Design of epoxy resin with sustainability, high adhesion and excellent flame retardancy based on bio-based molecules
The preparation of bio-based epoxy resin with excellent thermal properties and flame retardant properties from green renewable resources had attracted extensive attention in recent years. Starting from the driving structural properties, the purpose of this study is to prepare multifunctional triglyc...
Gespeichert in:
| Veröffentlicht in: | Journal of materials science 2022-07, Vol.57 (27), p.13078-13096 |
|---|---|
| Hauptverfasser: | , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 13096 |
|---|---|
| container_issue | 27 |
| container_start_page | 13078 |
| container_title | Journal of materials science |
| container_volume | 57 |
| creator | Xie, Ruihang Yuan, Yexin Sun, Pengbo Liu, Zhe Ma, Jinpeng Yang, Guorui Wang, Kui Li, Ming Shang, Lei Ao, Yuhui |
| description | The preparation of bio-based epoxy resin with excellent thermal properties and flame retardant properties from green renewable resources had attracted extensive attention in recent years. Starting from the driving structural properties, the purpose of this study is to prepare multifunctional triglycidylester- diphenolic acid- bio-based epoxy (TDBE) with diphenolic acid (DPA), triglycidyl isocyanurate (TGIC), and 9,10-dihydro-9-oxa-10-phosphophenanthrene 10 oxide (DOPO) as raw materials. TDBE/DDM and bisphenol A epoxy resin curing agent (DGEBA/DDM) was prepared with 4,4 '- diaminodiphenylmethane (DDM) as curing agent. TDBE/DDM has excellent fire safety. LOI value rose from 24.5 to 42.0%, and the UL-94 test level passes V-0 level. In the cone calorimeter test, the peak heat release rate (pHRR) is decreased by 69.3%. Besides, the lap shear TDBE adhesive strength was 42.9 MPa, which increased by 62.5%. This new multifunctional bio-based flame retardant epoxy resin provides a broader application prospect for high-performance materials.
Graphical Abstract |
| doi_str_mv | 10.1007/s10853-022-07399-y |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2689392795</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A710296043</galeid><sourcerecordid>A710296043</sourcerecordid><originalsourceid>FETCH-LOGICAL-c392t-5730005a6bfdf3bdb61cbe266548b2c66b8baad47c9faf89f3139c32350319e3</originalsourceid><addsrcrecordid>eNp9kU1rFTEUhoMoeK3-AVcBV4JT8zGTmSxLrbZQELT7kGRO5qbMTa5JBu_8e3MdoXQjWYSTPM85B16E3lNySQnpP2dKho43hLGG9FzKZn2BdrTredMOhL9EO3L-Yq2gr9GbnB8JIV3P6A6VL5D9FHB0GI7xtOJU64B_-7LHeclF-6CNn31ZP-G9n_ZYj_tKxIB1GDGcLMwzhILdrA9Q5aLTqINdsdEZRlw542OzFYc4g11myG_RK6fnDO_-3Rfo4evNw_Vtc__929311X1juWSlqeuf99TCuNFxMxpBrQEmRNcOhlkhzGC0HtveSqfdIB2nXFrOeEc4lcAv0Iet7THFXwvkoh7jkkKdqJgYZJ3Ry65Slxs16RmUDy6WpG09Ixy8jQGcr-9XPSVMCtLyKnx8JlSmwKlMeslZ3f388ZxlG2tTzDmBU8fkDzqtihJ1Tk5tyakaj_qbnFqrxDcpVzhMkJ72_o_1B9SNnMs</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2689392795</pqid></control><display><type>article</type><title>Design of epoxy resin with sustainability, high adhesion and excellent flame retardancy based on bio-based molecules</title><source>SpringerLink Journals - AutoHoldings</source><creator>Xie, Ruihang ; Yuan, Yexin ; Sun, Pengbo ; Liu, Zhe ; Ma, Jinpeng ; Yang, Guorui ; Wang, Kui ; Li, Ming ; Shang, Lei ; Ao, Yuhui</creator><creatorcontrib>Xie, Ruihang ; Yuan, Yexin ; Sun, Pengbo ; Liu, Zhe ; Ma, Jinpeng ; Yang, Guorui ; Wang, Kui ; Li, Ming ; Shang, Lei ; Ao, Yuhui</creatorcontrib><description>The preparation of bio-based epoxy resin with excellent thermal properties and flame retardant properties from green renewable resources had attracted extensive attention in recent years. Starting from the driving structural properties, the purpose of this study is to prepare multifunctional triglycidylester- diphenolic acid- bio-based epoxy (TDBE) with diphenolic acid (DPA), triglycidyl isocyanurate (TGIC), and 9,10-dihydro-9-oxa-10-phosphophenanthrene 10 oxide (DOPO) as raw materials. TDBE/DDM and bisphenol A epoxy resin curing agent (DGEBA/DDM) was prepared with 4,4 '- diaminodiphenylmethane (DDM) as curing agent. TDBE/DDM has excellent fire safety. LOI value rose from 24.5 to 42.0%, and the UL-94 test level passes V-0 level. In the cone calorimeter test, the peak heat release rate (pHRR) is decreased by 69.3%. Besides, the lap shear TDBE adhesive strength was 42.9 MPa, which increased by 62.5%. This new multifunctional bio-based flame retardant epoxy resin provides a broader application prospect for high-performance materials.
