NaV(SO4)2/C, Na3V(SO4)3/C, and K2VO(SO4)2/C: three Li-free vanadium sulfate cathode materials for lithium-ion batteries
In this study, three Li-free polyanion vanadium sulfates containing Na/K alkali metals were successfully synthesized by a facile solid-state method at moderate temperature. To improve the electronic conductivity, these three vanadium sulfate samples were mixed with carbon black SuperP by ball millin...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2022-08, Vol.26 (8), p.1627-1636 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Ge, Xiuli Chen, Yongkai Liu, Shanshan Yang, Xin Feng, Kai |
| description | In this study, three Li-free polyanion vanadium sulfates containing Na/K alkali metals were successfully synthesized by a facile solid-state method at moderate temperature. To improve the electronic conductivity, these three vanadium sulfate samples were mixed with carbon black SuperP by ball milling. These composites were characterized using XRD, IR, Raman, UV–vis diffuse reflectance, and FESEM. Moreover, the NaV(SO
4
)
2
/C, Na
3
V(SO
4
)
3
/C, and K
2
VO(SO
4
)
2
/C composites were investigated as cathode materials for lithium-ion batteries (LIBs) for the first time. There are continuous ion transport channels in all three compounds, which tolerate reversible insertion-extraction of lithium ions. Benefiting from the two-electronic reaction of V
4+
/V
3+
and V
3+
/V
2+
redox pairs, Na
3
V(SO
4
)
3
/C and K
2
VO(SO
4
)
2
/C deliver discharge specific capacities of 120 mAh⋅g
−1
, while NaV(SO
4
)
2
/C displays a higher specific capacity of 200 mAh⋅g
−1
in the first cycle. However, their rate performance and cyclic stability are poor, which may be attributed to the solubility of sulfate in electrolyte. |
| doi_str_mv | 10.1007/s10008-022-05203-0 |
| format | Article |
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4
)
2
/C, Na
3
V(SO
4
)
3
/C, and K
2
VO(SO
4
)
2
/C composites were investigated as cathode materials for lithium-ion batteries (LIBs) for the first time. There are continuous ion transport channels in all three compounds, which tolerate reversible insertion-extraction of lithium ions. Benefiting from the two-electronic reaction of V
4+
/V
3+
and V
3+
/V
2+
redox pairs, Na
3
V(SO
4
)
3
/C and K
2
VO(SO
4
)
2
/C deliver discharge specific capacities of 120 mAh⋅g
−1
, while NaV(SO
4
)
2
/C displays a higher specific capacity of 200 mAh⋅g
−1
in the first cycle. However, their rate performance and cyclic stability are poor, which may be attributed to the solubility of sulfate in electrolyte.</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-022-05203-0</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Alkali metals ; Analytical Chemistry ; Ball milling ; Carbon black ; Cathodes ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Composite materials ; Condensed Matter Physics ; Electrochemistry ; Electrode materials ; Energy Storage ; Ion transport ; Lithium-ion batteries ; Original Paper ; Physical Chemistry ; Polyelectrolytes ; Rechargeable batteries ; Vanadium</subject><ispartof>Journal of solid state electrochemistry, 2022-08, Vol.26 (8), p.1627-1636</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-416ce92bd7107012f46bb0d346f7aa0d332cffe786d721832a0a4fbcbcfed3213</citedby><cites>FETCH-LOGICAL-c249t-416ce92bd7107012f46bb0d346f7aa0d332cffe786d721832a0a4fbcbcfed3213</cites><orcidid>0000-0002-4627-5515</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10008-022-05203-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10008-022-05203-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27931,27932,41495,42564,51326</link.rule.ids></links><search><creatorcontrib>Ge, Xiuli</creatorcontrib><creatorcontrib>Chen, Yongkai</creatorcontrib><creatorcontrib>Liu, Shanshan</creatorcontrib><creatorcontrib>Yang, Xin</creatorcontrib><creatorcontrib>Feng, Kai</creatorcontrib><title>NaV(SO4)2/C, Na3V(SO4)3/C, and K2VO(SO4)2/C: three Li-free vanadium sulfate cathode materials for lithium-ion batteries</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>In this study, three Li-free polyanion vanadium sulfates containing Na/K alkali metals were successfully synthesized by a facile solid-state method at moderate temperature. To improve the electronic conductivity, these three vanadium sulfate samples were mixed with carbon black SuperP by ball milling. These composites were characterized using XRD, IR, Raman, UV–vis diffuse reflectance, and FESEM. Moreover, the NaV(SO
4
)
2
/C, Na
3
V(SO
4
)
3
/C, and K
2
VO(SO
4
)
2
/C composites were investigated as cathode materials for lithium-ion batteries (LIBs) for the first time. There are continuous ion transport channels in all three compounds, which tolerate reversible insertion-extraction of lithium ions. Benefiting from the two-electronic reaction of V
4+
/V
3+
and V
3+
/V
2+
redox pairs, Na
3
V(SO
4
)
3
/C and K
2
VO(SO
4
)
2
/C deliver discharge specific capacities of 120 mAh⋅g
−1
, while NaV(SO
4
)
2
/C displays a higher specific capacity of 200 mAh⋅g
−1
