AN EXPLORATION OF STRUCTURALLY CHARACTERIZED HETERO-TRINUCLEAR [Cu(II)2Ca(II)] FLEXIBLE-BIS(SALAMO)-TYPE COMPLEX
A new bis(salamo)-type ligand has been designed and synthesized, and its hetero-trinuclear [Cu(II) 2 Ca(II)] complex has been successfully prepared. It is characterized by elemental analyses, IR spectra, UV-Vis absorption spectra and X-ray single crystal diffraction. Meanwhile, Hirshfeld surfaces an...
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| Veröffentlicht in: | Journal of structural chemistry 2022-06, Vol.63 (6), p.854-867 |
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| creator | Yue, Y. -N. Zhang, T. La, Y. -T. Dong, W. -K. |
| description | A new bis(salamo)-type ligand has been designed and synthesized, and its hetero-trinuclear [Cu(II)
2
Ca(II)] complex has been successfully prepared. It is characterized by elemental analyses, IR spectra, UV-Vis absorption spectra and X-ray single crystal diffraction. Meanwhile, Hirshfeld surfaces and fluorescence properties were investigated. The hetero-trinuclear [Cu(II)
2
Ca(II)] complex was obtained by 2 equiv. Cu(NO
3
)
2
·3H
2
O and 1 equiv. Ca(OAc)
2
·2H
2
O with 1 equiv. H
4
L. Obviously, there is the ligand, metal Cu(II) and Ca(II) ratio of 1:2:1 which formed the hetero-trinuclear [Cu(II)
2
Ca(II)] complex. X-ray diffraction result showed that Cu(II) and Ca(II) atoms in the crystal are geometric polyhedrons with different shapes. Both Cu(II) atoms are located respectively in N
2
O
2
cavities of the completely deprotonated ligand (L)
4–
unit. Cu(II) and Ca(II) atoms are bridged by nitrate groups, so that the two Cu(II) (Cu1 and Cu2) atoms have slightly distorted square pyramid geometries. In addition, Ca(II) atom is located in a O
6
cavity of the ligand (L)
4–
unit and possesses square antiprism with eight coordination. |
| doi_str_mv | 10.1134/S0022476622060026 |
| format | Article |
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2
Ca(II)] complex has been successfully prepared. It is characterized by elemental analyses, IR spectra, UV-Vis absorption spectra and X-ray single crystal diffraction. Meanwhile, Hirshfeld surfaces and fluorescence properties were investigated. The hetero-trinuclear [Cu(II)
2
Ca(II)] complex was obtained by 2 equiv. Cu(NO
3
)
2
·3H
2
O and 1 equiv. Ca(OAc)
2
·2H
2
O with 1 equiv. H
4
L. Obviously, there is the ligand, metal Cu(II) and Ca(II) ratio of 1:2:1 which formed the hetero-trinuclear [Cu(II)
2
Ca(II)] complex. X-ray diffraction result showed that Cu(II) and Ca(II) atoms in the crystal are geometric polyhedrons with different shapes. Both Cu(II) atoms are located respectively in N
2
O
2
cavities of the completely deprotonated ligand (L)
4–
unit. Cu(II) and Ca(II) atoms are bridged by nitrate groups, so that the two Cu(II) (Cu1 and Cu2) atoms have slightly distorted square pyramid geometries. In addition, Ca(II) atom is located in a O
6
cavity of the ligand (L)
4–
unit and possesses square antiprism with eight coordination.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476622060026</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Absorption spectra ; Atomic ; Atomic/Molecular Structure and Spectra ; Calcium ; Chemistry ; Chemistry and Materials Science ; Copper ; Crystals ; Holes ; Infrared spectroscopy ; Inorganic Chemistry ; Ligands ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Single crystals ; Solid State Physics</subject><ispartof>Journal of structural chemistry, 2022-06, Vol.63 (6), p.854-867</ispartof><rights>Pleiades Publishing, Ltd. 2022</rights><rights>Pleiades Publishing, Ltd. 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c246t-bc513d8812a49be157bb81ff514ef8d656e97e427b275b7ae9c68a2ffed1d91e3</citedby><cites>FETCH-LOGICAL-c246t-bc513d8812a49be157bb81ff514ef8d656e97e427b275b7ae9c68a2ffed1d91e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476622060026$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476622060026$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Yue, Y. -N.</creatorcontrib><creatorcontrib>Zhang, T.</creatorcontrib><creatorcontrib>La, Y. -T.</creatorcontrib><creatorcontrib>Dong, W. -K.</creatorcontrib><title>AN EXPLORATION OF STRUCTURALLY CHARACTERIZED HETERO-TRINUCLEAR [Cu(II)2Ca(II)] FLEXIBLE-BIS(SALAMO)-TYPE COMPLEX</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>A new bis(salamo)-type ligand has been designed and synthesized, and its hetero-trinuclear [Cu(II)
2
Ca(II)] complex has been successfully prepared. It is characterized by elemental analyses, IR spectra, UV-Vis absorption spectra and X-ray single crystal diffraction. Meanwhile, Hirshfeld surfaces and fluorescence properties were investigated. The hetero-trinuclear [Cu(II)
2
Ca(II)] complex was obtained by 2 equiv. Cu(NO
3
)
2
·3H
2
O and 1 equiv. Ca(OAc)
2
·2H
2
O with 1 equiv. H
4
L. Obviously, there is the ligand, metal Cu(II) and Ca(II) ratio of 1:2:1 which formed the hetero-trinuclear [Cu(II)
