental treatment.
•A series of hollow BiOI/TiO2/ZIF-8 heterojunctions have been obtained with improved photocatalytic activities.•The ·O2- and ·OH radicals should be the two dominating active species according to the trapping experiments.•Decorating porous ZIF-8 improves adsorption performance and achieves the more efficient hole-charge transfer.•In 2-BTZ system, it can provide more negative CB and more positive VB to generate more active ·O2- and ·OH species.</description><subject>BiOI</subject><subject>Carrier recombination</subject><subject>Catalytic activity</subject><subject>Current carriers</subject><subject>Heterojunctions</subject><subject>Heterostructures</subject><subject>Light irradiation</subject><subject>Metal organic framework</subject><subject>Norfloxacin</subject><subject>P-n heterojunction</subject><subject>P-n junctions</subject><subject>Performance degradation</subject><subject>Photocatalysis</subject><subject>Photocatalytic degradation</subject><subject>Photodegradation</subject><subject>Photoelectric effect</subject><subject>Photoluminescence</subject><subject>Titanium dioxide</subject><subject>X ray photoelectron spectroscopy</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqFkM1q3DAQx0VoIdu0j1AQ9Oxdfdiy3Utpl6RZCOwlueQixGgUy3ilraRtm7foI9fO5p7TDMz_g_kR8pmzNWdcbcb1aKYJ4mEtmBBrrhop1AVZ8a6VVa1U_46sWC-aqpNdd0k-5Dwyxngv-Yr828aQSzpB8THQ6KihQ5ym-If-8Pvd5t7vxeZxd1N1dMCCKY6n8CL9Sq_DYAKgpcchlgimmOm5eKBHTC6mw3Kj80JDTG6Kfw34QC0-JWPNS5cJlh4Q5hCfF58P2T8N5SN578yU8dPrvCIPN9f329vqbv9zt_1-V4GUbam4BNY1yERjnagbhZZho5xU0vRWWcP7hjloW1v3CJy1zCJHELVyreOAIK_Il3PuMcVfJ8xFj_GUwlypher6ltddzWZVc1ZBijkndPqY_MGkZ82ZXuDrUb_C1wt8fYY_-76dfTi_8Ntj0hk8Lrh8QijaRv9Gwn-H2ZLp</recordid><startdate>20220905</startdate><enddate>20220905</enddate><creator>Zhu, Yu</creator><creator>Xv, Qinyun</creator><creator>Wang, Dan</creator><creator>Sun, Bingxin</creator><creator>Wang, Yujia</creator><creator>Han, Zhiguo</creator><creator>Gou, Yongbo</creator><creator>Liu, Jiayu</creator><creator>Li, Bingdong</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20220905</creationdate><title>Construction of a hollow BiOI/TiO2/ZIF-8 heterojunction: Enhanced photocatalytic performance for norfloxacin degradation and mechanistic insight</title><author>Zhu, Yu ; Xv, Qinyun ; Wang, Dan ; Sun, Bingxin ; Wang, Yujia ; Han, Zhiguo ; Gou, Yongbo ; Liu, Jiayu ; Li, Bingdong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-13c085e025df2456ed0e56f363a9d6da1950fc77d49ec1070de1ec246f7f1cec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>BiOI</topic><topic>Carrier recombination</topic><topic>Catalytic activity</topic><topic>Current carriers</topic><topic>Heterojunctions</topic><topic>Heterostructures</topic><topic>Light irradiation</topic><topic>Metal organic framework</topic><topic>Norfloxacin</topic><topic>P-n heterojunction</topic><topic>P-n junctions</topic><topic>Performance degradation</topic><topic>Photocatalysis</topic><topic>Photocatalytic degradation</topic><topic>Photodegradation</topic><topic>Photoelectric effect</topic><topic>Photoluminescence</topic><topic>Titanium dioxide</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhu, Yu</creatorcontrib><creatorcontrib>Xv, Qinyun</creatorcontrib><creatorcontrib>Wang, Dan</creatorcontrib><creatorcontrib>Sun, Bingxin</creatorcontrib><creatorcontrib>Wang, Yujia</creatorcontrib><creatorcontrib>Han, Zhiguo</creatorcontrib><creatorcontrib>Gou, Yongbo</creatorcontrib><creatorcontrib>Liu, Jiayu</creatorcontrib><creatorcontrib>Li, Bingdong</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhu, Yu</au><au>Xv, Qinyun</au><au>Wang, Dan</au><au>Sun, Bingxin</au><au>Wang, Yujia</au><au>Han, Zhiguo</au><au>Gou, Yongbo</au><au>Liu, Jiayu</au><au>Li, Bingdong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Construction