Electrodeposition of self-supported NiMo amorphous coating as an efficient and stable catalyst for hydrogen evolution reaction
NiMo-based materials have been identified as potential candidates of Pt/C electrocatalysts for hydrogen evolution reaction (HER) due to appropriate binding energy to hydrogen, and good resistance to corrosive environments. However, little work has been carried out to enhance the catalytic performanc...
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| Veröffentlicht in: | Rare metals 2022-08, Vol.41 (8), p.2624-2632 |
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| creator | Yuan, Fu-Hang Mohammadi, Mohammad-Reza Ma, Li-Li Cui, Zhen-Duo Zhu, Sheng-Li Li, Zhao-Yang Wu, Shui-Lin Jiang, Hui Liang, Yan-Qin |
| description | NiMo-based materials have been identified as potential candidates of Pt/C electrocatalysts for hydrogen evolution reaction (HER) due to appropriate binding energy to hydrogen, and good resistance to corrosive environments. However, little work has been carried out to enhance the catalytic performance in large-scale water-alkali electrolysis. The NiMo amorphous coating, as a high-efficient and cost-effective catalyst toward HER, was synthesized by a facile electrodeposition strategy in this study. The effects of the pH value of electrolyte on the structure and HER activity of NiMo coating were investigated. The as-prepared NiMo
(pH10)
exhibited the highest HER activity with overpotentials of 63.9 and 157.1 mV (vs. RHE, with 80% potential drop due to electrical resistance (
iR
) compensation) at the current density of − 10 mA·cm
−2
and − 100 mA·cm
−2
. This NiMo
(pH10)
coating also had excellent long-term durability of up to 100 h stable operation under the constant current density of − 100 mA·cm
−2
. The rapid HER kinetics and outstanding endurance can be ascribed to the NiMo compact coating with amorphous structures as well as good contact between NiMo coating and Ni foam substrate, endowing it grand feasibility in practical industrial applications.
Graphical abstract |
| doi_str_mv | 10.1007/s12598-022-01967-6 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2689682628</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2689682628</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-9972aeb4781b65d156630df8b671369ebaf3df8b9ba79ee0d815fe3b34a43dcd3</originalsourceid><addsrcrecordid>eNp9kMtOwzAURCMEEqXwA6wssQ74kTj2ElXlIRXYwNpy4us2VRoH20Hqhm_HbZDYsbpzpTMz0mTZNcG3BOPqLhBaSpFjSnNMJK9yfpLNiEiiIqI8TRpjkuOSkvPsIoQtxkXBOZ5l38sOmuidgcGFNrauR86iAJ3NwzgMzkcw6LV9cUjvnB82bgyocTq2_RrpgHSPwNq2aaGP6TEoRF13gBoddbcPEVnn0WZvvFtDQr9cNx47POjmIC6zM6u7AFe_d559PCzfF0_56u3xeXG_yhtGZMylrKiGuqgEqXlpSMk5w8aKmleEcQm1tuzwylpXEgAbQUoLrGaFLphpDJtnN1Pu4N3nCCGqrRt9nyoV5UJyQTkViaIT1XgXggerBt_utN8rgtVhZzXtrNLO6riz4snEJlNIcL8G_xf9j-sHl32D5Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2689682628</pqid></control><display><type>article</type><title>Electrodeposition of self-supported NiMo amorphous coating as an efficient and stable catalyst for hydrogen evolution reaction</title><source>SpringerLink Journals</source><source>Alma/SFX Local Collection</source><creator>Yuan, Fu-Hang ; Mohammadi, Mohammad-Reza ; Ma, Li-Li ; Cui, Zhen-Duo ; Zhu, Sheng-Li ; Li, Zhao-Yang ; Wu, Shui-Lin ; Jiang, Hui ; Liang, Yan-Qin</creator><creatorcontrib>Yuan, Fu-Hang ; Mohammadi, Mohammad-Reza ; Ma, Li-Li ; Cui, Zhen-Duo ; Zhu, Sheng-Li ; Li, Zhao-Yang ; Wu, Shui-Lin ; Jiang, Hui ; Liang, Yan-Qin</creatorcontrib><description>NiMo-based materials have been identified as potential candidates of Pt/C electrocatalysts for hydrogen evolution reaction (HER) due to appropriate binding energy to hydrogen, and good resistance to corrosive environments. However, little work has been carried out to enhance the catalytic performance in large-scale water-alkali electrolysis. The NiMo amorphous coating, as a high-efficient and cost-effective catalyst toward HER, was synthesized by a facile electrodeposition strategy in this study. The effects of the pH value of electrolyte on the structure and HER activity of NiMo coating were investigated. The as-prepared NiMo