in the first cycle. However, their rate performance and cyclic stability are poor, which may be attributed to the solubility of sulfate in electrolyte.</description><subject>Alkali metals</subject><subject>Analytical Chemistry</subject><subject>Ball milling</subject><subject>Carbon black</subject><subject>Cathodes</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composite materials</subject><subject>Condensed Matter Physics</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Energy Storage</subject><subject>Ion transport</subject><subject>Lithium-ion batteries</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polyelectrolytes</subject><subject>Rechargeable batteries</subject><subject>Vanadium</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhYMoWKt_wFXAjYKxN48mqTspvrC0C7XbkJlJ7JR2piYziv_etKO4c5N7Dvc7N3AQOqVwRQHUIKYXNAHGCAwZcAJ7qEcFT0JJvb_TjGih9SE6inEJQJWk0EOfUzs_f56JCzYYX-Kp5Z3jW2erAj-x-ex3f42bRXAOT0rit_PDVrYo2zWO7crbxuHcNou6cHidTCjtKmJfB7wqm0WiSFlXOLPNduXiMTrwCXAnP7OPXu9uX8YPZDK7fxzfTEjOxKghgsrcjVhWKAoKKPNCZhkUXEivrE2Cs9x7p7QsFKOaMwtW-CzPcu8Kzijvo7Pu7ibU762LjVnWbajSl4ZJrYeKSjlMFOuoPNQxBufNJpRrG74MBbMt2HQFm1Sw2RVsIIV4F4oJrt5c-Dv9T-obhjh6Uw</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>Ge, Xiuli</creator><creator>Chen, Yongkai</creator><creator>Liu, Shanshan</creator><creator>Yang, Xin</creator><creator>Feng, Kai</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-4627-5515</orcidid></search><sort><creationdate>20220801</creationdate><title>NaV(SO4)2/C, Na3V(SO4)3/C, and K2VO(SO4)2/C: three Li-free vanadium sulfate cathode materials for lithium-ion batteries</title><author>Ge, Xiuli ; Chen, Yongkai ; Liu, Shanshan ; Yang, Xin ; Feng, Kai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-416ce92bd7107012f46bb0d346f7aa0d332cffe786d721832a0a4fbcbcfed3213</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Alkali metals</topic><topic>Analytical Chemistry</topic><topic>Ball milling</topic><topic>Carbon black</topic><topic>Cathodes</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composite materials</topic><topic>Condensed Matter Physics</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Energy Storage</topic><topic>Ion transport</topic><topic>Lithium-ion batteries</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polyelectrolytes</topic><topic>Rechargeable batteries</topic><topic>Vanadium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ge, Xiuli</creatorcontrib><creatorcontrib>Chen, Yongkai</creatorcontrib><creatorcontrib>Liu, Shanshan</creatorcontrib><creatorcontrib>Yang, Xin</creatorcontrib><creatorcontrib>Feng, Kai</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ge, Xiuli</au><au>Chen, Yongkai</au><au>Liu, Shanshan</au><au>Yang, Xin</au><au>Feng, Kai</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>NaV(SO4)2/C, Na3V(SO4)3/C, and K2VO(SO4)2/C: three Li-free vanadium sulfate cathode materials for lithium-ion batteries</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2022-08-01</date><risdate>2022</risdate><volume>26</volume><issue>8</issue><spage>1627</spage><epage>1636</epage><pages>1627-1636</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>In this study, three Li-free polyanion vanadium sulfates containing Na/K alkali metals were successfully synthesized by a facile solid-state method at moderate temperature. To improve the electronic conductivity, these three vanadium sulfate samples were mixed with carbon black SuperP by ball milling. These composites were characterized using XRD, IR, Raman, UV–vis diffuse reflectance, and FESEM. Moreover, the NaV(SO
4
)
2
/C, Na
3
V(SO
4
)
3
/C, and K
2
VO(SO
4
)
2
/C composites were investigated as cathode materials for lithium-ion batteries (LIBs) for the first time. There are continuous ion transport channels in all three compounds, which tolerate reversible insertion-extraction of lithium ions. Benefiting from the two-electronic reaction of V
4+
/V
3+
and V
3+
/V
2+
redox pairs, Na
3
V(SO
4
)
3
/C and K
2
VO(SO
4
)
2
/C deliver discharge specific capacities of 120 mAh⋅g
−1
, while NaV(SO
4
)
2
/C displays a higher specific capacity of 200 mAh⋅g
−1
in the first cycle. However, their rate performance and cyclic stability are poor, which may be attributed to the solubility of sulfate in electrolyte.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-022-05203-0</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-4627-5515</orcidid></addata></record> |
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| identifier | ISSN: 1432-8488 |
| ispartof | Journal of solid state electrochemistry, 2022-08, Vol.26 (8), p.1627-1636 |
| issn | 1432-8488 1433-0768 |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Alkali metals Analytical Chemistry Ball milling Carbon black Cathodes Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Composite materials Condensed Matter Physics Electrochemistry Electrode materials Energy Storage Ion transport Lithium-ion batteries Original Paper Physical Chemistry Polyelectrolytes Rechargeable batteries Vanadium |
| title | NaV(SO4)2/C, Na3V(SO4)3/C, and K2VO(SO4)2/C: three Li-free vanadium sulfate cathode materials for lithium-ion batteries |
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