Facile synthesis of PdCu nanocluster-assembled granular films as highly efficient electrocatalysts for formic acid oxidation
Developing efficient and stable bimetallic Pd-based anode electrocatalysts toward formic acid oxidation (FAO) is of great significance for commercial applications of direct formic acid fuel cells (DFAFCs). Herein, we report a facile synthesis approach to fabricate PdCu nanoclusters (NCs) catalysts w...
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| Veröffentlicht in: | Rare metals 2022-08, Vol.41 (8), p.2595-2605 |
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| creator | Ding, Qing-Wei Luo, Qing Lin, Liang Fu, Xing-Ping Wang, Lai-Sen Yue, Guang-Hui Lin, Jie Xie, Qing-Shui Peng, Dong-Liang |
| description | Developing efficient and stable bimetallic Pd-based anode electrocatalysts toward formic acid oxidation (FAO) is of great significance for commercial applications of direct formic acid fuel cells (DFAFCs). Herein, we report a facile synthesis approach to fabricate PdCu nanoclusters (NCs) catalysts with granular-film structure. The introduction of Cu can adjust the electronic structure and d-band center of Pd, which can improve the catalytic performance of the catalysts. Compared with Pd NCs catalyst, the catalytic durability and activity of PdCu NCs catalysts for FAO are greatly improved. The order for catalytic activity of NC metals is Pd
85
Cu
15
NCs > Pd
70
Cu
30
NCs > Pd NCs. The maximum mass activity can be acquired with the Pd
85
Cu
15
NCs catalyst, which is about 1.7 times that of the Pd NCs catalyst. And Pd
85
Cu
15
NCs catalyst still maintains the highest catalytic current density after 50 cycles, indicating that Pd
85
Cu
15
NCs catalyst has the best durability and electrocatalytic activity for FAO. Our work provides a new prospect for the design of highly efficient anode catalysts materials for DFAFCs.
Graphical Abstract |
| doi_str_mv | 10.1007/s12598-022-01997-0 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2689682095</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2689682095</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-50988c76a59d35bdc145453c6d8202ab8b871111bbcf749397dc83f156e044e33</originalsourceid><addsrcrecordid>eNp9kEFLAzEQhRdRsFb_gKeA52iyu9lNjlKsCgU96Dlks0mbkm5qJgsW_PGmruDNgWHm8N4b5iuKa0puKSHtHdCSCY5JWWJChWgxOSlmlDctbilnp3knhGLCSnpeXABsCanrpiGz4muptPMGwWFIGwMOULDotV-MaFBD0H6EZCJWAGbXedOjdVTD6FVE1vkdIAVo49Ybf0DGWqedGRIy3ugUg1ZJ-QMkQDbEY--cRvlYj8Kn61VyYbgszqzyYK5-57x4Xz68LZ7w6uXxeXG_wrqiImFGBOe6bRQTfcW6XtOa1azSTc9LUqqOd7ylubpO27YWlWh7zStLWWPym6aq5sXNlLuP4WM0kOQ2jHHIJ2XZcNHkGMGyqpxUOgaAaKzcR7dT8SApkUfKcqIsM2X5Q1mSbKomE2TxsDbxL_of1zdTfIGq</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2689682095</pqid></control><display><type>article</type><title>Facile synthesis of PdCu nanocluster-assembled granular films as highly efficient electrocatalysts for formic acid oxidation</title><source>SpringerLink Journals</source><source>Alma/SFX Local Collection</source><creator>Ding, Qing-Wei ; Luo, Qing ; Lin, Liang ; Fu, Xing-Ping ; Wang, Lai-Sen ; Yue, Guang-Hui ; Lin, Jie ; Xie, Qing-Shui ; Peng, Dong-Liang</creator><creatorcontrib>Ding, Qing-Wei ; Luo, Qing ; Lin, Liang ; Fu, Xing-Ping ; Wang, Lai-Sen ; Yue, Guang-Hui ; Lin, Jie ; Xie, Qing-Shui ; Peng, Dong-Liang</creatorcontrib><description>Developing efficient and stable bimetallic Pd-based anode electrocatalysts toward formic acid oxidation (FAO) is of great significance for commercial applications of direct formic acid fuel cells (DFAFCs). Herein, we report a facile synthesis approach to fabricate PdCu nanoclusters (NCs) catalysts with granular-film structure. The introduction of Cu can adjust the electronic structure and d-band center of Pd, which can improve the catalytic performance of the catalysts. Compared with Pd NCs catalyst, the catalytic durability and activity of PdCu NCs catalysts for FAO are greatly improved. The order for catalytic activity of NC metals is Pd
85
Cu
15
NCs > Pd
70
Cu
30
NCs > Pd NCs. The maximum mass activity can be acquired with the Pd
85
Cu
15
NCs catalyst, which is about 1.7 times that of the Pd NCs catalyst. And Pd
85
Cu
15
NCs catalyst still maintains the highest catalytic current density after 50 cycles, indicating that Pd
85
Cu
15
NCs catalyst has the best durability and electrocatalytic activity for FAO. Our work provides a new prospect for the design of highly efficient anode catalysts materials for DFAFCs.