Graphical Abstract</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-022-07399-y</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Acids ; Additives ; Adhesive strength ; Biopolymers ; Bisphenol A ; Bond strength ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Cone calorimeters ; Crystallography and Scattering Methods ; Curing agents ; Epoxy resins ; Fire prevention ; Fire protection ; Fire safety ; Fireproofing agents ; Flame retardants ; Heat release rate ; Heat resistance ; Materials Science ; Mechanical properties ; Methylene dianiline ; NMR ; Nuclear magnetic resonance ; Phosphorus ; Polymer Sciences ; Polymers & Biopolymers ; Raw materials ; Renewable resources ; Solid Mechanics ; Sustainability ; Sustainable development ; Thermal properties ; Thermodynamic properties ; Triglycidyl isocyanurate</subject><ispartof>Journal of materials science, 2022-07, Vol.57 (27), p.13078-13096</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022</rights><rights>COPYRIGHT 2022 Springer</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c392t-5730005a6bfdf3bdb61cbe266548b2c66b8baad47c9faf89f3139c32350319e3</citedby><cites>FETCH-LOGICAL-c392t-5730005a6bfdf3bdb61cbe266548b2c66b8baad47c9faf89f3139c32350319e3</cites><orcidid>0000-0002-7426-037X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-022-07399-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-022-07399-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Xie, Ruihang</creatorcontrib><creatorcontrib>Yuan, Yexin</creatorcontrib><creatorcontrib>Sun, Pengbo</creatorcontrib><creatorcontrib>Liu, Zhe</creatorcontrib><creatorcontrib>Ma, Jinpeng</creatorcontrib><creatorcontrib>Yang, Guorui</creatorcontrib><creatorcontrib>Wang, Kui</creatorcontrib><creatorcontrib>Li, Ming</creatorcontrib><creatorcontrib>Shang, Lei</creatorcontrib><creatorcontrib>Ao, Yuhui</creatorcontrib><title>Design of epoxy resin with sustainability, high adhesion and excellent flame retardancy based on bio-based molecules</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>The preparation of bio-based epoxy resin with excellent thermal properties and flame retardant properties from green renewable resources had attracted extensive attention in recent years. Starting from the driving structural properties, the purpose of this study is to prepare multifunctional triglycidylester- diphenolic acid- bio-based epoxy (TDBE) with diphenolic acid (DPA), triglycidyl isocyanurate (TGIC), and 9,10-dihydro-9-oxa-10-phosphophenanthrene 10 oxide (DOPO) as raw materials. TDBE/DDM and bisphenol A epoxy resin curing agent (DGEBA/DDM) was prepared with 4,4 '- diaminodiphenylmethane (DDM) as curing agent. TDBE/DDM has excellent fire safety. LOI value rose from 24.5 to 42.0%, and the UL-94 test level passes V-0 level. In the cone calorimeter test, the peak heat release rate (pHRR) is decreased by 69.3%. Besides, the lap shear TDBE adhesive strength was 42.9 MPa, which increased by 62.5%. This new multifunctional bio-based flame retardant epoxy resin provides a broader application prospect for high-performance materials.