of a hollow BiOI/TiO2/ZIF-8 heterojunction: Enhanced photocatalytic performance for norfloxacin degradation and mechanistic insight</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2022-09-05</date><risdate>2022</risdate><volume>914</volume><spage>165326</spage><pages>165326-</pages><artnum>165326</artnum><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>The overuse of norfloxacin (NOR) has attracted wide attention because of the persistence and bio-accumulate in ecosystems and the negative impacts on human health. To solve the environmental issue, BiOI/TiO2 p-n heterojunctions have been developed and decorated with a porous ZIF-8 to obtain novel hollow BiOI/TiO2/ZIF-8 heterojunctions, which were further characterized by XRD, SEM, HRTEM, XPS, BET, UV–vis DRS, photoluminescence, ESR, photocurrent and EIS analyses. The BiOI/TiO2/ZIF-8 heterojunctions exhibited evidently improved photocatalytic performance compared with pristine BiOI, TiO2 and BiOI/TiO2 composites under visible light irradiation. ZIF-8 plays a key role in both the enhancement of adsorption and the photocatalytic activity in NOR removal. ·O2- and ·OH radicals were the two dominating active species in the photocatalytic process according to the trapping experiments. In 2-BTZ system, large specific surface area, highly effective charge carrier migration with inhibiting recombination, more negative CB and positive VB to generate more active ·O2- and ·OH species resulted in superior photocatalytic activity. This work provides a new idea to design a kind of photocatalytic heterostructure with more active species for potential application in the field of environmental treatment.
•A series of hollow BiOI/TiO2/ZIF-8 heterojunctions have been obtained with improved photocatalytic activities.•The ·O2- and ·OH radicals should be the two dominating active species according to the trapping experiments.•Decorating porous ZIF-8 improves adsorption performance and achieves the more efficient hole-charge transfer.•In 2-BTZ system, it can provide more negative CB and more positive VB to generate more active ·O2- and ·OH species.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2022.165326</doi></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0925-8388 |
ispartof | Journal of alloys and compounds, 2022-09, Vol.914, p.165326, Article 165326 |
issn | 0925-8388 1873-4669 |
language | eng |
recordid | cdi_proquest_journals_2689714840 |
source | Elsevier ScienceDirect Journals Complete |
subjects | BiOI Carrier recombination Catalytic activity Current carriers Heterojunctions Heterostructures Light irradiation Metal organic framework Norfloxacin P-n heterojunction P-n junctions Performance degradation Photocatalysis Photocatalytic degradation Photodegradation Photoelectric effect Photoluminescence Titanium dioxide X ray photoelectron spectroscopy |
title | Construction of a hollow BiOI/TiO2/ZIF-8 heterojunction: Enhanced photocatalytic performance for norfloxacin degradation and mechanistic insight |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T12%3A16%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Construction%20of%20a%20hollow%20BiOI/TiO2/ZIF-8%20heterojunction:%20Enhanced%20photocatalytic%20performance%20for%20norfloxacin%20degradation%20and%20mechanistic%20insight&rft.jtitle=Journal%20of%20alloys%20and%20compounds&rft.au=Zhu,%20Yu&rft.date=2022-09-05&rft.volume=914&rft.spage=165326&rft.pages=165326-&rft.artnum=165326&rft.issn=0925-8388&rft.eissn=1873-4669&rft_id=info:doi/10.1016/j.jallcom.2022.165326&rft_dat=%3Cproquest_cross%3E2689714840%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2689714840&rft_id=info:pmid/&rft_els_id=S0925838822017170&rfr_iscdi=true |