Access to Nitrones from Amines via Electrocatalysis at Room Temperature
A self‐enabled electrooxidative protocol for the synthesis of nitrones from bench stable amines has been developed under constant current electrolysis at room temperature, rendering metal and external oxidant‐free protocol in an alkaline medium. The electrocatalysis steps of reported strategy involv...
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| Veröffentlicht in: | Advanced synthesis & catalysis 2022-06, Vol.364 (12), p.1982-1988 |
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| container_end_page | 1988 |
|---|---|
| container_issue | 12 |
| container_start_page | 1982 |
| container_title | Advanced synthesis & catalysis |
| container_volume | 364 |
| creator | Shukla, Gaurav Yadav, Dhananjay Singh, Saurabh Shankar Singh, Maya |
| description | A self‐enabled electrooxidative protocol for the synthesis of nitrones from bench stable amines has been developed under constant current electrolysis at room temperature, rendering metal and external oxidant‐free protocol in an alkaline medium. The electrocatalysis steps of reported strategy involve anodic oxidation of benzyl amines followed by cathodic reduction of nitro‐functional group in an undivided cell affording functional nitrones. The robustness of the electrocatalysis was reflected by tolerant substrate scope, oxidant‐free conditions, and an operationally friendly procedure. Moreover, the cyclic voltammetry and control experiment studies also support the electrochemical process in alkaline medium. |
| doi_str_mv | 10.1002/adsc.202200188 |
| format | Article |
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The electrocatalysis steps of reported strategy involve anodic oxidation of benzyl amines followed by cathodic reduction of nitro‐functional group in an undivided cell affording functional nitrones. The robustness of the electrocatalysis was reflected by tolerant substrate scope, oxidant‐free conditions, and an operationally friendly procedure. 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Moreover, the cyclic voltammetry and control experiment studies also support the electrochemical process in alkaline medium.</description><subject>Amines</subject><subject>Anodizing</subject><subject>Benzyl amines</subject><subject>Chemical reduction</subject><subject>Electrocatalysis</subject><subject>Electrochemical</subject><subject>Electrolysis</subject><subject>Functional groups</subject><subject>Metal-free</subject><subject>Nitrones</subject><subject>Oxidant-free</subject><subject>Oxidation</subject><subject>Oxidizing agents</subject><subject>Room temperature</subject><subject>Substrates</subject><issn>1615-4150</issn><issn>1615-4169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqFkN1LwzAUxYMoOKevPgd87sxHm6SPZc4pDAWdzyGmN9DRLjNplf33y6jMR-HCPXB_5x44CN1SMqOEsHtTRztjhDFCqFJnaEIFLbKcivL8pAtyia5i3CREKiknaFlZCzHi3uOXpg9-CxG74Dtcdc1RfzcGL1qw6WRNb9p9bCI2PX7ziVlDt4Ng-iHANbpwpo1w87un6ONxsZ4_ZavX5fO8WmWWF1JlVpXgHHdCQV4AVQB1AYyVQpDaUeFyx3LGRRpqCiulNYJKbtWn5WWugPMpuhv_7oL_GiD2euOHsE2RmgmpSsmJkomajZQNPsYATu9C05mw15ToY1n6WJY-lZUM5Wj4aVrY_0Pr6uF9_uc9AJ68bVc</recordid><startdate>20220621</startdate><enddate>20220621</enddate><creator>Shukla, Gaurav</creator><creator>Yadav, Dhananjay</creator><creator>Singh, Saurabh</creator><creator>Shankar Singh, Maya</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20220621</creationdate><title>Access to Nitrones from Amines via Electrocatalysis at Room Temperature</title><author>Shukla, Gaurav ; Yadav, Dhananjay ; Singh, Saurabh ; Shankar Singh, Maya</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3578-c89eff3f68e45e18eed5e229660df16f4f242362361a5c77ca6173c8bc3948e33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Amines</topic><topic>Anodizing</topic><topic>Benzyl amines</topic><topic>Chemical reduction</topic><topic>Electrocatalysis</topic><topic>Electrochemical</topic><topic>Electrolysis</topic><topic>Functional groups</topic><topic>Metal-free</topic><topic>Nitrones</topic><topic>Oxidant-free</topic><topic>Oxidation</topic><topic>Oxidizing agents</topic><topic>Room temperature</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shukla, Gaurav</creatorcontrib><creatorcontrib>Yadav, Dhananjay</creatorcontrib><creatorcontrib>Singh, Saurabh</creatorcontrib><creatorcontrib>Shankar Singh, Maya</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced synthesis & catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shukla, Gaurav</au><au>Yadav, Dhananjay</au><au>Singh, Saurabh</au><au>Shankar Singh, Maya</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Access to Nitrones from Amines via Electrocatalysis at Room Temperature</atitle><jtitle>Advanced synthesis & catalysis</jtitle><date>2022-06-21</date><risdate>2022</risdate><volume>364</volume><issue>12</issue><spage>1982</spage><epage>1988</epage><pages>1982-1988</pages><issn>1615-4150</issn><eissn>1615-4169</eissn><abstract>A self‐enabled electrooxidative protocol for the synthesis of nitrones from bench stable amines has been developed under constant current electrolysis at room temperature, rendering metal and external oxidant‐free protocol in an alkaline medium. 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| source | Wiley Online Library All Journals |
| subjects | Amines Anodizing Benzyl amines Chemical reduction Electrocatalysis Electrochemical Electrolysis Functional groups Metal-free Nitrones Oxidant-free Oxidation Oxidizing agents Room temperature Substrates |
| title | Access to Nitrones from Amines via Electrocatalysis at Room Temperature |
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