(pH10)
exhibited the highest HER activity with overpotentials of 63.9 and 157.1 mV (vs. RHE, with 80% potential drop due to electrical resistance (
iR
) compensation) at the current density of − 10 mA·cm
−2
and − 100 mA·cm
−2
. This NiMo
(pH10)
coating also had excellent long-term durability of up to 100 h stable operation under the constant current density of − 100 mA·cm
−2
. The rapid HER kinetics and outstanding endurance can be ascribed to the NiMo compact coating with amorphous structures as well as good contact between NiMo coating and Ni foam substrate, endowing it grand feasibility in practical industrial applications.
Graphical abstract</description><identifier>ISSN: 1001-0521</identifier><identifier>EISSN: 1867-7185</identifier><identifier>DOI: 10.1007/s12598-022-01967-6</identifier><language>eng</language><publisher>Beijing: Nonferrous Metals Society of China</publisher><subject>Biomaterials ; Catalysts ; Chemical synthesis ; Chemistry and Materials Science ; Coated electrodes ; Corrosion resistance ; Current density ; Durability ; Electric contacts ; Electrocatalysts ; Electrodeposition ; Electrolysis ; Energy ; Hydrogen evolution reactions ; Hydrogen-based energy ; Industrial applications ; Materials Engineering ; Materials Science ; Metal foams ; Metallic Materials ; Nanoscale Science and Technology ; Original Article ; Physical Chemistry ; Substrates</subject><ispartof>Rare metals, 2022-08, Vol.41 (8), p.2624-2632</ispartof><rights>Youke Publishing Co.,Ltd 2022</rights><rights>Youke Publishing Co.,Ltd 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-9972aeb4781b65d156630df8b671369ebaf3df8b9ba79ee0d815fe3b34a43dcd3</citedby><cites>FETCH-LOGICAL-c319t-9972aeb4781b65d156630df8b671369ebaf3df8b9ba79ee0d815fe3b34a43dcd3</cites><orcidid>0000-0001-6317-8314 ; 0000-0002-4577-2886</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12598-022-01967-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12598-022-01967-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Yuan, Fu-Hang</creatorcontrib><creatorcontrib>Mohammadi, Mohammad-Reza</creatorcontrib><creatorcontrib>Ma, Li-Li</creatorcontrib><creatorcontrib>Cui, Zhen-Duo</creatorcontrib><creatorcontrib>Zhu, Sheng-Li</creatorcontrib><creatorcontrib>Li, Zhao-Yang</creatorcontrib><creatorcontrib>Wu, Shui-Lin</creatorcontrib><creatorcontrib>Jiang, Hui</creatorcontrib><creatorcontrib>Liang, Yan-Qin</creatorcontrib><title>Electrodeposition of self-supported NiMo amorphous coating as an efficient and stable catalyst for hydrogen evolution reaction</title><title>Rare metals</title><addtitle>Rare Met</addtitle><description>NiMo-based materials have been identified as potential candidates of Pt/C electrocatalysts for hydrogen evolution reaction (HER) due to appropriate binding energy to hydrogen, and good resistance to corrosive environments. However, little work has been carried out to enhance the catalytic performance in large-scale water-alkali electrolysis. The NiMo amorphous coating, as a high-efficient and cost-effective catalyst toward HER, was synthesized by a facile electrodeposition strategy in this study. The effects of the pH value of electrolyte on the structure and HER activity of NiMo coating were investigated. The as-prepared NiMo
(pH10)
exhibited the highest HER activity with overpotentials of 63.9 and 157.1 mV (vs. RHE, with 80% potential drop due to electrical resistance (
iR
) compensation) at the current density of − 10 mA·cm
−2
and − 100 mA·cm
−2
. This NiMo
(pH10)
coating also had excellent long-term durability of up to 100 h stable operation under the constant current density of − 100 mA·cm
−2
. The rapid HER kinetics and outstanding endurance can be ascribed to the NiMo compact coating with amorphous structures as well as good contact between NiMo coating and Ni foam substrate, endowing it grand feasibility in practical industrial applications.