Graphical Abstract</description><identifier>ISSN: 1001-0521</identifier><identifier>EISSN: 1867-7185</identifier><identifier>DOI: 10.1007/s12598-022-01997-0</identifier><language>eng</language><publisher>Beijing: Nonferrous Metals Society of China</publisher><subject>Anodes ; Anodizing ; Bimetals ; Biomaterials ; Catalysts ; Catalytic activity ; Chemistry and Materials Science ; Durability ; Electrocatalysts ; Electronic structure ; Energy ; Formic acid ; Fuel cells ; Materials Engineering ; Materials Science ; Metallic Materials ; Nanoclusters ; Nanoscale Science and Technology ; Original Article ; Oxidation ; Palladium ; Physical Chemistry</subject><ispartof>Rare metals, 2022-08, Vol.41 (8), p.2595-2605</ispartof><rights>Youke Publishing Co.,Ltd 2022</rights><rights>Youke Publishing Co.,Ltd 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-50988c76a59d35bdc145453c6d8202ab8b871111bbcf749397dc83f156e044e33</citedby><cites>FETCH-LOGICAL-c319t-50988c76a59d35bdc145453c6d8202ab8b871111bbcf749397dc83f156e044e33</cites><orcidid>0000-0003-2523-3313</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12598-022-01997-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12598-022-01997-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Ding, Qing-Wei</creatorcontrib><creatorcontrib>Luo, Qing</creatorcontrib><creatorcontrib>Lin, Liang</creatorcontrib><creatorcontrib>Fu, Xing-Ping</creatorcontrib><creatorcontrib>Wang, Lai-Sen</creatorcontrib><creatorcontrib>Yue, Guang-Hui</creatorcontrib><creatorcontrib>Lin, Jie</creatorcontrib><creatorcontrib>Xie, Qing-Shui</creatorcontrib><creatorcontrib>Peng, Dong-Liang</creatorcontrib><title>Facile synthesis of PdCu nanocluster-assembled granular films as highly efficient electrocatalysts for formic acid oxidation</title><title>Rare metals</title><addtitle>Rare Met</addtitle><description>Developing efficient and stable bimetallic Pd-based anode electrocatalysts toward formic acid oxidation (FAO) is of great significance for commercial applications of direct formic acid fuel cells (DFAFCs). Herein, we report a facile synthesis approach to fabricate PdCu nanoclusters (NCs) catalysts with granular-film structure. The introduction of Cu can adjust the electronic structure and d-band center of Pd, which can improve the catalytic performance of the catalysts. Compared with Pd NCs catalyst, the catalytic durability and activity of PdCu NCs catalysts for FAO are greatly improved. The order for catalytic activity of NC metals is Pd
85
Cu
15
NCs > Pd
70
Cu
30
NCs > Pd NCs. The maximum mass activity can be acquired with the Pd
85
Cu
15
NCs catalyst, which is about 1.7 times that of the Pd NCs catalyst. And Pd
85
Cu
15
NCs catalyst still maintains the highest catalytic current density after 50 cycles, indicating that Pd
85
Cu
15
NCs catalyst has the best durability and electrocatalytic activity for FAO. Our work provides a new prospect for the design of highly efficient anode catalysts materials for DFAFCs.
Graphical Abstract</description><subject>Anodes</subject><subject>Anodizing</subject><subject>Bimetals</subject><subject>Biomaterials</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemistry and Materials Science</subject><subject>Durability</subject><subject>Electrocatalysts</subject><subject>Electronic structure</subject><subject>Energy</subject><subject>Formic acid</subject><subject>Fuel cells</subject><subject>Materials Engineering</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Nanoclusters</subject><subject>Nanoscale Science and Technology</subject><subject>Original Article</subject><subject>Oxidation</subject><subject>Palladium</subject><subject>Physical Chemistry</subject><issn>1001-0521</issn><issn>1867-7185</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kEFLAzEQhRdRsFb_gKeA52iyu9lNjlKsCgU96Dlks0mbkm5qJgsW_PGmruDNgWHm8N4b5iuKa0puKSHtHdCSCY5JWWJChWgxOSlmlDctbilnp3knhGLCSnpeXABsCanrpiGz4muptPMGwWFIGwMOULDotV-MaFBD0H6EZCJWAGbXedOjdVTD6FVE1vkdIAVo49Ybf0DGWqedGRIy3ugUg1ZJ-QMkQDbEY--cRvlYj8Kn61VyYbgszqzyYK5-57x4Xz68LZ7w6uXxeXG_wrqiImFGBOe6bRQTfcW6XtOa1azSTc9LUqqOd7ylubpO27YWlWh7zStLWWPym6aq5sXNlLuP4WM0kOQ2jHHIJ2XZcNHkGMGyqpxUOgaAaKzcR7dT8SApkUfKcqIsM2X5Q1mSbKomE2TxsDbxL_of1zdTfIGq</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>Ding, Qing-Wei</creator><creator>Luo, Qing</creator><creator>Lin, Liang</creator><creator>Fu, Xing-Ping</creator><creator>Wang, Lai-Sen</creator><creator>Yue, Guang-Hui</creator><creator>Lin, Jie</creator><creator>Xie, Qing-Shui</creator><creator>Peng, Dong-Liang</creator><general>Nonferrous