Supramolecular Arrangement Built from Zinc and Cadmium Complexes with 4′-(4-Substituted)-2,2′:6′,2″-Terpyridine: Crystallographic Investigation, Luminescence and Thermal Properties
The reaction of Zn(NO 3 ) 2 ⋅6H 2 O with tpyOH or ftpy in the presence of KSCN affords the new zinc(II) complexes [Zn(tpyOH)(NCS) 2 ] ( 1 ) and [Zn(ftpy)(NCS) 2 ] ( 2 ) while two isostructural compound of [Zn(tpyOH)(NCS) 2 ].DMSO ( 1 .DMSO) and [Zn(ftpy)(NCS) 2 ].DMSO ( 2 .DMSO) were obtained during...
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| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2022, Vol.32 (6), p.2279-2297 |
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| creator | Momeni, Badri Z. Kazemzade Anari, Sanaz Janczak, Jan Fallahpour, Reza |
| description | The reaction of Zn(NO
3
)
2
⋅6H
2
O with tpyOH or ftpy in the presence of KSCN affords the new zinc(II) complexes [Zn(tpyOH)(NCS)
2
] (
1
) and [Zn(ftpy)(NCS)
2
] (
2
) while two isostructural compound of [Zn(tpyOH)(NCS)
2
].DMSO (
1
.DMSO) and [Zn(ftpy)(NCS)
2
].DMSO (
2
.DMSO) were obtained during the crystallization in DMSO, respectively. Structurally,
1
.DMSO and
2
.DMSO reveal that the Zn(II) is penta-coordinated by two nitrogen atoms of NCS
−
and three nitrogen atoms from tpyOH or ftpy in a highly distorted square pyramidal geometry. Interestingly,
1
.DMSO contains four crystallographically independent molecules, each of them is hydrogen-bonded to DMSO and adopts supramolecular structure constructed by OH…O hydrogen bonds. On the other hand, the reaction of CdCl
2
with ftpy has been resulted in the formation of the new distorted square pyramid complex [Cd(ftpy)Cl
2
] (
3
). The crystal structure of
3
is stabilized by the extensive hydrogen bonds of C–H…Cl between H atoms of ftpy and the Cl atoms. Crystal structures of
2
.DMSO and
3
reveal that these porous materials have voids, occupied by the solvents. The volume of voids in
2
.DMSO and
3
are 542 and 555 Å
3
, respectively. Hirshfeld surface analysis were used to identify and quantify the inter-molecular interactions such as H-bonds and π-stackings. Thermogravimetric and differential thermal analysis showed that three compounds possess great thermal stabilities, especially for
2
which is stable up to 373 °C. The luminescent properties of compounds were assigned to π–π* transitions. |
| doi_str_mv | 10.1007/s10904-022-02299-9 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2679268618</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2679268618</sourcerecordid><originalsourceid>FETCH-LOGICAL-c249t-40ce60b3ae2c26ac3baed0614e1bdd1bc2cefec0da817b729902e37da8422b223</originalsourceid><addsrcrecordid>eNp9Uc1u1DAQjhBIlMILcLLEBaQabMebbHorUYFKK4HU5cLFcpzZXVexHcY2sLc-E1x5Gp4EbxfBjcP86vtmRvNV1VPOXnLG2leRs45JyoQ4WNfR7l51whetpFwu-P2_uawfVo9ivGGsXrIFP6l-XucZtQsTmDxpJBeI2m_BgU_kdbZTIhsMjnyy3hDtR9Lr0dnsSB_cPME3iOSrTTsif91-p88lvc5DTDblBOMLKs5EaZ83xR2yH3QNOO_RjtbDOelxH5OeprBFPe-sIVf-CxTyVicb_BlZZVdw0YA3cLd6vQN0eiIfMMyAyUJ8XD3Y6CnCkz_xtPr45nLdv6Or92-v-osVNUJ2iUpmoGFDrUEY0WhTDxpG1nAJfBhHPhhhYAOGjXrJ26Et72MC6raUUohBiPq0enacO2P4nMuR6iZk9GWlEk3biWbZ8GVBiSPKYIgRYaNmtE7jXnGmDiqpo0qqKKTuVFJdIdVHUizg8nj8N_o_rN_vFJzf</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2679268618</pqid></control><display><type>article</type><title>Supramolecular Arrangement Built from Zinc and Cadmium Complexes with 4′-(4-Substituted)-2,2′:6′,2″-Terpyridine: Crystallographic Investigation, Luminescence and Thermal Properties</title><source>SpringerNature Journals</source><creator>Momeni, Badri Z. ; Kazemzade Anari, Sanaz ; Janczak, Jan ; Fallahpour, Reza</creator><creatorcontrib>Momeni, Badri Z. ; Kazemzade Anari, Sanaz ; Janczak, Jan ; Fallahpour, Reza</creatorcontrib><description>The reaction of Zn(NO