Graphical abstract</description><subject>Biomaterials</subject><subject>Catalysts</subject><subject>Chemical synthesis</subject><subject>Chemistry and Materials Science</subject><subject>Coated electrodes</subject><subject>Corrosion resistance</subject><subject>Current density</subject><subject>Durability</subject><subject>Electric contacts</subject><subject>Electrocatalysts</subject><subject>Electrodeposition</subject><subject>Electrolysis</subject><subject>Energy</subject><subject>Hydrogen evolution reactions</subject><subject>Hydrogen-based energy</subject><subject>Industrial applications</subject><subject>Materials Engineering</subject><subject>Materials Science</subject><subject>Metal foams</subject><subject>Metallic Materials</subject><subject>Nanoscale Science and Technology</subject><subject>Original Article</subject><subject>Physical Chemistry</subject><subject>Substrates</subject><issn>1001-0521</issn><issn>1867-7185</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAURCMEEqXwA6wssQ74kTj2ElXlIRXYwNpy4us2VRoH20Hqhm_HbZDYsbpzpTMz0mTZNcG3BOPqLhBaSpFjSnNMJK9yfpLNiEiiIqI8TRpjkuOSkvPsIoQtxkXBOZ5l38sOmuidgcGFNrauR86iAJ3NwzgMzkcw6LV9cUjvnB82bgyocTq2_RrpgHSPwNq2aaGP6TEoRF13gBoddbcPEVnn0WZvvFtDQr9cNx47POjmIC6zM6u7AFe_d559PCzfF0_56u3xeXG_yhtGZMylrKiGuqgEqXlpSMk5w8aKmleEcQm1tuzwylpXEgAbQUoLrGaFLphpDJtnN1Pu4N3nCCGqrRt9nyoV5UJyQTkViaIT1XgXggerBt_utN8rgtVhZzXtrNLO6riz4snEJlNIcL8G_xf9j-sHl32D5Q</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>Yuan, Fu-Hang</creator><creator>Mohammadi, Mohammad-Reza</creator><creator>Ma, Li-Li</creator><creator>Cui, Zhen-Duo</creator><creator>Zhu, Sheng-Li</creator><creator>Li, Zhao-Yang</creator><creator>Wu, Shui-Lin</creator><creator>Jiang, Hui</creator><creator>Liang, Yan-Qin</creator><general>Nonferrous Metals Society of China</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-6317-8314</orcidid><orcidid>https://orcid.org/0000-0002-4577-2886</orcidid></search><sort><creationdate>20220801</creationdate><title>Electrodeposition of self-supported NiMo amorphous coating as an efficient and stable catalyst for hydrogen evolution reaction</title><author>Yuan, Fu-Hang ; Mohammadi, Mohammad-Reza ; Ma, Li-Li ; Cui, Zhen-Duo ; Zhu, Sheng-Li ; Li, Zhao-Yang ; Wu, Shui-Lin ; Jiang, Hui ; Liang, Yan-Qin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-9972aeb4781b65d156630df8b671369ebaf3df8b9ba79ee0d815fe3b34a43dcd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Biomaterials</topic><topic>Catalysts</topic><topic>Chemical synthesis</topic><topic>Chemistry and Materials Science</topic><topic>Coated electrodes</topic><topic>Corrosion resistance</topic><topic>Current density</topic><topic>Durability</topic><topic>Electric contacts</topic><topic>Electrocatalysts</topic><topic>Electrodeposition</topic><topic>Electrolysis</topic><topic>Energy</topic><topic>Hydrogen evolution reactions</topic><topic>Hydrogen-based energy</topic><topic>Industrial applications</topic><topic>Materials Engineering</topic><topic>Materials Science</topic><topic>Metal foams</topic><topic>Metallic Materials</topic><topic>Nanoscale Science and Technology</topic><topic>Original Article</topic><topic>Physical