Yolk-shell Co-glycerate@Fe-Co Prussian blue analogue spheres for high-performance lithium-ion batteries
•Yolk-shell Co-glycerate@Fe-Co Prussian blue analogue spheres.•Co-glycerate reversibly stores Li-ions.•High specific capacity and rate performance, stable cycling performance. Yolk-shell spheres of Co-glycerate@Fe-Co Prussian blue analogue are synthesized by the etching reaction of water towards Co-...
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| Veröffentlicht in: | Materials letters 2022-08, Vol.320, p.132358, Article 132358 |
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| container_title | Materials letters |
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| creator | Chen, Y.X. Yuan, Y.F. Mo, C.L. Du, P.F. Guo, S.Y. |
| description | •Yolk-shell Co-glycerate@Fe-Co Prussian blue analogue spheres.•Co-glycerate reversibly stores Li-ions.•High specific capacity and rate performance, stable cycling performance.
Yolk-shell spheres of Co-glycerate@Fe-Co Prussian blue analogue are synthesized by the etching reaction of water towards Co-glycerate spheres and coordination reaction of K3[Fe(CN)6] and Co ions. Co-glycerate@Fe-Co Prussian blue analogue exhibits high reversible capacity and good cycling performance, as anode material of lithium-ion batteries. The discharge capacity can stabilize at about 1100 mAh g−1 at 0.2 A g−1 and 600 mAh g−1 at 1 A g−1. Even at 5 A g−1, discharge capacity still stabilizes at about 820 mAh g−1. The excellent lithium storage performance indicates that it is a promising anode material for lithium-ion batteries. |
| doi_str_mv | 10.1016/j.matlet.2022.132358 |
| format | Article |
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Yolk-shell spheres of Co-glycerate@Fe-Co Prussian blue analogue are synthesized by the etching reaction of water towards Co-glycerate spheres and coordination reaction of K3[Fe(CN)6] and Co ions. Co-glycerate@Fe-Co Prussian blue analogue exhibits high reversible capacity and good cycling performance, as anode material of lithium-ion batteries. The discharge capacity can stabilize at about 1100 mAh g−1 at 0.2 A g−1 and 600 mAh g−1 at 1 A g−1. Even at 5 A g−1, discharge capacity still stabilizes at about 820 mAh g−1. The excellent lithium storage performance indicates that it is a promising anode material for lithium-ion batteries.</description><identifier>ISSN: 0167-577X</identifier><identifier>EISSN: 1873-4979</identifier><identifier>DOI: 10.1016/j.matlet.2022.132358</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Anodes ; Co glycerate ; Cobalt ; Composite materials ; Discharge ; Electrode materials ; Energy storage and conversion ; Iron ; Lithium-ion batteries ; Materials science ; Pigments ; Potassium ferricyanide ; Rechargeable batteries</subject><ispartof>Materials letters, 2022-08, Vol.320, p.132358, Article 132358</ispartof><rights>2022 Elsevier B.V.</rights><rights>Copyright Elsevier BV Aug 1, 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c334t-170fc2c65a1e91e23c59c13507744c01520247bbdef7ffa56662b66e717963a3</citedby><cites>FETCH-LOGICAL-c334t-170fc2c65a1e91e23c59c13507744c01520247bbdef7ffa56662b66e717963a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0167577X2200711X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Chen, Y.X.</creatorcontrib><creatorcontrib>Yuan, Y.F.</creatorcontrib><creatorcontrib>Mo, C.L.</creatorcontrib><creatorcontrib>Du, P.F.</creatorcontrib><creatorcontrib>Guo, S.Y.</creatorcontrib><title>Yolk-shell Co-glycerate@Fe-Co Prussian blue analogue spheres for high-performance lithium-ion batteries</title><title>Materials letters</title><description>•Yolk-shell Co-glycerate@Fe-Co Prussian blue analogue spheres.•Co-glycerate reversibly stores Li-ions.•High specific capacity and rate performance, stable cycling performance.