3
)
2
⋅6H
2
O with tpyOH or ftpy in the presence of KSCN affords the new zinc(II) complexes [Zn(tpyOH)(NCS)
2
] (
1
) and [Zn(ftpy)(NCS)
2
] (
2
) while two isostructural compound of [Zn(tpyOH)(NCS)
2
].DMSO (
1
.DMSO) and [Zn(ftpy)(NCS)
2
].DMSO (
2
.DMSO) were obtained during the crystallization in DMSO, respectively. Structurally,
1
.DMSO and
2
.DMSO reveal that the Zn(II) is penta-coordinated by two nitrogen atoms of NCS
−
and three nitrogen atoms from tpyOH or ftpy in a highly distorted square pyramidal geometry. Interestingly,
1
.DMSO contains four crystallographically independent molecules, each of them is hydrogen-bonded to DMSO and adopts supramolecular structure constructed by OH…O hydrogen bonds. On the other hand, the reaction of CdCl
2
with ftpy has been resulted in the formation of the new distorted square pyramid complex [Cd(ftpy)Cl
2
] (
3
). The crystal structure of
3
is stabilized by the extensive hydrogen bonds of C–H…Cl between H atoms of ftpy and the Cl atoms. Crystal structures of
2
.DMSO and
3
reveal that these porous materials have voids, occupied by the solvents. The volume of voids in
2
.DMSO and
3
are 542 and 555 Å
3
, respectively. Hirshfeld surface analysis were used to identify and quantify the inter-molecular interactions such as H-bonds and π-stackings. Thermogravimetric and differential thermal analysis showed that three compounds possess great thermal stabilities, especially for
2
which is stable up to 373 °C. The luminescent properties of compounds were assigned to π–π* transitions.</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-022-02299-9</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Atomic structure ; Chemical bonds ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Crystallization ; Crystallography ; Differential thermal analysis ; Differential thermogravimetric analysis ; Hydrogen bonding ; Hydrogen bonds ; Inorganic Chemistry ; Luminescence ; Molecular interactions ; Nitrogen atoms ; Optical properties ; Organic Chemistry ; Polymer Sciences ; Porous materials ; Surface analysis (chemical) ; Thermodynamic properties ; Zinc compounds</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2022, Vol.32 (6), p.2279-2297</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-40ce60b3ae2c26ac3baed0614e1bdd1bc2cefec0da817b729902e37da8422b223</citedby><cites>FETCH-LOGICAL-c249t-40ce60b3ae2c26ac3baed0614e1bdd1bc2cefec0da817b729902e37da8422b223</cites><orcidid>0000-0002-3184-9432</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-022-02299-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-022-02299-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Momeni, Badri Z.</creatorcontrib><creatorcontrib>Kazemzade Anari, Sanaz</creatorcontrib><creatorcontrib>Janczak, Jan</creatorcontrib><creatorcontrib>Fallahpour, Reza</creatorcontrib><title>Supramolecular Arrangement Built from Zinc and Cadmium Complexes with 4′-(4-Substituted)-2,2′:6′,2″-Terpyridine: Crystallographic Investigation, Luminescence and Thermal Properties</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>The reaction of Zn(NO
3
)
2
⋅6H
2
O with tpyOH or ftpy in the presence of KSCN affords the new zinc(II) complexes [Zn(tpyOH)(NCS)
2
] (
1
) and [Zn(ftpy)(NCS)
2
] (
2
) while two isostructural compound of [Zn(tpyOH)(NCS)
2
].DMSO (
1
.DMSO) and [Zn(ftpy)(NCS)
2
].DMSO (
2
.DMSO) were obtained during the crystallization in DMSO, respectively. Structurally,
1
.DMSO and
2
.DMSO reveal that the Zn(II) is penta-coordinated by two nitrogen atoms of NCS
−
and three nitrogen atoms from tpyOH or ftpy in a highly distorted square pyramidal geometry. Interestingly,