2
Ca(II)] complex. X-ray diffraction result showed that Cu(II) and Ca(II) atoms in the crystal are geometric polyhedrons with different shapes. Both Cu(II) atoms are located respectively in N
2
O
2
cavities of the completely deprotonated ligand (L)
4–
unit. Cu(II) and Ca(II) atoms are bridged by nitrate groups, so that the two Cu(II) (Cu1 and Cu2) atoms have slightly distorted square pyramid geometries. In addition, Ca(II) atom is located in a O
6
cavity of the ligand (L)
4–
unit and possesses square antiprism with eight coordination.</description><subject>Absorption spectra</subject><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Calcium</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copper</subject><subject>Crystals</subject><subject>Holes</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Single crystals</subject><subject>Solid State Physics</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1UFtLwzAYDaLgnP4A3wK-zIdqkrZJ-pjFzBWydfQCmyKll1Qcus12e_DfmzLBB_HpHDiXj-8AcI3RHcaud58gRIjHKCUEUcvpCRhgn7kOZyw4BYNednr9HFx03RohFPCADsBOzKFaLnQUizSM5jCawCSNM5lmsdB6BeVUxEKmKg6f1AOcKssiJ43DeSa1EjF8lodRGN4SWfTwAidaLcOxVs44TEaJ0GIW3TrpaqGgjGYLK16Cs6Z478zVDw5BNlGpnDo6egyl0E5FPLp3ysrHbs05JoUXlMa-UpYcN42PPdPwmvrUBMx4hJWE-SUrTFBRXpCmMTWuA2zcIbg59u7a7efBdPt8vT20G3syJ5QTjgPk-9aFj66q3XZda5p81759FO1XjlHeD5v_GdZmyDHTWe_m1bS_zf-HvgG88nCm</recordid><startdate>20220601</startdate><enddate>20220601</enddate><creator>Yue, Y. -N.</creator><creator>Zhang, T.</creator><creator>La, Y. -T.</creator><creator>Dong, W. -K.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220601</creationdate><title>AN EXPLORATION OF STRUCTURALLY CHARACTERIZED HETERO-TRINUCLEAR [Cu(II)2Ca(II)] FLEXIBLE-BIS(SALAMO)-TYPE COMPLEX</title><author>Yue, Y. -N. ; Zhang, T. ; La, Y. -T. ; Dong, W. -K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c246t-bc513d8812a49be157bb81ff514ef8d656e97e427b275b7ae9c68a2ffed1d91e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Absorption spectra</topic><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Calcium</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copper</topic><topic>Crystals</topic><topic>Holes</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Single crystals</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yue, Y. -N.</creatorcontrib><creatorcontrib>Zhang, T.</creatorcontrib><creatorcontrib>La, Y. -T.</creatorcontrib><creatorcontrib>Dong, W. -K.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yue, Y. -N.</au><au>Zhang, T.</au><au>La, Y. -T.</au><au>Dong, W. -K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>AN EXPLORATION OF STRUCTURALLY CHARACTERIZED HETERO-TRINUCLEAR [Cu(II)2Ca(II)] FLEXIBLE-BIS(SALAMO)-TYPE COMPLEX</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2022-06-01</date><risdate>2022</risdate><volume>63</volume><issue>6</issue><spage>854</spage><epage>867</epage><pages>854-867</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>A new bis(salamo)-type ligand has been designed and synthesized, and its hetero-trinuclear [Cu(II)
2
Ca(II)] complex has been successfully prepared. It is characterized by elemental analyses, IR spectra, UV-Vis absorption spectra and X-ray single crystal diffraction. Meanwhile, Hirshfeld surfaces and fluorescence properties were investigated. The hetero-trinuclear [Cu(II)
2
Ca(II)] complex was obtained by 2 equiv. Cu(NO
3
)
2
·3H
2
O and 1 equiv. Ca(OAc)
2
·2H
2
O with 1 equiv. H
4
L. Obviously, there is the ligand, metal Cu(II) and Ca(II) ratio of 1:2:1 which formed the hetero-trinuclear [Cu(II)
2
Ca(II)] complex. X-ray diffraction result showed that Cu(II) and Ca(II) atoms in the crystal are geometric polyhedrons with different shapes. Both Cu(II) atoms are located respectively in N
2
O
2
cavities of the completely deprotonated ligand (L)
4–
unit. Cu(II) and Ca(II) atoms are bridged by nitrate groups, so that the two Cu(II) (Cu1 and Cu2) atoms have slightly distorted square pyramid geometries. In addition, Ca(II) atom is located in a O
6
cavity of the ligand (L)
4–
unit and possesses square antiprism with eight coordination.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476622060026</doi><tpages>14</tpages></addata></record> |
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| ispartof | Journal of structural chemistry, 2022-06, Vol.63 (6), p.854-867 |
| issn | 0022-4766 1573-8779 |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Absorption spectra Atomic Atomic/Molecular Structure and Spectra Calcium Chemistry Chemistry and Materials Science Copper Crystals Holes Infrared spectroscopy Inorganic Chemistry Ligands Molecular Optical and Plasma Physics Physical Chemistry Single crystals Solid State Physics |
| title | AN EXPLORATION OF STRUCTURALLY CHARACTERIZED HETERO-TRINUCLEAR [Cu(II)2Ca(II)] FLEXIBLE-BIS(SALAMO)-TYPE COMPLEX |
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