Yolk-shell spheres of Co-glycerate@Fe-Co Prussian blue analogue are synthesized by the etching reaction of water towards Co-glycerate spheres and coordination reaction of K3[Fe(CN)6] and Co ions. Co-glycerate@Fe-Co Prussian blue analogue exhibits high reversible capacity and good cycling performance, as anode material of lithium-ion batteries. The discharge capacity can stabilize at about 1100 mAh g−1 at 0.2 A g−1 and 600 mAh g−1 at 1 A g−1. Even at 5 A g−1, discharge capacity still stabilizes at about 820 mAh g−1. The excellent lithium storage performance indicates that it is a promising anode material for lithium-ion batteries.</description><subject>Anodes</subject><subject>Co glycerate</subject><subject>Cobalt</subject><subject>Composite materials</subject><subject>Discharge</subject><subject>Electrode materials</subject><subject>Energy storage and conversion</subject><subject>Iron</subject><subject>Lithium-ion batteries</subject><subject>Materials science</subject><subject>Pigments</subject><subject>Potassium ferricyanide</subject><subject>Rechargeable batteries</subject><issn>0167-577X</issn><issn>1873-4979</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kD9PwzAUxC0EEuXPN2CIxOxix4mdLAhUUUCqBEMHmCzHfUkc3LrYDlK_Pa7CzPRuuDu9-yF0Q8mcEsrvhvlWRQtxnpM8n1OWs7I6QTNaCYaLWtSnaJZsApdCfJyjixAGQkhRk2KGuk9nv3Dowdps4XBnDxq8ivCwBLxw2bsfQzBqlzV2hEztlHVdEmHfg4eQtc5nvel6vAef9FbtNGTWxN6MW2xciqkYwRsIV-isVTbA9d-9ROvl03rxgldvz6-LxxXWjBURU0FanWteKgo1hZzpstaUlUSIotCElmlhIZpmA61oW1VyzvOGcxBU1Jwpdolup9q9d98jhCgHN_r0dpA5r0TFGK9IchWTS3sXgodW7r3ZKn-QlMgjUTnIiag8EpUT0RS7n2KQBvwY8DJoA2nyxnjQUW6c-b_gF5PpgWI</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>Chen, Y.X.</creator><creator>Yuan, Y.F.</creator><creator>Mo, C.L.</creator><creator>Du, P.F.</creator><creator>Guo, S.Y.</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20220801</creationdate><title>Yolk-shell Co-glycerate@Fe-Co Prussian blue analogue spheres for high-performance lithium-ion batteries</title><author>Chen, Y.X. ; Yuan, Y.F. ; Mo, C.L. ; Du, P.F. ; Guo, S.Y.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c334t-170fc2c65a1e91e23c59c13507744c01520247bbdef7ffa56662b66e717963a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Anodes</topic><topic>Co glycerate</topic><topic>Cobalt</topic><topic>Composite materials</topic><topic>Discharge</topic><topic>Electrode materials</topic><topic>Energy storage and conversion</topic><topic>Iron</topic><topic>Lithium-ion batteries</topic><topic>Materials science</topic><topic>Pigments</topic><topic>Potassium ferricyanide</topic><topic>Rechargeable batteries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Y.X.</creatorcontrib><creatorcontrib>Yuan, Y.F.</creatorcontrib><creatorcontrib>Mo, C.L.</creatorcontrib><creatorcontrib>Du, P.F.</creatorcontrib><creatorcontrib>Guo, S.Y.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Materials letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Y.X.</au><au>Yuan, Y.F.</au><au>Mo, C.L.</au><au>Du, P.F.</au><au>Guo, S.Y.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Yolk-shell Co-glycerate@Fe-Co Prussian blue analogue spheres for high-performance lithium-ion batteries</atitle><jtitle>Materials letters</jtitle><date>2022-08-01</date><risdate>2022</risdate><volume>320</volume><spage>132358</spage><pages>132358-</pages><artnum>132358</artnum><issn>0167-577X</issn><eissn>1873-4979</eissn><abstract>•Yolk-shell Co-glycerate@Fe-Co Prussian blue analogue spheres.•Co-glycerate reversibly stores Li-ions.•High specific capacity and rate performance, stable cycling performance.
Yolk-shell spheres of Co-glycerate@Fe-Co Prussian blue analogue are synthesized by the etching reaction of water towards Co-glycerate spheres and coordination reaction of K3[Fe(CN)6] and Co ions. Co-glycerate@Fe-Co Prussian blue analogue exhibits high reversible capacity and good cycling performance, as anode material of lithium-ion batteries. The discharge capacity can stabilize at about 1100 mAh g−1 at 0.2 A g−1 and 600 mAh g−1 at 1 A g−1. Even at 5 A g−1, discharge capacity still stabilizes at about 820 mAh g−1. The excellent lithium storage performance indicates that it is a promising anode material for lithium-ion batteries.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.matlet.2022.132358</doi></addata></record> |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Anodes Co glycerate Cobalt Composite materials Discharge Electrode materials Energy storage and conversion Iron Lithium-ion batteries Materials science Pigments Potassium ferricyanide Rechargeable batteries |
| title | Yolk-shell Co-glycerate@Fe-Co Prussian blue analogue spheres for high-performance lithium-ion batteries |
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