SPIN CROSSOVER AND TEMPERATURE SENSITIVITY OF PARAMAGNETIC NMR CHEMICAL SHIFTS IN AN AQUEOUS SOLUTION OF THE IRON(II) NAPHTHALENESULFONATE COMPLEX WITH TRIS(PYRAZOL-1-YL)METHANE [Fe(HC(Pz)3)2](C10H7SO3)2

Paramagnetic chemical shifts in the iron(II) tris(pyrazole-1-yl)methane [Fe(HC(Pz) 3 ) 2 ](C 10 H 7 SO 3 ) 2 complex exhibiting spin crossover were studied by 1 H NMR at different temperatures. The studied complex demonstrates a relatively sharp temperature change of NMR chemical shifts due to spin...

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Veröffentlicht in:Journal of structural chemistry 2022, Vol.63 (6), p.923-929
Hauptverfasser: Zapolotsky, E. N., Babailov, S. P., Chuykov, I. P., Kokovkin, V. V., Shakirova, O. G.
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Sprache:eng
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