Electronic Structure of Carbon Dioxide in Sylgard-184 Evaluated by Using X-ray Emission Spectroscopy
To investigate the interactions between carbon dioxide (CO2) and Sylgard-184, which is mainly composed of polydimethylsiloxane and dimethylvinylated and trimethylated silica, the electronic structure of CO2 sorbed in Sylgard-184 was evaluated by using X-ray emission spectroscopy. The spectrum corres...
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| Veröffentlicht in: | Chemistry letters 2022-06, Vol.51 (6), p.650-653 |
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| container_issue | 6 |
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| container_title | Chemistry letters |
| container_volume | 51 |
| creator | Matsuno, Ryosuke Nutthon, Yokajaksusri Miyano, Akira Ninomiya, Kakeru Nishibori, Maiko Kiuchi, Hisao Fujikawa, Shigenori Harada, Yoshihisa Takahara, Atsushi |
| description | To investigate the interactions between carbon dioxide (CO2) and Sylgard-184, which is mainly composed of polydimethylsiloxane and dimethylvinylated and trimethylated silica, the electronic structure of CO2 sorbed in Sylgard-184 was evaluated by using X-ray emission spectroscopy. The spectrum corresponding to the highest occupied molecular orbital of CO2 in the membrane showed a shoulder on the high energy side compared with that of CO2 gas, indicating that the symmetry of the electronic structure was disturbed owing to the interaction with Sylgard components. |
| doi_str_mv | 10.1246/cl.220113 |
| format | Article |
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| ispartof | Chemistry letters, 2022-06, Vol.51 (6), p.650-653 |
| issn | 0366-7022 1348-0715 |
| language | eng |
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| source | Oxford University Press Journals All Titles (1996-Current) |
| subjects | Carbon dioxide Electronic structure Emission analysis Emission spectroscopy Molecular orbitals Polydimethylsiloxane X-ray spectroscopy |
| title | Electronic Structure of Carbon Dioxide in Sylgard-184 Evaluated by Using X-ray Emission Spectroscopy |
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