Cyclometallated Ruthenium Complex with 3,3',5,5'-Tetramethyl-1,1'-biphenyl-4,4'-bipyrazole and 2,2'-Dicarboxybipyridine: Synthesis, Optical Properties, and Quantum Chemical Modeling

New complex [RuL(Dmdcbp) 2 ]PF 6 ( I ) is synthesized by the consecutive reactions of [Ru- p -cymene] 2 Cl 4 with 3,3',5,5'-tetramethyl-1,1'-biphenyl-4,4'-bipyrazole (L) and 4,4'-dicarboxy-2,2'-bipyridine in a methanol–chloroform medium. The composition of complex I is...

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Veröffentlicht in:	Russian journal of coordination chemistry 2022-06, Vol.48 (6), p.353-361
Hauptverfasser:	Lavrova, M. A., Lunev, A. M., Goncharenko, V. E., Taidakov, I. V., Dolzhenko, V. D., Belousov, Yu. A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical synthesis Chemistry Chemistry and Materials Science Chloroform Coordination compounds Density functional theory Emission spectra Inorganic Chemistry Luminescence NMR Nuclear magnetic resonance Optical properties Physical Chemistry Quantum chemistry Ruthenium compounds
Online-Zugang:	Volltext
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