Waste-to-BioEnergy pathway for waste activated sludge from food processing industries: An experiment on the valorization potential under CO2 and N2 atmospheres through microwave-induced pyrolysis

[Display omitted] •Microwave pyrolysis successfully reduce the mass of waste activated sludge by 80 wt%.•CO2 pyrolysis improves CO generation in the gaseous product (up to ∼ 50 vol%).•CO2 pyrolysis produce biochar with higher energy density profit (11–14%).•N2 pyrolysis improves H2 generation in the...

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Veröffentlicht in:Fuel (Guildford) 2022-09, Vol.323, p.124380, Article 124380
Hauptverfasser: Mong, Guo Ren, Chong, William Woei Fong, Nor, Siti Aminah Mohd, Ng, Jo-Han, Chong, Cheng Tung, Idris, Rubia, Chiong, Meng Choung, Wong, Syieluing, Nyakuma, Bemgba Bevan
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container_end_page
container_issue
container_start_page 124380
container_title Fuel (Guildford)
container_volume 323
creator Mong, Guo Ren
Chong, William Woei Fong
Nor, Siti Aminah Mohd
Ng, Jo-Han
Chong, Cheng Tung
Idris, Rubia
Chiong, Meng Choung
Wong, Syieluing
Nyakuma, Bemgba Bevan
description [Display omitted] •Microwave pyrolysis successfully reduce the mass of waste activated sludge by 80 wt%.•CO2 pyrolysis improves CO generation in the gaseous product (up to ∼ 50 vol%).•CO2 pyrolysis produce biochar with higher energy density profit (11–14%).•N2 pyrolysis improves H2 generation in the gaseous product (up to ∼ 29 vol%).•Up to 83.2% of the energy stored within the waste can be retrieved in bioenergy form. Pyrolysis is a green and effective method for converting various waste streams into products with bio-energy potential. Waste activated sludge (WAS) from industries requires post-treatment before disposal and will cause serious pollution if not managed properly. Pyrolysis is a viable method for converting WAS into higher-value bio-products. This is the first study to use a lab-scaled microwave reactor to analyse WAS from a food processing and manufacturing company's wastewater treatment plant. The goal is to compare bioproduct formation under various N2 and CO2 atmospheres in order to analyse the WAS waste-to-bioproduct transformation pathway. Result revealed that CO2 pyrolysis on WAS tends to: 1) increase water formation (∼19 wt%), 2) produce biochar with higher energy density profit (∼14%) and 3) generate gaseous products with a higher CO proportion (∼50 vol%). WAS pyrolysis under N2 atmosphere showed 1) an overall better energy profit (
doi_str_mv 10.1016/j.fuel.2022.124380
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Pyrolysis is a green and effective method for converting various waste streams into products with bio-energy potential. Waste activated sludge (WAS) from industries requires post-treatment before disposal and will cause serious pollution if not managed properly. Pyrolysis is a viable method for converting WAS into higher-value bio-products. This is the first study to use a lab-scaled microwave reactor to analyse WAS from a food processing and manufacturing company's wastewater treatment plant. The goal is to compare bioproduct formation under various N2 and CO2 atmospheres in order to analyse the WAS waste-to-bioproduct transformation pathway. Result revealed that CO2 pyrolysis on WAS tends to: 1) increase water formation (∼19 wt%), 2) produce biochar with higher energy density profit (∼14%) and 3) generate gaseous products with a higher CO proportion (∼50 vol%). WAS pyrolysis under N2 atmosphere showed 1) an overall better energy profit (&lt;83.2 %), while producing 2) a higher gaseous yield (∼32 wt%) with 3) higher H2 proportion (∼29 vol%) and 4) biochar of larger surface area (22 m2/g). Integrating CO2 as the pyrolysis medium utilises the excess CO2, potentially relieving the carbon burden on the environment.