1
.DMSO contains four crystallographically independent molecules, each of them is hydrogen-bonded to DMSO and adopts supramolecular structure constructed by OH…O hydrogen bonds. On the other hand, the reaction of CdCl
2
with ftpy has been resulted in the formation of the new distorted square pyramid complex [Cd(ftpy)Cl
2
] (
3
). The crystal structure of
3
is stabilized by the extensive hydrogen bonds of C–H…Cl between H atoms of ftpy and the Cl atoms. Crystal structures of
2
.DMSO and
3
reveal that these porous materials have voids, occupied by the solvents. The volume of voids in
2
.DMSO and
3
are 542 and 555 Å
3
, respectively. Hirshfeld surface analysis were used to identify and quantify the inter-molecular interactions such as H-bonds and π-stackings. Thermogravimetric and differential thermal analysis showed that three compounds possess great thermal stabilities, especially for
2
which is stable up to 373 °C. The luminescent properties of compounds were assigned to π–π* transitions.</description><subject>Atomic structure</subject><subject>Chemical bonds</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Crystallization</subject><subject>Crystallography</subject><subject>Differential thermal analysis</subject><subject>Differential thermogravimetric analysis</subject><subject>Hydrogen bonding</subject><subject>Hydrogen bonds</subject><subject>Inorganic Chemistry</subject><subject>Luminescence</subject><subject>Molecular interactions</subject><subject>Nitrogen atoms</subject><subject>Optical properties</subject><subject>Organic Chemistry</subject><subject>Polymer Sciences</subject><subject>Porous materials</subject><subject>Surface analysis (chemical)</subject><subject>Thermodynamic properties</subject><subject>Zinc compounds</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9Uc1u1DAQjhBIlMILcLLEBaQabMebbHorUYFKK4HU5cLFcpzZXVexHcY2sLc-E1x5Gp4EbxfBjcP86vtmRvNV1VPOXnLG2leRs45JyoQ4WNfR7l51whetpFwu-P2_uawfVo9ivGGsXrIFP6l-XucZtQsTmDxpJBeI2m_BgU_kdbZTIhsMjnyy3hDtR9Lr0dnsSB_cPME3iOSrTTsif91-p88lvc5DTDblBOMLKs5EaZ83xR2yH3QNOO_RjtbDOelxH5OeprBFPe-sIVf-CxTyVicb_BlZZVdw0YA3cLd6vQN0eiIfMMyAyUJ8XD3Y6CnCkz_xtPr45nLdv6Or92-v-osVNUJ2iUpmoGFDrUEY0WhTDxpG1nAJfBhHPhhhYAOGjXrJ26Et72MC6raUUohBiPq0enacO2P4nMuR6iZk9GWlEk3biWbZ8GVBiSPKYIgRYaNmtE7jXnGmDiqpo0qqKKTuVFJdIdVHUizg8nj8N_o_rN_vFJzf</recordid><startdate>2022</startdate><enddate>2022</enddate><creator>Momeni, Badri Z.</creator><creator>Kazemzade Anari, Sanaz</creator><creator>Janczak, Jan</creator><creator>Fallahpour, Reza</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-3184-9432</orcidid></search><sort><creationdate>2022</creationdate><title>Supramolecular Arrangement Built from Zinc and Cadmium Complexes with 4′-(4-Substituted)-2,2′:6′,2″-Terpyridine: Crystallographic Investigation, Luminescence and Thermal Properties</title><author>Momeni, Badri Z. ; Kazemzade Anari, Sanaz ; Janczak, Jan ; Fallahpour, Reza</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-40ce60b3ae2c26ac3baed0614e1bdd1bc2cefec0da817b729902e37da8422b223</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Atomic structure</topic><topic>Chemical bonds</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Crystallization</topic><topic>Crystallography</topic><topic>Differential thermal analysis</topic><topic>Differential thermogravimetric analysis</topic><topic>Hydrogen bonding</topic><topic>Hydrogen bonds</topic><topic>Inorganic Chemistry</topic><topic>Luminescence</topic><topic>Molecular interactions</topic><topic>Nitrogen atoms</topic><topic>Optical properties</topic><topic>Organic Chemistry</topic><topic>Polymer Sciences</topic><topic>Porous materials</topic><topic>Surface analysis (chemical)</topic><topic>Thermodynamic properties</topic><topic>Zinc compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Momeni, Badri Z.