Base‐Promoted Reaction of Phenols with Spirocylic λ3‐Iodanes: Access to Both 2‐Iodovinyl Aryl Ethers and Diaryl Ethers

Herein, an efficient method for vinyl or aryl C(sp2)−O bond forming to construct both the (Z)‐2‐iodovinyl aryl ethers and diaryl ethers under metal‐, photocatalyst‐ and light‐free condition in one‐step, has been developed. To generate the two desired products, we proposed a SNAr2 reaction of phenol...

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Veröffentlicht in:	European journal of organic chemistry 2022-07, Vol.2022 (26), p.n/a
Hauptverfasser:	He, Shun‐Dong, Guo, Xiao‐Qiang, Li, Jun, Zhang, Yu‐Cheng, Chen, Lian‐Mei, Kang, Tai‐Ran
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Aromatic compounds Diaryl ethers Ethynyl-benziodoxolones Hypervalent iodine reagents Phenols Synthetic methods Vinyl aryl ethers
Online-Zugang:	Volltext
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