Chemistry</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yuan, Fu-Hang</creatorcontrib><creatorcontrib>Mohammadi, Mohammad-Reza</creatorcontrib><creatorcontrib>Ma, Li-Li</creatorcontrib><creatorcontrib>Cui, Zhen-Duo</creatorcontrib><creatorcontrib>Zhu, Sheng-Li</creatorcontrib><creatorcontrib>Li, Zhao-Yang</creatorcontrib><creatorcontrib>Wu, Shui-Lin</creatorcontrib><creatorcontrib>Jiang, Hui</creatorcontrib><creatorcontrib>Liang, Yan-Qin</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Rare metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yuan, Fu-Hang</au><au>Mohammadi, Mohammad-Reza</au><au>Ma, Li-Li</au><au>Cui, Zhen-Duo</au><au>Zhu, Sheng-Li</au><au>Li, Zhao-Yang</au><au>Wu, Shui-Lin</au><au>Jiang, Hui</au><au>Liang, Yan-Qin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrodeposition of self-supported NiMo amorphous coating as an efficient and stable catalyst for hydrogen evolution reaction</atitle><jtitle>Rare metals</jtitle><stitle>Rare Met</stitle><date>2022-08-01</date><risdate>2022</risdate><volume>41</volume><issue>8</issue><spage>2624</spage><epage>2632</epage><pages>2624-2632</pages><issn>1001-0521</issn><eissn>1867-7185</eissn><abstract>NiMo-based materials have been identified as potential candidates of Pt/C electrocatalysts for hydrogen evolution reaction (HER) due to appropriate binding energy to hydrogen, and good resistance to corrosive environments. However, little work has been carried out to enhance the catalytic performance in large-scale water-alkali electrolysis. The NiMo amorphous coating, as a high-efficient and cost-effective catalyst toward HER, was synthesized by a facile electrodeposition strategy in this study. The effects of the pH value of electrolyte on the structure and HER activity of NiMo coating were investigated. The as-prepared NiMo
(pH10)
exhibited the highest HER activity with overpotentials of 63.9 and 157.1 mV (vs. RHE, with 80% potential drop due to electrical resistance (
iR
) compensation) at the current density of − 10 mA·cm
−2
and − 100 mA·cm
−2
. This NiMo
(pH10)
coating also had excellent long-term durability of up to 100 h stable operation under the constant current density of − 100 mA·cm
−2
. The rapid HER kinetics and outstanding endurance can be ascribed to the NiMo compact coating with amorphous structures as well as good contact between NiMo coating and Ni foam substrate, endowing it grand feasibility in practical industrial applications.
Graphical abstract</abstract><cop>Beijing</cop><pub>Nonferrous Metals Society of China</pub><doi>10.1007/s12598-022-01967-6</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-6317-8314</orcidid><orcidid>https://orcid.org/0000-0002-4577-2886</orcidid></addata></record> |
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| subjects | Biomaterials Catalysts Chemical synthesis Chemistry and Materials Science Coated electrodes Corrosion resistance Current density Durability Electric contacts Electrocatalysts Electrodeposition Electrolysis Energy Hydrogen evolution reactions Hydrogen-based energy Industrial applications Materials Engineering Materials Science Metal foams Metallic Materials Nanoscale Science and Technology Original Article Physical Chemistry Substrates |
| title | Electrodeposition of self-supported NiMo amorphous coating as an efficient and stable catalyst for hydrogen evolution reaction |
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