</creatorcontrib><creatorcontrib>Kazemzade Anari, Sanaz</creatorcontrib><creatorcontrib>Janczak, Jan</creatorcontrib><creatorcontrib>Fallahpour, Reza</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Momeni, Badri Z.</au><au>Kazemzade Anari, Sanaz</au><au>Janczak, Jan</au><au>Fallahpour, Reza</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Supramolecular Arrangement Built from Zinc and Cadmium Complexes with 4′-(4-Substituted)-2,2′:6′,2″-Terpyridine: Crystallographic Investigation, Luminescence and Thermal Properties</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2022</date><risdate>2022</risdate><volume>32</volume><issue>6</issue><spage>2279</spage><epage>2297</epage><pages>2279-2297</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>The reaction of Zn(NO
3
)
2
⋅6H
2
O with tpyOH or ftpy in the presence of KSCN affords the new zinc(II) complexes [Zn(tpyOH)(NCS)
2
] (
1
) and [Zn(ftpy)(NCS)
2
] (
2
) while two isostructural compound of [Zn(tpyOH)(NCS)
2
].DMSO (
1
.DMSO) and [Zn(ftpy)(NCS)
2
].DMSO (
2
.DMSO) were obtained during the crystallization in DMSO, respectively. Structurally,
1
.DMSO and
2
.DMSO reveal that the Zn(II) is penta-coordinated by two nitrogen atoms of NCS
−
and three nitrogen atoms from tpyOH or ftpy in a highly distorted square pyramidal geometry. Interestingly,
1
.DMSO contains four crystallographically independent molecules, each of them is hydrogen-bonded to DMSO and adopts supramolecular structure constructed by OH…O hydrogen bonds. On the other hand, the reaction of CdCl
2
with ftpy has been resulted in the formation of the new distorted square pyramid complex [Cd(ftpy)Cl
2
] (
3
). The crystal structure of
3
is stabilized by the extensive hydrogen bonds of C–H…Cl between H atoms of ftpy and the Cl atoms. Crystal structures of
2
.DMSO and
3
reveal that these porous materials have voids, occupied by the solvents. The volume of voids in
2
.DMSO and
3
are 542 and 555 Å
3
, respectively. Hirshfeld surface analysis were used to identify and quantify the inter-molecular interactions such as H-bonds and π-stackings. Thermogravimetric and differential thermal analysis showed that three compounds possess great thermal stabilities, especially for
2
which is stable up to 373 °C. The luminescent properties of compounds were assigned to π–π* transitions.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-022-02299-9</doi><tpages>19</tpages><orcidid>https://orcid.org/0000-0002-3184-9432</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1574-1443 |
| ispartof | Journal of inorganic and organometallic polymers and materials, 2022, Vol.32 (6), p.2279-2297 |
| issn | 1574-1443 1574-1451 |
| language | eng |
| recordid | cdi_proquest_journals_2679268618 |
| source | SpringerNature Journals |
| subjects | Atomic structure Chemical bonds Chemistry Chemistry and Materials Science Crystal structure Crystallization Crystallography Differential thermal analysis Differential thermogravimetric analysis Hydrogen bonding Hydrogen bonds Inorganic Chemistry Luminescence Molecular interactions Nitrogen atoms Optical properties Organic Chemistry Polymer Sciences Porous materials Surface analysis (chemical) Thermodynamic properties Zinc compounds |
| title | Supramolecular Arrangement Built from Zinc and Cadmium Complexes with 4′-(4-Substituted)-2,2′:6′,2″-Terpyridine: Crystallographic Investigation, Luminescence and Thermal Properties |
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