Metals Society of China</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-2523-3313</orcidid></search><sort><creationdate>20220801</creationdate><title>Facile synthesis of PdCu nanocluster-assembled granular films as highly efficient electrocatalysts for formic acid oxidation</title><author>Ding, Qing-Wei ; Luo, Qing ; Lin, Liang ; Fu, Xing-Ping ; Wang, Lai-Sen ; Yue, Guang-Hui ; Lin, Jie ; Xie, Qing-Shui ; Peng, Dong-Liang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-50988c76a59d35bdc145453c6d8202ab8b871111bbcf749397dc83f156e044e33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Anodes</topic><topic>Anodizing</topic><topic>Bimetals</topic><topic>Biomaterials</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemistry and Materials Science</topic><topic>Durability</topic><topic>Electrocatalysts</topic><topic>Electronic structure</topic><topic>Energy</topic><topic>Formic acid</topic><topic>Fuel cells</topic><topic>Materials Engineering</topic><topic>Materials Science</topic><topic>Metallic Materials</topic><topic>Nanoclusters</topic><topic>Nanoscale Science and Technology</topic><topic>Original Article</topic><topic>Oxidation</topic><topic>Palladium</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ding, Qing-Wei</creatorcontrib><creatorcontrib>Luo, Qing</creatorcontrib><creatorcontrib>Lin, Liang</creatorcontrib><creatorcontrib>Fu, Xing-Ping</creatorcontrib><creatorcontrib>Wang, Lai-Sen</creatorcontrib><creatorcontrib>Yue, Guang-Hui</creatorcontrib><creatorcontrib>Lin, Jie</creatorcontrib><creatorcontrib>Xie, Qing-Shui</creatorcontrib><creatorcontrib>Peng, Dong-Liang</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Rare metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ding, Qing-Wei</au><au>Luo, Qing</au><au>Lin, Liang</au><au>Fu, Xing-Ping</au><au>Wang, Lai-Sen</au><au>Yue, Guang-Hui</au><au>Lin, Jie</au><au>Xie, Qing-Shui</au><au>Peng, Dong-Liang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile synthesis of PdCu nanocluster-assembled granular films as highly efficient electrocatalysts for formic acid oxidation</atitle><jtitle>Rare metals</jtitle><stitle>Rare Met</stitle><date>2022-08-01</date><risdate>2022</risdate><volume>41</volume><issue>8</issue><spage>2595</spage><epage>2605</epage><pages>2595-2605</pages><issn>1001-0521</issn><eissn>1867-7185</eissn><abstract>Developing efficient and stable bimetallic Pd-based anode electrocatalysts toward formic acid oxidation (FAO) is of great significance for commercial applications of direct formic acid fuel cells (DFAFCs). Herein, we report a facile synthesis approach to fabricate PdCu nanoclusters (NCs) catalysts with granular-film structure. The introduction of Cu can adjust the electronic structure and d-band center of Pd, which can improve the catalytic performance of the catalysts. Compared with Pd NCs catalyst, the catalytic durability and activity of PdCu NCs catalysts for FAO are greatly improved. The order for catalytic activity of NC metals is Pd
85
Cu
15
NCs > Pd
70
Cu
30
NCs > Pd NCs. The maximum mass activity can be acquired with the Pd
85
Cu
15
NCs catalyst, which is about 1.7 times that of the Pd NCs catalyst. And Pd
85
Cu
15
NCs catalyst still maintains the highest catalytic current density after 50 cycles, indicating that Pd
85
Cu
15
NCs catalyst has the best durability and electrocatalytic activity for FAO. Our work provides a new prospect for the design of highly efficient anode catalysts materials for DFAFCs.
Graphical Abstract</abstract><cop>Beijing</cop><pub>Nonferrous Metals Society of China</pub><doi>10.1007/s12598-022-01997-0</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0003-2523-3313</orcidid></addata></record> |
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| subjects | Anodes Anodizing Bimetals Biomaterials Catalysts Catalytic activity Chemistry and Materials Science Durability Electrocatalysts Electronic structure Energy Formic acid Fuel cells Materials Engineering Materials Science Metallic Materials Nanoclusters Nanoscale Science and Technology Original Article Oxidation Palladium Physical Chemistry |
| title | Facile synthesis of PdCu nanocluster-assembled granular films as highly efficient electrocatalysts for formic acid oxidation |
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