Graphical Abstract</description><subject>Acids</subject><subject>Additives</subject><subject>Adhesive strength</subject><subject>Biopolymers</subject><subject>Bisphenol A</subject><subject>Bond strength</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Cone calorimeters</subject><subject>Crystallography and Scattering Methods</subject><subject>Curing agents</subject><subject>Epoxy resins</subject><subject>Fire prevention</subject><subject>Fire protection</subject><subject>Fire safety</subject><subject>Fireproofing agents</subject><subject>Flame retardants</subject><subject>Heat release rate</subject><subject>Heat resistance</subject><subject>Materials Science</subject><subject>Mechanical properties</subject><subject>Methylene dianiline</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Phosphorus</subject><subject>Polymer Sciences</subject><subject>Polymers & Biopolymers</subject><subject>Raw materials</subject><subject>Renewable resources</subject><subject>Solid Mechanics</subject><subject>Sustainability</subject><subject>Sustainable development</subject><subject>Thermal properties</subject><subject>Thermodynamic properties</subject><subject>Triglycidyl isocyanurate</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kU1rFTEUhoMoeK3-AVcBV4JT8zGTmSxLrbZQELT7kGRO5qbMTa5JBu_8e3MdoXQjWYSTPM85B16E3lNySQnpP2dKho43hLGG9FzKZn2BdrTredMOhL9EO3L-Yq2gr9GbnB8JIV3P6A6VL5D9FHB0GI7xtOJU64B_-7LHeclF-6CNn31ZP-G9n_ZYj_tKxIB1GDGcLMwzhILdrA9Q5aLTqINdsdEZRlw542OzFYc4g11myG_RK6fnDO_-3Rfo4evNw_Vtc__929311X1juWSlqeuf99TCuNFxMxpBrQEmRNcOhlkhzGC0HtveSqfdIB2nXFrOeEc4lcAv0Iet7THFXwvkoh7jkkKdqJgYZJ3Ry65Slxs16RmUDy6WpG09Ixy8jQGcr-9XPSVMCtLyKnx8JlSmwKlMeslZ3f388ZxlG2tTzDmBU8fkDzqtihJ1Tk5tyakaj_qbnFqrxDcpVzhMkJ72_o_1B9SNnMs</recordid><startdate>20220701</startdate><enddate>20220701</enddate><creator>Xie, Ruihang</creator><creator>Yuan, Yexin</creator><creator>Sun, Pengbo</creator><creator>Liu, Zhe</creator><creator>Ma, Jinpeng</creator><creator>Yang, Guorui</creator><creator>Wang, Kui</creator><creator>Li, Ming</creator><creator>Shang, Lei</creator><creator>Ao, Yuhui</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-7426-037X</orcidid></search><sort><creationdate>20220701</creationdate><title>Design of epoxy resin with sustainability, high adhesion and excellent flame retardancy based on bio-based molecules</title><author>Xie, Ruihang ; Yuan, Yexin ; Sun, Pengbo ; Liu, Zhe ; Ma, Jinpeng ; Yang, Guorui ; Wang, Kui ; Li, Ming ; Shang, Lei ; Ao, Yuhui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c392t-5730005a6bfdf3bdb61cbe266548b2c66b8baad47c9faf89f3139c32350319e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Acids</topic><topic>Additives</topic><topic>Adhesive strength</topic><topic>Biopolymers</topic><topic>Bisphenol A</topic><topic>Bond strength</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Cone calorimeters</topic><topic>Crystallography and Scattering Methods</topic><topic>Curing agents</topic><topic>Epoxy resins</topic><topic>Fire prevention</topic><topic>Fire protection</topic><topic>Fire safety</topic><topic>Fireproofing agents</topic><topic>Flame retardants</topic><topic>Heat release rate</topic><topic>Heat resistance</topic><topic>Materials Science</topic><topic>Mechanical properties</topic><topic>Methylene dianiline</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Phosphorus</topic><topic>Polymer Sciences</topic><topic>Polymers & Biopolymers</topic><topic>Raw materials</topic><topic>Renewable resources</topic><topic>Solid Mechanics</topic><topic>Sustainability</topic><topic>Sustainable development</topic><topic>Thermal properties</topic><topic>Thermodynamic properties</topic><topic>Triglycidyl