Neutral Five‐Coordinate Arylated Copper(III) Complex: Key Intermediate in Copper‐Mediated Arene Trifluoromethylation

Comprehensive Summary Five‐coordinate neutral Cu(III) complexes have long been considered as the key intermediates in copper‐mediated/catalyzed arene trifluoromethylative reactions, but the identity of these complexes remains elusive. Herein, we reported, for the first time, the preparation and char...

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Veröffentlicht in:	Chinese journal of chemistry 2022-08, Vol.40 (16), p.1924-1930
Hauptverfasser:	Wang, Guangyu, Li, Man, Leng, Xuebing, Xue, Xiaosong, Shen, Qilong
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical reactions Concerted pathway Copper Cu(III) Intermediates Mechanism Reductive elimination Temperature effects Trifluoromethyl
Online-Zugang:	Volltext
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