Oxidative versus basic asynchronous hydrogen atom transfer reactions of Mn( iii )-hydroxo and Mn( iii )-aqua complexes

Hydrogen atom transfer (HAT) reactions of metal–oxygen intermediates such as metal-oxo, -hydroxo and -superoxo species have so far been studied extensively. However, HAT reactions of metal-aqua complexes are yet to be studied in comparison with those of the corresponding metal-hydroxo complexes. In...

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Veröffentlicht in:	Inorganic chemistry frontiers 2022-06, Vol.9 (13), p.3233-3243
Hauptverfasser:	Zhang, Jisheng, Lee, Yong-Min, Seo, Mi Sook, Kim, Youngsuk, Lee, Eunsung, Fukuzumi, Shunichi, Nam, Wonwoo
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystal structure Electron transfer Electrons Hydrogen atoms Inorganic chemistry Nitrogen dioxide Protons Rate constants Substitutes Triflic acid
Online-Zugang:	Volltext
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