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2022.124380</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Activated sludge ; Atmosphere ; Atmospheres ; Carbon dioxide ; Charcoal ; CO2 utilisation ; Conversion ; Energy ; Food industry ; Food processing ; Food processing industry ; Microwave pyrolysis ; Pyrolysis ; Renewable energy ; Waste activated sludge ; Waste management ; Waste streams ; Waste-to-BioEnergy ; Wastewater treatment ; Wastewater treatment plants</subject><ispartof>Fuel (Guildford), 2022-09, Vol.323, p.124380, Article 124380</ispartof><rights>2022 Elsevier Ltd</rights><rights>Copyright Elsevier BV Sep 1, 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c243t-fe88d4381d525e90169720ec747febaa7de8a76a0ba94ee8c244b25916eec5d63</citedby><cites>FETCH-LOGICAL-c243t-fe88d4381d525e90169720ec747febaa7de8a76a0ba94ee8c244b25916eec5d63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.fuel.2022.124380$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Mong, Guo Ren</creatorcontrib><creatorcontrib>Chong, William Woei Fong</creatorcontrib><creatorcontrib>Nor, Siti Aminah Mohd</creatorcontrib><creatorcontrib>Ng, Jo-Han</creatorcontrib><creatorcontrib>Chong, Cheng Tung</creatorcontrib><creatorcontrib>Idris, Rubia</creatorcontrib><creatorcontrib>Chiong, Meng Choung</creatorcontrib><creatorcontrib>Wong, Syieluing</creatorcontrib><creatorcontrib>Nyakuma, Bemgba Bevan</creatorcontrib><title>Waste-to-BioEnergy pathway for waste activated sludge from food processing industries: An experiment on the valorization potential under CO2 and N2 atmospheres through microwave-induced pyrolysis</title><title>Fuel (Guildford)</title><description>[Display omitted] •Microwave pyrolysis successfully reduce the mass of waste activated sludge by 80 wt%.•CO2 pyrolysis improves CO generation in the gaseous product (up to ∼ 50 vol%).•CO2 pyrolysis produce biochar with higher energy density profit (11–14%).•N2 pyrolysis improves H2 generation in the gaseous product (up to ∼ 29 vol%).•Up to 83.2% of the energy stored within the waste can be retrieved in bioenergy form. 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Pyrolysis is a green and effective method for converting various waste streams into products with bio-energy potential. Waste activated sludge (WAS) from industries requires post-treatment before disposal and will cause serious pollution if not managed properly. Pyrolysis is a viable method for converting WAS into higher-value bio-products. This is the first study to use a lab-scaled microwave reactor to analyse WAS from a food processing and manufacturing company's wastewater treatment plant. The goal is to compare bioproduct formation under various N2 and CO2 atmospheres in order to analyse the WAS waste-to-bioproduct transformation pathway. Result revealed that CO2 pyrolysis on WAS tends to: 1) increase water formation (∼19 wt%), 2) produce biochar with higher energy density profit (∼14%) and 3) generate gaseous products with a higher CO proportion (∼50 vol%). WAS pyrolysis under N2 atmosphere showed 1) an overall better energy profit (&lt;83.2 %), while producing 2) a higher gaseous yield (∼32 wt%) with 3) higher H2 proportion (∼29 vol%) and 4) biochar of larger surface area (22 m2/g). Integrating CO2 as the pyrolysis medium utilises the excess CO2, potentially relieving the carbon burden on the environment.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.fuel.2022.124380</doi></addata></record>
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1873-7153
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source Elsevier ScienceDirect Journals Complete
subjects Activated sludge
Atmosphere
Atmospheres
Carbon dioxide
Charcoal
CO2 utilisation
Conversion
Energy
Food industry
Food processing
Food processing industry
Microwave pyrolysis
Pyrolysis
Renewable energy
Waste activated sludge
Waste management
Waste streams
Waste-to-BioEnergy
Wastewater treatment
Wastewater treatment plants
title Waste-to-BioEnergy pathway for waste activated sludge from food processing industries: An experiment on the valorization potential under CO2 and N2 atmospheres through microwave-induced pyrolysis
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