isocyanurate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xie, Ruihang</creatorcontrib><creatorcontrib>Yuan, Yexin</creatorcontrib><creatorcontrib>Sun, Pengbo</creatorcontrib><creatorcontrib>Liu, Zhe</creatorcontrib><creatorcontrib>Ma, Jinpeng</creatorcontrib><creatorcontrib>Yang, Guorui</creatorcontrib><creatorcontrib>Wang, Kui</creatorcontrib><creatorcontrib>Li, Ming</creatorcontrib><creatorcontrib>Shang, Lei</creatorcontrib><creatorcontrib>Ao, Yuhui</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xie, Ruihang</au><au>Yuan, Yexin</au><au>Sun, Pengbo</au><au>Liu, Zhe</au><au>Ma, Jinpeng</au><au>Yang, Guorui</au><au>Wang, Kui</au><au>Li, Ming</au><au>Shang, Lei</au><au>Ao, Yuhui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Design of epoxy resin with sustainability, high adhesion and excellent flame retardancy based on bio-based molecules</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2022-07-01</date><risdate>2022</risdate><volume>57</volume><issue>27</issue><spage>13078</spage><epage>13096</epage><pages>13078-13096</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>The preparation of bio-based epoxy resin with excellent thermal properties and flame retardant properties from green renewable resources had attracted extensive attention in recent years. Starting from the driving structural properties, the purpose of this study is to prepare multifunctional triglycidylester- diphenolic acid- bio-based epoxy (TDBE) with diphenolic acid (DPA), triglycidyl isocyanurate (TGIC), and 9,10-dihydro-9-oxa-10-phosphophenanthrene 10 oxide (DOPO) as raw materials. TDBE/DDM and bisphenol A epoxy resin curing agent (DGEBA/DDM) was prepared with 4,4 '- diaminodiphenylmethane (DDM) as curing agent. TDBE/DDM has excellent fire safety. LOI value rose from 24.5 to 42.0%, and the UL-94 test level passes V-0 level. In the cone calorimeter test, the peak heat release rate (pHRR) is decreased by 69.3%. Besides, the lap shear TDBE adhesive strength was 42.9 MPa, which increased by 62.5%. This new multifunctional bio-based flame retardant epoxy resin provides a broader application prospect for high-performance materials.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-022-07399-y</doi><tpages>19</tpages><orcidid>https://orcid.org/0000-0002-7426-037X</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-2461 |
| ispartof | Journal of materials science, 2022-07, Vol.57 (27), p.13078-13096 |
| issn | 0022-2461 1573-4803 |
| language | eng |
| recordid | cdi_proquest_journals_2689392795 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Acids Additives Adhesive strength Biopolymers Bisphenol A Bond strength Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Cone calorimeters Crystallography and Scattering Methods Curing agents Epoxy resins Fire prevention Fire protection Fire safety Fireproofing agents Flame retardants Heat release rate Heat resistance Materials Science Mechanical properties Methylene dianiline NMR Nuclear magnetic resonance Phosphorus Polymer Sciences Polymers & Biopolymers Raw materials Renewable resources Solid Mechanics Sustainability Sustainable development Thermal properties Thermodynamic properties Triglycidyl isocyanurate |
| title | Design of epoxy resin with sustainability, high adhesion and excellent flame retardancy based on bio-based molecules |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T19%3A00%3A24IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Design%20of%20epoxy%20resin%20with%20sustainability,%20high%20adhesion%20and%20excellent%20flame%20retardancy%20based%20on%20bio-based%20molecules&rft.jtitle=Journal%20of%20materials%20science&rft.au=Xie,%20Ruihang&rft.date=2022-07-01&rft.volume=57&rft.issue=27&rft.spage=13078&rft.epage=13096&rft.pages=13078-13096&rft.issn=0022-2461&rft.eissn=1573-4803&rft_id=info:doi/10.1007/s10853-022-07399-y&rft_dat=%3Cgale_proqu%3EA710296043%3C/gale_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2689392795&rft_id=info:pmid/&rft_galeid=A710296043&rfr_iscdi=true |